Stereochemical applications of NMR studies in rigid bicyclic systems

書誌事項

Stereochemical applications of NMR studies in rigid bicyclic systems

by Alan P. Marchand

(Methods in stereochemical analysis, v. 1)

Verlag Chemie International , Verlag Chemie, c1982

  • : us
  • : gw

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注記

Bibliography: p. 207-217

Includes indexes

内容説明・目次

内容説明

This monograph presents extensive tabulations of NMR chemical shifts, coupling constants, and correlations for rigid bicyclic systems related to bicyclo[2.2.1]heptane ("norbornane") and bicyclo[2.2.2]octane. These systems are useful because they are relatively fixed and allow accurate estimation of internuclear distances and bond angles. Thus, they serve as model systems for the estimation of steric and electronic substituent effects on NMR chemical shifts and coupling constants in non-rigid systems. No similar treatment of NMR data of rigid bicyclic systems has ever appeared before.

目次

  • Introduction
  • Aids to Making NMR Spectral Assignments in Rigid Bicyclic Systems
  • Stereochemical Applications of NMR Chemical Shifts in Rigid Bicyclic Systems
  • Stereochemical Applications on NMR Spin-Spin Coupling Constants in Rigid Bicyclic Systems.

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