Construction of cyclic compounds using organozirconium complexes 有機ジルコニウム錯体を用いた環状化合物の構築
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著者
書誌事項
- タイトル
-
Construction of cyclic compounds using organozirconium complexes
- タイトル別名
-
有機ジルコニウム錯体を用いた環状化合物の構築
- 著者名
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劉, 元紅
- 著者別名
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リュウ, ユェンホン
- 学位授与大学
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北海道大学
- 取得学位
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博士 (薬学)
- 学位授与番号
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甲第5103号
- 学位授与年月日
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2000-03-24
注記・抄録
博士論文
目次
- Contents / (0003.jp2)
- Chapter 1.General Introduction to Organozirconium Chemistry and Its Use in the Preparation of Cyclic Compounds / p1 (0006.jp2)
- 1.1 Hydrozirconation of Alkenes or Alkynes / p2 (0007.jp2)
- 1.2 Zirconocene (II) Species in Organic Synthesis / p4 (0009.jp2)
- 1.3 The Synthetic Utilities of Zirconacycles in The Construction of Cyclized Compounds / p9 (0014.jp2)
- References and Notes / p16 (0021.jp2)
- Chapter 2.Formation of 4-Membered Carbocycles I: Reductive Elimination of α-Alkynyl Substituted Zirconacyclopentenes: Formation of Cyclobutene Derivatives / p20 (0025.jp2)
- Introduction / p21 (0026.jp2)
- Results and Discussion / p21 (0026.jp2)
- Experimental Section / p28 (0033.jp2)
- General Experimental Section / p28 (0033.jp2)
- References and Notes / p34 (0039.jp2)
- Chapter 3.Formation of 4-Membered Carbocycles II: Zirconocene-catalyzed Cyclobutene Formation by Reaction of Alkynyl Halides with EtMgBr / p36 (0041.jp2)
- Introduction / p37 (0042.jp2)
- Results and Discussion / p37 (0042.jp2)
- Experimental Section / p43 (0048.jp2)
- References and Notes / p46 (0051.jp2)
- Chapter 4.Formation of 5 and 6-Membered Carbocycles I: Inter-or Intramolecular Carbometallation of Nonactivated Alkynes by Zirconacycles in the Presence of Copper Chloride / p48 (0053.jp2)
- 4.1 Alkynylation of Zirconacycles in the Presence of CuCl / p49 (0054.jp2)
- 4.2 Inter-or Intramolecular Carbometallation of Nonactivated Alkynes by Zirconacyclopentanes or-pentenes / p53 (0058.jp2)
- Experimental Section / p62 (0067.jp2)
- References and Notes / p74 (0079.jp2)
- Chapter 5.Formation of 5 and 6-Membered Carbocycles II: Cycloaddition Reaction of Zirconacyclopentadienes to Alkynes: Formation of Benzene or Cyclopentadiene Derivatives by Different Reaction Pathways / p77 (0082.jp2)
- 5.1 Cycloaddition of Zirconacyclopentadienes to an Electron-deficient Alkynes:Formation of Benzene Derivatives / p78 (0083.jp2)
- 5.2 Mechanism of Cycloaddition Reaction of Zirconacyclopentadienes to Dimethyl Acetylenedicarboxylate / p79 (0084.jp2)
- 5.3 Cycloaddition of Zirconacyclopentadienes with Electron-deficient Alkynes: Formation of Cyclopentadiene Derivatives / p86 (0091.jp2)
- Experimental Section / p89 (0094.jp2)
- References and Notes / p96 (0101.jp2)
- Chapter 6.Formation of 6-Membered Carbocycles:Direct Michael Addition of Zircona-cyclopentanes and-pentenes to Activated Alkenes / p100 (0105.jp2)
- Introduction / p101 (0106.jp2)
- Results and Discussion / p101 (0106.jp2)
- Experimental Section / p111 (0116.jp2)
- References and Notes / p124 (0129.jp2)
- Chapter 7.Formation of 8-Membered Carbocycles: Novel and Stereocontrolled Synthesis of 8-Membered Carbocycles by Zirconacyclopentadienes / p126 (0131.jp2)
- Introduction / p127 (0132.jp2)
- Results and Discussion / p127 (0132.jp2)
- Experimental Section / p133 (0138.jp2)
- References and Notes / p136 (0141.jp2)
- Chapter 8.Zirconium Catalyzed C-C Bond Formation of Imines with EtMgBr / p139 (0144.jp2)
- Introduction / p140 (0145.jp2)
- Results and Discussion / p140 (0145.jp2)
- Experimental Section / p144 (0149.jp2)
- References and Notes / p146 (0151.jp2)
- List of Publications / p147 (0152.jp2)
- Acknowledgments / p150 (0155.jp2)
