Application of chiral cyclic diols to asymmetric induction キラル環状ジオールを用いた不斉誘起反応

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Author

    • 加藤, 恵介 カトウ, ケイスケ

Bibliographic Information

Title

Application of chiral cyclic diols to asymmetric induction

Other Title

キラル環状ジオールを用いた不斉誘起反応

Author

加藤, 恵介

Author(Another name)

カトウ, ケイスケ

University

九州大学

Types of degree

博士 (薬学)

Grant ID

甲第3298号

Degree year

1994-03-25

Note and Description

博士論文

資料形態 : テキストデータ プレーンテキスト

コレクション : 国立国会図書館デジタルコレクション > デジタル化資料 > 博士論文

CHAPTER 1 Asymmetric alkylation of chiral acetals prepared from cyclic or acyclic β-keto esters and chiral cyclic diols CHAPTER 2 Preparation of optically active tricyclic 1,4-dioxepin-5-one derivatives and its application to asymmetric alkylation CHAPTER 3 Asymmetric induction to meso-cyclohexane-1,2-diol, based on diastereoselective elimination CHAPTER 4 Asymmetric oxidation of β-keto esters using chiral cyclic diols CHAPTER 5 A new type of asymmetric double Michael reaction induced by chiral acetal

Table of Contents

  1. CONTENTS
  2. INTRODUCTION
  3. LIST OF PUBLICATIONS
  4. CHAPTER I Asymmetric alkylation of chiral acetals prepared from cyclic or acyclic β-keto esters and chiral cyclic diols
  5. 1.Introduction
  6. 2.Preparation of acetal substrates
  7. 3.Alkylation of five-membered ring and acyclic substrates
  8. 4.Alkylation of six-membered ring substrates
  9. 5.Determination of absolute configuration and proposed mechanism
  10. 6.Stereoselective synthesis of (+) and(-)-spiro [4.4] nonan-1,6-diols
  11. CHAPTER II Preparation of optically active tricyclic 1,4-dioxepin-5-one derivatives and its application to asymmetric alkylation
  12. 1.Introduction
  13. 2.Preparation of chiral tricyclic γ-oxa-α,β-unsaturated lactones
  14. 3.Asymmetric alkylation of chiral tricyclic γ-oxa-α,β-unsaturated lactones
  15. 4.Determination of absolute configuration and proposed mechanism
  16. CHAPTER III Asymmetric induction to meso-cyclohexane-1,2-diol, based on diastereoselective elimination
  17. 1.Introduction
  18. 2.Preparation of substrates
  19. 3.Asymmetric induction to meso-cyclohexane-1,2-diol
  20. 4.Determination of absolute configuration and proposed mechanism
  21. CHAPTER IV Asymmetric oxidation of β-keto esters using chiral cyclic diols
  22. 1.Introduction
  23. 2.Preparation of substrates
  24. 3.Oxidation of β'-trimethylsilyloxy enol ethers
  25. 4.Oxidation of enol ethers with free hydroxy group
  26. 5.Determination of absolute configuration and proposed mechanism
  27. CHAPTER V A new type of asymmetric double Michael reaction induced by chiral acetal
  28. 1.Introduction
  29. 2.Asymmetric double Michael reaction
  30. 3.Determination of absolute configuration and proposed mechanism
  31. SUMMARY OF THE ORIGINAL WORKS
  32. EXPERIMENTAL SECTION
  33. Chapter I
  34. Chapter II
  35. Chapter III
  36. Chapter IV
  37. Chapter V
  38. REFERENCES
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Codes

  • NII Article ID (NAID)
    500002023819
  • NII Author ID (NRID)
    • 8000002587781
  • DOI(NDL)
  • Text Lang
    • eng
  • NDLBibID
    • 000000270560
  • Source
    • Institutional Repository
    • NDL ONLINE
    • NDL Digital Collections

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