General considerations and reactions at coventional rates
著者
書誌事項
General considerations and reactions at coventional rates
（Techniques of chemistry, v. 6 . Investigation of rates and mechanisms of reactions ; pt. 1）
Wiley, c1986
4th ed. / edited by Claude F. Bernasconi
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注記
"A Wiley-Interscience publication."
Includes bibliographical references and index
内容説明・目次
内容説明
For over 25 years, Investigation of Rates and Mechanisms of Reactions has been a preeminent source of guidance for research chemists, biochemists, and advanced students engaged in this active area of chemical research. Previous editions have introduced significant methods that have contributed to our understanding of chemical transformations at the molecular level. Now, the 4th Edition of this reference work provides an updated review of current kinetic and non-kinetic methods for investigating reaction mechanisms. Part I of this two-part series deals with general considerations and theoretical aspects of mechanistic studies and with experimental techniques suitable for the study of reactions occurring at conventional rates. 16 chapters contributed by internationally recognized authorities cover a wide range of topics, including kinetics in solution, kinetics in the gas phase, kinetics in heterogeneous systems, transition state theory, kinetic isotope effects, catalysis by small molecules and enzymes, kinetics of complex reactions, linear free energy relationships, and non-kinetic methods such as stereo-chemical studies and the use of tracers and computers.
目次
- GENERAL CONSIDERATIONS AND REACTIONS AT CONVENTIONAL RATES: Introduction
- Transition State Theory
- Homogeneous Gas Phase Reactions
- Kinetics in Solution
- From Kinetic Data to Reaction Mechanism
- Kinetics and Mechanisms of Complex Reactions
- Reversible and Other Complex Reactions: A Simple Relaxation Kinetics Approach
- Homogeneous Inorganic Reactions
- Kinetic Isotope Effects
- Tracer Methods
- Stereochemistry and Reaction Mechanism
- Catalysis by Small Molecules in Homogeneous Solution
- Enzyme Kinetics as a Tool for Determination of Enzyme Mechanisms
- Linear Free Energy Relationships
- Ion Cyclotron Resonance and Fourier-Transform Mass Spectrometry
- Mechanism in Heterogeneous Catalysis
- Use of Computers
- INVESTIGATION OF ELEMENTARY REACTION STEPS IN SOLUTION AND FAST REACTION TECHNIQUES: Introduction
- Rapid Flow Methods
- Theoretical Basis of Chemical Relaxation
- Temperature-Jump Methods
- Pressure-Jump Methods
- Electric Field Methods
- Ultrasonic Methods
- Electrochemical Reactions
- Flash and Laser Photolysis
- Pulse Radiolysis
- Nuclear Magnetic Resonance Line- Shape Analysis of Reorganizing Systems
- Electron Paramagnetic Resonance.
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