Reaction Efficiency of Exciplexes in Singlet Sensitized Decomposition of Dibenzoyl Peroxide

• Hiroaki Misawa

  Department of Chemistry, University of Tsukuba

• Akihide Kitamura

  Department of Chemistry, University of Tsukuba

• Hirochika Sakuragi

  Department of Chemistry, University of Tsukuba

• Katsumi Tokumaru

  Department of Chemistry, University of Tsukuba

抄録

Quantum yields were measured for aromatic hydrocarbon-sensitized decomposition of dibenzoyl peroxide in benzene. For the sensitizers employed, naphthalene, phenanthrene, triphenylene, and chrysene, the ratio of the rate constants for decay and radical formation from intermediate exciplexes was found to be similar (0.2–0.4), indicating that the reactivity of the peroxide moiety in the intermediate is independent of the structural factors of the sensitizers as far as examined.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 57 (4), 1167-1168, 1984-04-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219102139136
• NII論文ID: 130001984657
• DOI: 10.1246/bcsj.57.1167
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/57/4/1167/55669609/bcsj.57.1167.pdf
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