Stereochemical assignment for acyclic structures in natural products based on long-range C-H nuclear spin coupling constants

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Title: Stereochemical assignment for acyclic structures in natural products based on long-range C-H nuclear spin coupling constants

博士論文

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学位論文本体及び論文要旨 : 1-183コマ

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Contents
Abbreviations
General Introduction
Chapter1.Methodology to Determine Relative Configuration in Acyclic Structures,and NMR Experiments for Measuring [数式]
1-1 Introduction
1-2 Dihedral angle dependency of coupling constants
1-3 Strategy for determining the relative stereochemistry
1-4 Methods for measuring [数式]
Chapter2.Application to Maitotoxin-Stereochemical Assignments for Terminal Acyclic Portions-
2-1 Introduction
2-2 Methods and Materials
2-3 Results and Discussion
2-4 Conclusion
Supplementary Material of Chapter2
Chapter3.Application to Amphidinol 3-Stereochemical Assignments for Amphidinol3-
3-1 Introduction
3-2 Methods and Materials
3-3 Results and Discussion
3-4 Conclusion
Supplementary Material of Chapter3
Concluding Remarks
Appendix I.Application to Zooxanthellatoxin Fragment-Stereochemical Assignments for C3´ -C7´Portion-
I-1 Introduction
I-2 Methods and Materials
I-3 Results and Discussion
Supplementary Material of Appendix I
Appendix II.Conformational Analysis of Natural Products Using Long-Range Carbon-Proton Coupling Constants:Three-Dimensional Structure of Okadaic Acid in Solution
II-1 Introduction
II-2 Results and Discussion
II-3 Experimental
Appendix III.Pulse Programs of the NMR experiments
Appendix IV.List of Publications