Development of stereoselective catalytic reactions and construction of polycyclic furan ring systems based on furan ring transfer reaction 立体選択的触媒反応の開発とフラン環転送反応を用いる多環性フランの構築法
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著者
書誌事項
- タイトル
-
Development of stereoselective catalytic reactions and construction of polycyclic furan ring systems based on furan ring transfer reaction
- タイトル別名
-
立体選択的触媒反応の開発とフラン環転送反応を用いる多環性フランの構築法
- 著者名
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馬場, 良泰
- 著者別名
-
ババ, ヨシヤス
- 学位授与大学
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九州大学
- 取得学位
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博士 (薬学)
- 学位授与番号
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甲第3389号
- 学位授与年月日
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1994-05-23
注記・抄録
博士論文
目次
- CONTENTS / p3 (0004.jp2)
- PART I / (0005.jp2)
- Development of Stereoselective Catalytic Reactions / (0005.jp2)
- INTRODUCTION / p1 (0006.jp2)
- CHAPTER I Stereoselective Reduction of Alkynes by the Reagent Samarium(II) Iodide-Transition Metal Catalyst Reducing System / p3 (0007.jp2)
- 1.General Aspect / p3 (0007.jp2)
- 2.Catalytic Activity and Reaction Conditions / p6 (0009.jp2)
- 3.Reduction of Various Alkynes / p11 (0011.jp2)
- 4.Mechanistic Consideration / p15 (0013.jp2)
- 5.Conclusion / p17 (0014.jp2)
- CHAPTER II Phosphine(III)-Catalyzed Conjugate Addition of Alcohols to α,β-Unsaturated Alkynic Esters / p18 (0015.jp2)
- 1.General Aspect / p18 (0015.jp2)
- 2.Examination of Catalytic Activity and Reaction Conditions / p20 (0016.jp2)
- 3.Scope and Limitation / p23 (0017.jp2)
- 4.Reaction Mechanism / p28 (0020.jp2)
- 5.Synthetic Utility of 3-Allyloxy Acrylate / p30 (0021.jp2)
- PART II / (0024.jp2)
- Construction of Polycyclic Furan Ring Systems Based on Furan Ring Transfer Reaction / (0024.jp2)
- INTRODUCTION / p37 (0025.jp2)
- CHAPTER III Total Synthesis of(±)-Euryfuran / p44 (0029.jp2)
- 1.General Aspect / p44 (0029.jp2)
- 2.Synthetic Strategies for Euryfuran / p52 (0033.jp2)
- 3.Synthesis of (±)-Euryfuran / p52 (0033.jp2)
- CHAPTER IV Construction of Furanohydrophenanthrene Ring System Based on Furan Ring Transfer Reaction / p59 (0036.jp2)
- 1.General Aspect / p59 (0036.jp2)
- 2.Synthetic Approach for Furanohydrophenanthrene Ring System via FRT Reaction and Sequential Annulation / p61 (0037.jp2)
- 3.Synthetic Approach for Furanohydrophenanthrene Ring System via FRT Reaction and Sequential Annulation and Bis-annulation / p65 (0039.jp2)
- 4.Studies on the Stereochemical Outcome on the Basis of Molecular Mechanics Calculations / p68 (0041.jp2)
- CHAPTER V Efficient Synthetic Strategies for Hydroazulenofuran ring systems. Synthetic Approach to(±)-Furoscrobiculin B / p71 (0042.jp2)
- 1.General Aspect / p71 (0042.jp2)
- 2.Synthetic Strategies for(±)-Furoscrobiculin B / p75 (0044.jp2)
- 3.Synthesis for(±)-Furoscrobiculin B / p75 (0044.jp2)
- SUMMARY OF THE ORIGINAL WORK / p83 (0048.jp2)
- EXPERIMENTAL SECTION / p85 (0049.jp2)
- CHAPTER I / p85 (0049.jp2)
- CHAPTER II / p86 (0050.jp2)
- CHAPTER III / p88 (0051.jp2)
- CHAPTER IV / p98 (0056.jp2)
- CHAPTER V / p101 (0057.jp2)
- REFERENCES / p109 (0061.jp2)
- LIST OF PUBLICATIONS / p113 (0063.jp2)