Application of chiral cyclic diols to asymmetric induction キラル環状ジオールを用いた不斉誘起反応

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Author

    • 加藤, 恵介 カトウ, ケイスケ

Bibliographic Information

Title

Application of chiral cyclic diols to asymmetric induction

Other Title

キラル環状ジオールを用いた不斉誘起反応

Author

加藤, 恵介

Author(Another name)

カトウ, ケイスケ

University

九州大学

Types of degree

博士 (薬学)

Grant ID

甲第3298号

Degree year

1994-03-25

Note and Description

博士論文

CHAPTER 1 Asymmetric alkylation of chiral acetals prepared from cyclic or acyclic β-keto esters and chiral cyclic diols CHAPTER 2 Preparation of optically active tricyclic 1,4-dioxepin-5-one derivatives and its application to asymmetric alkylation CHAPTER 3 Asymmetric induction to meso-cyclohexane-1,2-diol, based on diastereoselective elimination CHAPTER 4 Asymmetric oxidation of β-keto esters using chiral cyclic diols CHAPTER 5 A new type of asymmetric double Michael reaction induced by chiral acetal

Table of Contents

  1. CONTENTS / (0003.jp2)
  2. INTRODUCTION / p1 (0004.jp2)
  3. LIST OF PUBLICATIONS / p7 (0007.jp2)
  4. CHAPTER I Asymmetric alkylation of chiral acetals prepared from cyclic or acyclic β-keto esters and chiral cyclic diols / p9 (0008.jp2)
  5. 1.Introduction / p9 (0008.jp2)
  6. 2.Preparation of acetal substrates / p10 (0008.jp2)
  7. 3.Alkylation of five-membered ring and acyclic substrates / p12 (0009.jp2)
  8. 4.Alkylation of six-membered ring substrates / p14 (0010.jp2)
  9. 5.Determination of absolute configuration and proposed mechanism / p19 (0013.jp2)
  10. 6.Stereoselective synthesis of (+) and(-)-spiro [4.4] nonan-1,6-diols / p21 (0014.jp2)
  11. CHAPTER II Preparation of optically active tricyclic 1,4-dioxepin-5-one derivatives and its application to asymmetric alkylation / p32 (0019.jp2)
  12. 1.Introduction / p32 (0019.jp2)
  13. 2.Preparation of chiral tricyclic γ-oxa-α,β-unsaturated lactones / p34 (0020.jp2)
  14. 3.Asymmetric alkylation of chiral tricyclic γ-oxa-α,β-unsaturated lactones / p36 (0021.jp2)
  15. 4.Determination of absolute configuration and proposed mechanism / p38 (0022.jp2)
  16. CHAPTER III Asymmetric induction to meso-cyclohexane-1,2-diol, based on diastereoselective elimination / p42 (0024.jp2)
  17. 1.Introduction / p42 (0024.jp2)
  18. 2.Preparation of substrates / p43 (0025.jp2)
  19. 3.Asymmetric induction to meso-cyclohexane-1,2-diol / p45 (0026.jp2)
  20. 4.Determination of absolute configuration and proposed mechanism / p47 (0027.jp2)
  21. CHAPTER IV Asymmetric oxidation of β-keto esters using chiral cyclic diols / p51 (0029.jp2)
  22. 1.Introduction / p51 (0029.jp2)
  23. 2.Preparation of substrates / p52 (0029.jp2)
  24. 3.Oxidation of β'-trimethylsilyloxy enol ethers / p54 (0030.jp2)
  25. 4.Oxidation of enol ethers with free hydroxy group / p56 (0031.jp2)
  26. 5.Determination of absolute configuration and proposed mechanism / p58 (0032.jp2)
  27. CHAPTER V A new type of asymmetric double Michael reaction induced by chiral acetal / p64 (0035.jp2)
  28. 1.Introduction / p64 (0035.jp2)
  29. 2.Asymmetric double Michael reaction / p65 (0036.jp2)
  30. 3.Determination of absolute configuration and proposed mechanism / p69 (0038.jp2)
  31. SUMMARY OF THE ORIGINAL WORKS / p74 (0040.jp2)
  32. EXPERIMENTAL SECTION / p75 (0041.jp2)
  33. Chapter I / p75 (0041.jp2)
  34. Chapter II / p90 (0048.jp2)
  35. Chapter III / p94 (0050.jp2)
  36. Chapter IV / p97 (0052.jp2)
  37. Chapter V / p104 (0055.jp2)
  38. REFERENCES / p109 (0058.jp2)
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Codes

  • NII Article ID (NAID)
    500000106246
  • NII Author ID (NRID)
    • 8000000106486
  • DOI(NDL)
  • Text Lang
    • eng
  • NDLBibID
    • 000000270560
  • Source
    • Institutional Repository
    • NDL ONLINE
    • NDL Digital Collections

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