Efficient carbon-carbon bond formation utilizing electrochemically generated reactive metals and by the use of electrochemical method 電解調製活性金属および電気化学的手法を用いる効率的炭素-炭素結合生成
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著者
書誌事項
- タイトル
-
Efficient carbon-carbon bond formation utilizing electrochemically generated reactive metals and by the use of electrochemical method
- タイトル別名
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電解調製活性金属および電気化学的手法を用いる効率的炭素-炭素結合生成
- 著者名
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黒野, 暢仁
- 著者別名
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クロノ, ノブヒト
- 学位授与大学
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北海道大学
- 取得学位
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博士 (工学)
- 学位授与番号
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甲第5109号
- 学位授与年月日
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2000-03-24
注記・抄録
博士論文
目次
- CONTENTS / (0003.jp2)
- Chapter 1 Introduction / p1 (0007.jp2)
- References / p5 (0011.jp2)
- Chapter 2 Preparation and Characterization of Electrogenerated Reactive Metals / p6 (0012.jp2)
- 2-1 Introduction / p7 (0013.jp2)
- 2-2 Electrogenerated Reactive Zinc(EGZn) / p9 (0015.jp2)
- 2-3 Electrogenerated Reactive Copper(EGCu)and Electrogenerated Zinc-Copper Couple (EGZn/EGCu,EGCu/EGZn) / p22 (0028.jp2)
- 2-4 Highly Reactive Electrogenerated Zinc (EGZn/Naph) / p36 (0042.jp2)
- Experimental Section / p46 (0052.jp2)
- References / p52 (0058.jp2)
- Chapter 3 Allylation and Propargylation by the Use of Electrogenerated Reactive Zinc(EGZn) or by Electrolysis Using a Zinc Anode / p53 (0059.jp2)
- 3-1 Introduction / p54 (0060.jp2)
- 3-2 Allylation by the Use of Electrogenerated Reactive Zinc (EGZn) / p56 (0062.jp2)
- 3-3 Propargylation by the Electrolysis Using a Zinc and Aluminum Anode / p65 (0071.jp2)
- Experimental Section / p76 (0082.jp2)
- References / p90 (0096.jp2)
- Chapter 4 Cross-coupling Reaction of Functionalized Alkyl Iodides with Aryl Halides by the Use of EGZn or by Electrolysis Using a Zinc Anode / p93 (0099.jp2)
- 4-1 Introduction / p94 (0100.jp2)
- 4-2 Cross-coupling Reaction of Functionalized Alkyl Iodides with Aryl Halides by the Use of EGZn / p96 (0102.jp2)
- 4-3 Cross-coupling Reaction of Functionalized Alkyl Iodides with Aryl Halides by the Electrolysis Using a Zinc Anode / p102 (0108.jp2)
- Experimental Section / p107 (0113.jp2)
- References / p117 (0123.jp2)
- Chapter 5 Use of Polyaromatics as a Mediator in the Electroorganic Synthesis. Facile Cross-coupling of Functionalized Alkyl Bromides with Aryl Halide and Facile Radical Cyclization / p118 (0124.jp2)
- 5-1 Introduction / p119 (0125.jp2)
- 5-2 Facile Cross-coupling of Functionalized Alkyl Bromides with Aryl Halides / p122 (0128.jp2)
- 5-3 Facile Radical Cyclization / p129 (0135.jp2)
- 5-4 Radical Cyclization / p131 (0137.jp2)
- 5-5 High Reactivity of EGZn/Naph / p145 (0151.jp2)
- Experimental Section / p147 (0153.jp2)
- References / p155 (0161.jp2)
- Chapter 6 Use of Water or Methanol Solvent in Electrochemical Allylation and Propargylation / (0162.jp2)
- 6-1 Introduction / p156 (0163.jp2)
- 6-2 Electrochemical Allylation and Propargylation in the Water / p159 (0166.jp2)
- 6-3 Electrochemical Allylation and Propargylation in Methanol / p171 (0178.jp2)
- Experimental Section / p183 (0190.jp2)
- References / p192 (0199.jp2)