Temperature dependence of the sticking probability and molecular size of the film growth species in an atmospheric chemical vapor deposition process to form AlN from AlCl3 and NH3
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- H. J. Kim
- Department of Chemical Engineering, Faculty of Engineering, The University of Tokyo Bunkyo-ku, Tokyo 113, Japan
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- Y. Egashira
- Department of Chemical Engineering, Faculty of Engineering, The University of Tokyo Bunkyo-ku, Tokyo 113, Japan
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- H. Komiyama
- Department of Chemical Engineering, Faculty of Engineering, The University of Tokyo Bunkyo-ku, Tokyo 113, Japan
抄録
<jats:p>The sticking probability and molecular size of the growth species were determined as a function of deposition temperature ranging from 700 to 950 °C, in the AlN films prepared from AlCl3 and NH3. A novel method was developed, that includes the measurement of the film thickness profile on micron-sized trenches and the molecular diffusivity of the growth species. The molecular size was about 1 nm at 700–850 °C and decreased gradually with increasing temperature. The sticking probability increased from 0.02 to 0.5 in the temperature range 700–950 °C and, surprisingly, obeyed the Arrhenius law in spite of this large probability of sticking. The activation energy amounted to 136 kJ/mol.</jats:p>
収録刊行物
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- Applied Physics Letters
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Applied Physics Letters 59 (20), 2521-2523, 1991-11-11
AIP Publishing
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詳細情報 詳細情報について
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- CRID
- 1363670319185299328
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- NII論文ID
- 80006190128
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- DOI
- 10.1063/1.106406
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- ISSN
- 10773118
- 00036951
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- データソース種別
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