A rearrangement route to the synthesis of fluorinated amino acids 含フッ素アミノ酸合成に対する転位反応の応用
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Bibliographic Information
- Title
-
A rearrangement route to the synthesis of fluorinated amino acids
- Other Title
-
含フッ素アミノ酸合成に対する転位反応の応用
- Author
-
郝, 健
- Author(Another name)
-
ハオ, ケン
- University
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岡山大学
- Types of degree
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博士(工学)
- Grant ID
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甲第1888号
- Degree year
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1999-03-25
Note and Description
博士論文
Table of Contents
- Contents / p7 (0005.jp2)
- Preface / p9 (0006.jp2)
- Chapter1 General Introduction / p1 (0007.jp2)
- 1-1 The Aim of this Thesis / p2 (0008.jp2)
- 1-2 A Brief Overview of the Naturally Occurring Amino Acids and Their Fluorinated Agonists / p3 (0009.jp2)
- 1-3 General Summary / p15 (0015.jp2)
- References / p20 (0017.jp2)
- Chapter2 Synthesis of Fluorinated Isoserines / p24 (0019.jp2)
- 2-1 Introduction / p25 (0020.jp2)
- 2-2 Preparation of Fluorinated Imino Ethers / p29 (0022.jp2)
- 2-3 Intramolecular rearrangement Approach to the Synthesis of Fluorinated Imino Esters / p31 (0023.jp2)
- 2-4 Diastereoselective Reduction of Fluorinated Imino Alcohols / p35 (0025.jp2)
- 2-4 Proposed Mechanism for the Intramolecular Rearrangement of Fluoro-alkylated Imino Ethers / p40 (0028.jp2)
- 2-6 Experiment Section / p42 (0029.jp2)
- References / p48 (0032.jp2)
- Chapter3 Synthesis of Fluorinated Quinazolines and Indoles / p50 (0033.jp2)
- 3-1 Introduction / p51 (0034.jp2)
- 3-2 Preparation of Trifluoromethylated Imidamides / p57 (0037.jp2)
- 3-3 Intramolecular Defluorinative Cyclization for the Synthesis of Difluoro-Methylated Quinazolines and Indoles / p60 (0039.jp2)
- 3-4 Proposed Mechanism for the Intramolecular Defluorinative Cyclization / p72 (0045.jp2)
- 3-5 Preparation and Mechanism of Trifluoromethylated Imidazoles and Quinazolines / p78 (0048.jp2)
- 3-6 Experiment Section / p82 (0050.jp2)
- References / p92 (0055.jp2)
- Chapter4 Synthesis of Trifluoromethylated Thioamino Acid Derivatives / p94 (0056.jp2)
- 4-1 Introduction / p95 (0057.jp2)
- 4-2 Preparation of Trifluoromethylated Imino Thioethers / p98 (0059.jp2)
- 4-3 Intramolecular Desulfurization of Trifluoromethylated Imino Thioethers / p98 (0059.jp2)
- 4-4 Proposed Mechanism of Intramolecular Desulfurization / p101 (0060.jp2)
- 4-5 Experiment Section / p103 (0061.jp2)
- References / p106 (0063.jp2)
- Acknowledgment / p107 (0063.jp2)