Effect of La substitution on Electrical Properties of Highly Oriented Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub>Films Prepared by Metalorganic Chemical Vapor Deposition
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- Sakai Tomohiro
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology G1-405
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- Watanabe Takayuki
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology G1-405
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- Funakubo Hiroshi
- Department of Innovative and Engineered Materials, Tokyo Institute of Technology G1-405
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- Saito Keisuke
- Application Laboratory, Analytical Department, Philips Japan, Ltd.
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- Osada Minoru
- PRESTO, Japan Science and Technology Corporation (JST)
書誌事項
- タイトル別名
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- Effect of La substitution on Electrical Properties of Highly Oriented Bi4Ti3O12 Films Prepared by Metalorganic Chemical Vapor Deposition.
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The effect of La substitution on the electrical properties of Bi4Ti3O12 was investigated by using epitaxially grown Bi4Ti3O12 (BIT) films and highly oriented (Bi3.25La0.75)Ti3O12 [BLT] films with (001)-, (118)- and (104)(014)-orientations. By characterizing the leakage current density for films with different orientations, it was found that the leakage current density along the a–b plane was decreased by La substitution. The spontaneous polarization (Ps) of the BLT film evaluated from the P–E hysteresis properties of the (001)- and (118)-oriented films was 3.5 and 38 μC/cm2 along the c-axis and the a-axis, respectively. They were smaller than those of the BIT films: 4.0 and 50 μC/cm2. Based on the fact that La preferentially substitutes for the Bi site in the pseudoperovskite layer, the large remanent polarization widely reported for polycrystalline (Bi3.25La0.75)Ti3O12 films is related to the reduction of the number of defect complexes in the pseudoperovskite layer that possibly pin the domain motion.
収録刊行物
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- Japanese Journal of Applied Physics
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Japanese Journal of Applied Physics 42 (1), 166-169, 2003
The Japan Society of Applied Physics
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詳細情報 詳細情報について
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- CRID
- 1390282681233003392
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- NII論文ID
- 80015859063
- 130004764367
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- NII書誌ID
- AA10457675
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- ISSN
- 13474065
- 00214922
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- NDL書誌ID
- 6441050
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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