Studies on scope and limitation of sigmatropic rearrangement of γ-trifluoromethylated allylic alcohols γ-トリフルオロメチルアリルアルコール類に対するシグマトロピー転位の適用と限界に関する研究

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著者

    • 今野, 勉 コンノ, ツトム

書誌事項

タイトル

Studies on scope and limitation of sigmatropic rearrangement of γ-trifluoromethylated allylic alcohols

タイトル別名

γ-トリフルオロメチルアリルアルコール類に対するシグマトロピー転位の適用と限界に関する研究

著者名

今野, 勉

著者別名

コンノ, ツトム

学位授与大学

東京工業大学

取得学位

博士 (工学)

学位授与番号

甲第3493号

学位授与年月日

1997-03-26

注記・抄録

博士論文

目次

  1. 論文目録 / (0002.jp2)
  2. Contents / (0004.jp2)
  3. Chapter1 Introduction / p1 (0009.jp2)
  4. 1-1 Introduction / p1 (0009.jp2)
  5. 1-2 Limitation in the“Building block methodology” / p9 (0017.jp2)
  6. 1-3 Sigmatropic rearrangement / p14 (0022.jp2)
  7. 1-4 Utility in [2,3]-Wittig or [3,3]-Claisen rearrangement of γ-trifluoromethylated allylic alcohol derivatives / p22 (0030.jp2)
  8. References / p29 (0037.jp2)
  9. Chapter2 Preparation of chiral γ-trifluoromethylated and γ-difluoromethylated allylic alcohols / p33 (0041.jp2)
  10. 2-1 Introduction / p33 (0041.jp2)
  11. 2-2 Preparation of enantiomerically pure γ-trifluoromethylated allylic alcohols using enzymatic kinetic resolution / p35 (0043.jp2)
  12. 2-3 Preparation of γ-difluoromethylated allylic alcohols via a difluorocarbenemediated reaction as a key step / p44 (0052.jp2)
  13. 2-4 Conclusion / p50 (0058.jp2)
  14. References / p51 (0059.jp2)
  15. Experimental section / p53 (0061.jp2)
  16. Chapter3 [2,3]-Wittig rearrangement / p66 (0074.jp2)
  17. 3-1 Introduction / p66 (0074.jp2)
  18. 3-2 Stereoselection depending on the migrating terminus / p69 (0077.jp2)
  19. 3-3 Disadvantage of [2,3]-Wittig rearrangement in the synthesis of trifluoromethylated compounds / p72 (0080.jp2)
  20. 3-4 Examination of ester enolate [2,3]-Wittig rearrangement / p75 (0083.jp2)
  21. 3-5 Clarification of stereochemistry / p78 (0086.jp2)
  22. 3-6 Investigation of [2,3]-Wittig rearrangement of γ-difluoromethylated allylic alcohol derivatives / p81 (0089.jp2)
  23. 3-7 Mechanistic study I / p82 (0090.jp2)
  24. 3-8 Mechanistic study II / p86 (0094.jp2)
  25. 3-9 Ab initio and semiempirical calculations / p96 (0104.jp2)
  26. 3-10 Conclusion / p128 (0136.jp2)
  27. References / p129 (0137.jp2)
  28. Experimental section / p132 (0140.jp2)
  29. Chapter4 Ireland-Claisen rearrangement / p146 (0154.jp2)
  30. 4-1 Introduction / p146 (0154.jp2)
  31. 4-2 Ireland-Claisen rearrangement / p149 (0157.jp2)
  32. 4-3 Examination of [3,3]-Ireland-Claisen rearrangement of CF₃-containing substrates / p155 (0163.jp2)
  33. 4-4 Mechanistic study I / p167 (0175.jp2)
  34. 4-5 Mechanistic study II / p171 (0179.jp2)
  35. 4-6 Application of the rearranged products / p177 (0185.jp2)
  36. 4-7 Ireland-Claisen rearrangement of the difluoromethylated substrates / p198 (0206.jp2)
  37. 4-8 Conclusion / p200 (0208.jp2)
  38. References / p202 (0210.jp2)
  39. Experimental section / p206 (0214.jp2)
  40. Chapter5 Johnson-and Eshenmoser-Claisen rearrangements / p219 (0227.jp2)
  41. 5-1 Introduction / p219 (0227.jp2)
  42. 5-2 Johnson-Claisen rearrangement / p224 (0232.jp2)
  43. 5-3 Eshenmoser-Claisen rearrangement / p228 (0236.jp2)
  44. 5-4 Clarification of the stereochemistry / p230 (0238.jp2)
  45. 5-5 Johnson-Claisen rearrangement of γ-difluoromethylated propargylic and allylic alcohols / p235 (0243.jp2)
  46. 5-6 Conclusion / p236 (0244.jp2)
  47. References / p237 (0245.jp2)
  48. Experimental section / p238 (0246.jp2)
  49. Chapter6 Conclusion / p247 (0255.jp2)
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各種コード

  • NII論文ID(NAID)
    500000153695
  • NII著者ID(NRID)
    • 8000001092710
  • DOI(NDL)
  • NDL書誌ID
    • 000000318009
  • データ提供元
    • NDL ONLINE
    • NDLデジタルコレクション
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