Reaction and stereochemistry of spirocyclic pentacoordinate (10-P-5) and hexacoordinate (12-P-6) phosphorus compounds スピロ型5配位(10-P-5)および6配位(12-P-6)リン化合物の反応と立体化学
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著者
書誌事項
- タイトル
-
Reaction and stereochemistry of spirocyclic pentacoordinate (10-P-5) and hexacoordinate (12-P-6) phosphorus compounds
- タイトル別名
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スピロ型5配位(10-P-5)および6配位(12-P-6)リン化合物の反応と立体化学
- 著者名
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中本, 真晃
- 著者別名
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ナカモト, マサアキ
- 学位授与大学
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広島大学
- 取得学位
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博士 (理学)
- 学位授与番号
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甲第1965号
- 学位授与年月日
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1999-03-25
注記・抄録
博士論文
目次
- Contents / (0005.jp2)
- General Introduction / p1 (0007.jp2)
- References / p15 (0021.jp2)
- Chapter1 Stereomutation and Apicophilicity of Diastereomeric 10-P-5 Phosphoranes / p19 (0025.jp2)
- 1.1 Introduction / p20 (0026.jp2)
- 1.2 Synthesis and Determination of Stereochemistry / p22 (0028.jp2)
- 1.3 Kinetic Measurements / p26 (0032.jp2)
- 1.4 Discussion / p29 (0035.jp2)
- 1.5 Experimental / p32 (0038.jp2)
- 1.6 References / p42 (0048.jp2)
- Chapter2 Stereochemistry on Substitution Reaction Using Spirocyclic 10-P-5 Phosphoranes / (0050.jp2)
- 2.1 Introduction / p45 (0051.jp2)
- 2.2 Synthesis and Determination of Stereochemistry / p47 (0053.jp2)
- 2.3 Nucleophilic Substitution / p48 (0054.jp2)
- 2.4 Discussion / p51 (0057.jp2)
- 2.5 Experimental / p54 (0060.jp2)
- 2.6 References / p56 (0062.jp2)
- Chapter3 Stereospecific Pseudorotation of Diastereomeric 10-P-5 Phosphoranes with Anti-apicophilicity / p58 (0064.jp2)
- 3.1 Introduction / p59 (0065.jp2)
- 3.2 Synthesis of Diastereomeric C-Apical Phosphoranes / p60 (0066.jp2)
- 3.3 X-ray Analysis:Determination of Stereochemistry / p62 (0068.jp2)
- 3.4 Stereospecific Pseudorotation / p64 (0070.jp2)
- 3.5 Discussion / p67 (0073.jp2)
- 3.6 Experimental / p72 (0078.jp2)
- 3.7 References / p79 (0085.jp2)
- Chapter4 Structure and Reactivity of 12-P-6 Phosphate with a Novel Dioxaphosphirane Ring System / p81 (0087.jp2)
- 4.1 Introduction / p82 (0088.jp2)
- 4.2 X-ray Structure of 10-P-4 Phosphoranide / p83 (0089.jp2)
- 4.3 Reaction of 10-P-4 Phosphoranide with Molecular Oxygen / p86 (0092.jp2)
- 4.4 X-ray Structure of 12-P-6 Phosphate with a Dioxaphosphirane Ring / p87 (0093.jp2)
- 4.5 Possible Mechanism / p89 (0095.jp2)
- 4.6 Thermolysis and Reactivity / p91 (0097.jp2)
- 4.7 Diastereomeric Analog / p94 (0100.jp2)
- 4.8 Experimental / p96 (0102.jp2)
- 4.9 References / p100 (0106.jp2)
- Acknowledgment / p103 (0109.jp2)
- List of Publications / p104 (0110.jp2)