Novel usage of indium catalyst for organic synthesis with organosilicon or organotin compounds インジウム触媒による有機ケイ素および有機スズ化合物を用いた合成反応の開発

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著者

    • 宮井, 孝 ミヤイ, タカシ

書誌事項

タイトル

Novel usage of indium catalyst for organic synthesis with organosilicon or organotin compounds

タイトル別名

インジウム触媒による有機ケイ素および有機スズ化合物を用いた合成反応の開発

著者名

宮井, 孝

著者別名

ミヤイ, タカシ

学位授与大学

大阪大学

取得学位

博士 (工学)

学位授与番号

甲第6856号

学位授与年月日

1999-03-25

注記・抄録

博士論文

目次

  1. Contents / p4 (0005.jp2)
  2. Preface / p1 (0003.jp2)
  3. List of Publications / p2 (0004.jp2)
  4. Contents / p4 (0005.jp2)
  5. General Introduction / p1 (0006.jp2)
  6. Chapter 1 Solvent-Controlled Addition of Alkynyltins or Allylic Tins to Aldehydes Catalyzed by Indium Trichloride / p4 (0007.jp2)
  7. 1-1 Introduction / p4 (0005.jp2)
  8. 1-2 Transmetalation between InCl₃ and Alkynyltins / p5 (0008.jp2)
  9. 1-3 Plausible Mechanism / p6 (0008.jp2)
  10. 1-4 Reaction of Alkynyltins with Aldehydes / p6 (0008.jp2)
  11. 1-5 Solvent-Controlled Addition of Cinnamyltributyltin to Aldehyde / p8 (0009.jp2)
  12. 1-6 Experimental Section / p9 (0010.jp2)
  13. 1-7 References / p12 (0011.jp2)
  14. Chapter 2 Indium Triiodide (InI3)-Catalyzed Allylation of Carbonyl Compounds by Allylic Tins / p14 (0012.jp2)
  15. 2-1 Introduction / p14 (0012.jp2)
  16. 2-2 Indium Trichloride Catalyzed Allylation of Aldehydes / p15 (0013.jp2)
  17. 2-3 Indium Triiodide Catalyzed Allylation of Carbonyl Compounds / p16 (0013.jp2)
  18. 2-4 Chelation-Controlled Allyaltion / p18 (0014.jp2)
  19. 2-5 Reaction of γ-substituted E-allylic tins with Aldehyde / p19 (0015.jp2)
  20. 2-6 Experimental Section / p19 (0015.jp2)
  21. 2-7 References and Note / p23 (0017.jp2)
  22. Chapter 3 Preparation of a Novel Indium Hydride and Application to Practical Organic Synthesis / p24 (0017.jp2)
  23. 3-1 Introduction / p24 (0017.jp2)
  24. 3-2 Generation of Dichloroindium Hydride / p25 (0018.jp2)
  25. 3-3 Reaction of Dichloroindium Hydride with Carbonyl Compounds / p26 (0018.jp2)
  26. 3-4 Reaction of Dichloroindium Hydride with Alkyl Halides / p27 (0019.jp2)
  27. 3-5 Experimental Section / p29 (0020.jp2)
  28. 3-6 References / p31 (0021.jp2)
  29. Chapter 4 Novel Reductive Friedel-Crafts Alkylation of Aromatics Catalyzed by Indium Compounds:Chemoselective Utilization of Carbonyl Moieties as Alkylating Reagents / p34 (0022.jp2)
  30. 4-1 Introduction / p34 (0022.jp2)
  31. 4-2 Investigation of Catalyst / p35 (0023.jp2)
  32. 4-3 Alkylation of Aromatics Using Carbonyl Compounds / p37 (0024.jp2)
  33. 4-4 Alkylation of Aromatics Using Functional Ketones / p39 (0025.jp2)
  34. 4-5 Reaction mechanism / p40 (0025.jp2)
  35. 4-6 Effect of Silyl Compounds / p41 (0026.jp2)
  36. 4-7 Benzylation of Anisole Under Harogen Free Conditions / p42 (0026.jp2)
  37. 4-8 Plausible Mechanism / p43 (0027.jp2)
  38. 4-9 Experimental Section / p44 (0027.jp2)
  39. 4-10 References / p52 (0031.jp2)
  40. Chapter 5 Novel Synthetic Usage of Indium Compounds as Catalyst:Reductive Deoxygenation of Aryl Ketones and sec-Benzylie Alcohols / p54 (0032.jp2)
  41. 5-1 Introduction / p54 (0032.jp2)
  42. 5-2 Effect of Indium Catalyst / p55 (0033.jp2)
  43. 5-3 Deoxygenation of Aryl Ketones / p56 (0033.jp2)
  44. 5-4 Deoxygenation of sec-Aryl Alcohols / p57 (0034.jp2)
  45. 5-5 Reaction Mechanism / p58 (0034.jp2)
  46. 5-6 Experimental Section / p58 (0034.jp2)
  47. 5-7 References / p62 (0036.jp2)
  48. Conclusion / p64 (0037.jp2)
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  • NII論文ID(NAID)
    500000176215
  • NII著者ID(NRID)
    • 8000000176493
  • DOI(NDL)
  • 本文言語コード
    • und
  • NDL書誌ID
    • 000000340529
  • データ提供元
    • 機関リポジトリ
    • NDL ONLINE
    • NDLデジタルコレクション

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