Reduction of diruthenium complexes by group 14 metal hydrides : an organometallic approach to catalytic CO hydrogenation 14族金属水素化物による複核ルテニウム錯体の還元反応 : 触媒的CO水素化反応への有機金属化学的アプローチ

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著者

    • 華, 瑞茂 ファー, ルイマオ

書誌事項

タイトル

Reduction of diruthenium complexes by group 14 metal hydrides : an organometallic approach to catalytic CO hydrogenation

タイトル別名

14族金属水素化物による複核ルテニウム錯体の還元反応 : 触媒的CO水素化反応への有機金属化学的アプローチ

著者名

華, 瑞茂

著者別名

ファー, ルイマオ

学位授与大学

東京工業大学

取得学位

博士 (工学)

学位授与番号

甲第3362号

学位授与年月日

1996-09-30

注記・抄録

博士論文

目次

  1. 論文目録 / (0001.jp2)
  2. Contents / (0005.jp2)
  3. Acknowledgment / (0004.jp2)
  4. Chapter 1 General Introduction / p1 (0007.jp2)
  5. 1-1 Catalytic CO Hydrogenation(Fischer-Tropsch Synthesis) and Proposed Reaction Mechanisms / p2 (0008.jp2)
  6. 1-2 Organometallic Approaches to the Reaction Mechanism of Catalytic CO Hydrogenation / p5 (0011.jp2)
  7. 1-3 Purpose and Scope of this Thesis / p10 (0016.jp2)
  8. 1-4 References / p14 (0020.jp2)
  9. Chapter 2 Deoxygenative Reduction of Diruthenium Carbonyl Complexes Cp₂Ru₂(μ-CO)₂(CO)₂ with Hydrosilanes Leading to Bridging Methylene Complexes Cp₂Ru₂(μ-CH₂)n(μ-CO)₂₋n(CO)₂(n=1,2) / p17 (0023.jp2)
  10. 2-1 Introduction / p18 (0024.jp2)
  11. 2-2 Reduction of Diruthenium Carbonyl Complex Cp₂Ru₂(CO)₄ Leading to μ-Methylene Complexes Cp₂Ru₂(μ-CH₂)n(CO)₄₋n(n=1,2) / p19 (0025.jp2)
  12. 2-3 Summary / p27 (0033.jp2)
  13. 2-4 References and Notes / p28 (0034.jp2)
  14. Chapter 3 Conversion of a Diruthenium μ-Methylene Complex Cp₂Ru₂(μ-CH₂)(μ-CO)(CO)₂ into Methane through Reduction with Hydrosilane:Chemical Properties of Silyl-μ-methylene Intermediates Cp₂Ru₂(μ-CH₂)(SiR₃)(X)(CO)₂(X=H,SiR₃)Relevant to Methanation / p30 (0036.jp2)
  15. 3-1 Introduction / p31 (0037.jp2)
  16. 3-2 Conversion of μ-Methylene Complex Cp₂Ru₂(μ-CH₂)(μ-CO)(CO)₂1 into Methane through Reduction with Hydrosilane / p31 (0037.jp2)
  17. 3-3 Reaction of Cp₂Ru₂(μ-CH₂)(μ-CO)(CO)(MeCN) 4 with Hydrostannanes Leading to Stannylated μ-Methylane Species Cp₂Ru₂(μ-CH₂)(X)(SnR₃)(CO)20(X=H) and 21(X=SnR₃) / p50 (0056.jp2)
  18. 3-4 Consideration of the Formation Mechanism of Methane from 1 / p55 (0061.jp2)
  19. 3-5 Summary / p58 (0064.jp2)
  20. 3-6 References and Notes / p60 (0066.jp2)
  21. Chapter 4 C-C Bond Formation of the Diruthenium μ-Methylene Complex Cp₂Ru₂(μ-CH₂)(CO)₂(MeCN) with Diazoalkane / p62 (0068.jp2)
  22. 4-1 Introduction / p63 (0069.jp2)
  23. 4-2 Reaction of the μ-Methylene Complex Cp₂Ru₂(μ-CH₂)(CO)₂(NCMe)1 with Diazoalkane(N₂=CR₂) / p64 (0070.jp2)
  24. 4-3 Summary / p73 (0079.jp2)
  25. 4-4 References / p74 (0080.jp2)
  26. Chapter 5 Interaction of Labile Diruthenium Bis-μ-methylene and Carbonyl Species Cp₂Ru₂(μ-X)₂(CO)(MeCN)(X=CH₂,CO) with Hydrosilane and -stannane / p75 (0081.jp2)
  27. 5-1 Introduction / p76 (0082.jp2)
  28. 5-2 Synthesis and Reactivity of the MeCN Adduct of the Di-μ-methylene Complex, Cp₂Ru₂(μ-CH₂)₂(CO)(MeCN)1 / p76 (0082.jp2)
  29. 5-3 Synthesis and Reactivity of the MeCN Adduct of a Carbonyl Complex, Cp₂Ru₂(CO₃)(MeCN)11, toward Hydrosilane and -stannane / p92 (0098.jp2)
  30. 5-4 Summary / p97 (0103.jp2)
  31. 5-5 References / p99 (0105.jp2)
  32. Chapter 6 Reduction of a Diruthenium Bridging Vinylidene Species Cp₂Ru₂(μ-C=CH₂)(CO)(μ-CO)(MeCN) by Hydrosilane Leading to a Vinyl complex Cp₂Ru₂(μ-CH=CH₂)(CO)₂(SiR₃) and Vinylsilane / p100 (0106.jp2)
  33. 6-1 Introduction / p101 (0107.jp2)
  34. 6-2 Reduction of Cp₂Ru₂(μ-C=CH₂)(μ,-CO)(CO)(MeCN)1 with HSiR₃ / p101 (0107.jp2)
  35. 6-3 Summary / p109 (0115.jp2)
  36. 6-4 References and Notes / p110 (0116.jp2)
  37. Chapter 7 Summary / p111 (0117.jp2)
  38. Chapter 8 Experimental Section / p114 (0120.jp2)
  39. List of Publications / p131 (0137.jp2)
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各種コード

  • NII論文ID(NAID)
    500000153564
  • NII著者ID(NRID)
    • 8000001087594
  • DOI(NDL)
  • NDL書誌ID
    • 000000317878
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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