Simultaneous Spectrophotometric Determination of Uranium and Thorium by Flow Injection Analysis Using Selective Masking.

DOI PDF Web Site Web Site Web Site ほか1件をすべて表示 一部だけ表示 被引用文献1件 参考文献31件
  • HIRANO Yoshihiro
    Department of Materials Technology, Faculty of Engineering, Chiba University
  • OGAWA Yuichi
    Department of Materials Technology, Faculty of Engineering, Chiba University
  • OGUMA Koichi
    Department of Materials Technology, Faculty of Engineering, Chiba University

この論文をさがす

抄録

A flow injection system for the simultaneous determination of uranium and thorium has been developed by using selective masking and a spectrophotometric detector with two flow cells aligned with the same optical path. The injected sample solution was first mixed with a reagent solution containing Chromazurol S (CAS) and cetyltrimethylammonium chloride (CTMAC), and the total absorbance of uranium- and thorium-CAS complexes was measured in the first flow cell at 620 nm. The sample stream was then mixed with an EDTA solution in order to convert the thorium-CAS complex to a thorium-EDTA complex, and the absorbance of the uranium-CAS complex was measured in the second flow cell. The detection limits were 10 μg dm-3 for uranium and 7 μg dm-3 for thorium. The calibration graphs were linear (r < 0.9998) at least over the ranges of 0.1 to 10 mg dm-3 for uranium and 0.08 to 8 mg dm-3 for thorium. The RSDs were less than 1.5% (n = 3) in the calibration range. Uranium and thorium of up to the 6-fold concentration to each other could be determined in admixtures with relative errors of less than 3.3%. The sample throughput was 24 per hour. The proposed system was successfully applied to the analysis of a uranium-thorium ore mock solution by coupling with anion-exchange in a magnesium nitrate medium to eliminate interference from coexisting elements.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 19 (2), 303-307, 2003

    社団法人 日本分析化学会

被引用文献 (1)*注記

もっと見る

参考文献 (31)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ