Studies on electrophilic substitutions of aromatic compounds using superacids

Access this Article

Title: Studies on electrophilic substitutions of aromatic compounds using superacids

博士論文

Contents / p4 (0005.jp2)
Preface / p1 (0003.jp2)
List of Publications / p2 (0004.jp2)
Contents / p4 (0005.jp2)
Introduction / p1 (0006.jp2)
General Introduction / p1 (0006.jp2)
References and Notes / p2 (0007.jp2)
Chapter1.Formylation of Aromatic Compounds / p3 (0007.jp2)
1-1.Introduction / p3 (0007.jp2)
1-2.Formylation of Aromatic Compounds with CO Using HSO₃F-SbF₅ / p3 (0007.jp2)
1-3.Diformylation of Polynuclear Aromatic Compounds with CO UsingHF-SbF₅ / p9 (0010.jp2)
1-4.Experimental Section / p15 (0013.jp2)
1-5.References and Notes / p18 (0015.jp2)
Chapter2.Formylation Mechanism of Aromatic Compounds / p20 (0016.jp2)
2-1.Introduction / p20 (0016.jp2)
2-2.Influence of Protonation on Formylation Rate / p21 (0016.jp2)
2-3.Nature of Formyl Cation / p32 (0022.jp2)
2-4.Influence of Protonation on Formylation Regioselectivity / p41 (0026.jp2)
2-5.Experimental Section / p46 (0029.jp2)
2-6.References and Notes / p50 (0031.jp2)
Chapter3.Sulfonation of Aromatic Compounds / p54 (0033.jp2)
3-1.Introduction / p54 (0033.jp2)
3-2.Sulfonation of Aromatic Compounds Using HSO₃F-SbF₅ / p55 (0033.jp2)
3-3.Experimental Section / p58 (0035.jp2)
3-4.References and Notes / p60 (0036.jp2)
Chapter4.Coupling Reaction of Aromatic Compounds / p61 (0036.jp2)
4-1.Introduction / p61 (0036.jp2)
4-2.Coupling Reaction of Naphthalene Derivatives Using CF₃SO₃H-NaN0₂ or SbF₅ / p61 (0036.jp2)
4-3.Experimental Section / p72 (0042.jp2)
4-4.References and Notes / p73 (0042.jp2)
Conclusions / p78 (0045.jp2)