Spectroscopy with polarized light : solute alignment by photoselection, in liquid crystals, polymers, and membranes
著者
書誌事項
Spectroscopy with polarized light : solute alignment by photoselection, in liquid crystals, polymers, and membranes
VCH, c1986
- us
- gw
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注記
Includes bibliographies and indexes
内容説明・目次
内容説明
This is the first book on polarized spectroscopy of partially oriented solutes. The purpose is to provide an introduction to those interested in the measurement of the anisotropy of molecular optical properties in the UV, visible or IR regions (one-and two-photon absorption, simultaneous or sequential, luminescence, Raman scattering, natural and magnetic optical activity), or in the determination of uniaxial order and organization in supermolecular assemblies (liquid crystals, stretched polymers and membranes). The orienting effects of radiation (photoselection) are covered as well. The book illustrates in numerous examples the use of the results to solve problems in chemistry, biology, and polymer science. It is written on a level for graduate students who have been exposed to elementary quantum mechanics, optics, and spectroscopy. The preface indicates sections to be skipped by a nonspecialist seeking primarily practical information for a specific application.
目次
- Introduction and Theoretical Background
- Transition Moments
- Techniques of Alignment and Measurement
- Quantitative Aspects of Uniaxial Alignment
- Processes of Rank Two
- Processes Reducible to Rank Two
- Processes of Rank Four
- Examples of Application
- Appendix I_Molecular Symmetry and Elementary Group Theory
- Appendix II_Cartesian Tensors and Polarized Intensities
- Appendix III_Mueller-Stokes Formalism for Description of the Interaction Between Polarized Light and Anisotropic Samples
- Subject Index
- Compound Index.
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