Metals speciation, separation, and recovery

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Bibliographic Information

Metals speciation, separation, and recovery

edited by James W. Patterson, Roberto Passino

Lewis Publishers, 1987-

  • [v. 1]
  • v. 2

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Note

[v. 1]: Proceedings of the International Symposium on Metals Speciation, Separation, and Recovery, held in Chicago, Ill. on July 27-Aug. 1, 1986, sponsored by the Industrial Waste Elimination Research Center of the Illinois Institute of Technology and the Water Research Institute of the National Research Council of Italy

v. 2: Proceedings of the Second International Symposium on Metals Speciation, Separation, and Recovery, Rome, Italy, May 14-19, 1989; sponsored by Water Research Institute, Italian National Research Council, and Industrial Waste Elimination Research Center, Illinois Institute of Technology

Includes index

Description and Table of Contents

Volume

[v. 1] ISBN 9780873710343

Description

This comprehensive book covers metals chemistry, separation chemistry, and metals separation processes. State-of-the-art papers give new and recent developments and future research needs.

Table of Contents

KEYNOTE PAPERS. Changes in Metal Mobilities in Aquatic and Terrestrial Cycles. General Affinity Concepts, Equilibria, and Kinetics in Aqueous Metals Chemistry. Metals Separation and Recovery. SECTION I: CRYSTALLIZATION AND PRECIPITATION PHENOMENA. Kinetics of Precipitation and Dissolution of Ferrous Carbonate. Use of Thiourea and Thioacetamide for Separation and Recovery of Heavy Metals from Mineral Treatment Waste Waters. The Effect of Citrate, a Weak Chelating Agent, on the Removal of Heavy Metals by Sulfide Precipitation. The Kinetics and Yield of the Magnesium Cementation of Cadmium. SECTION II: METALS SPECIATION: MODELS AND METHODS. Current Status of Metal Speciation Studies. Electroanalysis of Heavy Metal/Organic Matter Systems. High Pressure Liquid Chromatography with Element Specific Detectors for the Speciation of Inorganic and Organometallic Compounds. SECTION III: MEMBRANE AND BIOLOGICAL PROCESSES. Liquid Membranes for Metal Ion Removal from Aqueous Media-An Overview. Algal Sorbents for Selective Metal Ion Recovery. Fungal Biosorption: A Comparative Study of Metal Uptake by Penicillium and Cladosporium. SECTION IV: METALS SPECIATION: LIGAND DESIGN AND KINETIC CONTROLS. The Selective Extraction of Pd(II) and Ag(I) by Substituted Formazans. Kinetics of Cadmium and Copper Complexation. Ion Exchange Kinetics in Selective Systems. SECTION V: SORPTION ON SURFACE OXIDES. Chemical Interactions Between Heavy Metal Ions and Hydrous Solids. Mechanisms of Metal Ion Adsorption on Activated Alumina. Adsorption of Inorganic Arsenic and Organoarsenical on Hydrous Oxides. SECTION VI: ION EXCHANGE SEPARATIONS. Synthesis of Dual Mechanism Ion Exchange/Redox Resins and Ion Exchange/Coordination Resins with Application to Metal Ion Separations. The Separation of Precious Metals by Polymers Functionalized with Dehydrodithizone Derivatives. Cation Exchange Removal of Heavy Metals with a Recoverable Chelate Regenerant. SECTION VII: METALS RECOVERY APPLICATIONS PROCESS RESEARCH. Development of an Ion Exchange Process to Recover Cobalt and Nickel from Primary Lead Smelter Residues. Purifying Plating Baths by Chelate Ion Exchange. A Continuous Electrolytic Process for the Recovery of Copper from Spent LT CO Shift Catalyst. Heavy Metals Removal: Pilot Scale Research on the Advanced MEXICO Precipitation Process. SECTION VIII: METALS RECOVERY APPLICATIONS: CASE STUDIES. Economic Feasibility of a State-Wide Hydrometallurgical Recovery Facility. Recovery of Aluminum as Aluminum Sulfate from Aluminum Anodizing Sludge. Studies of the Uptake of Heavy Metals by Activated Sludge. INDEX. 779 pp., 1987, ISBN 0-87371-034-7.
Volume

v. 2 ISBN 9780873712682

Description

By and for engineers and scientists, this comprehensive book covers all aspects of metals chemistry, separation chemistry, and metals separation processes. State-of-the-art papers give news and recent developments and future research needs, of special value and interest to persons from industry, academia, government agencies, commercial and research institutes, information centers and libraries. This valuable work is the complete proceedings of the Metals Speciation, Separation and Recovery International Symposium sponsored by the Industrial Waste Elimination Research Center at the Illinois Institute of Technology, Chicago, Illinois, and the Water Research Institute of the Italian National Research Council, Rome, Italy, held in Rome, May 14-19, 1989. The book will be about 800 pages replete with drawings, tables, and charts helpful to understanding and use of the information presented. Written by some 50 specialists from leading institutions and companies from Europe, Asia, North and Latin America, choice information and data in this valuable new volume are organized into seven major parts: One: Chemistry of Toxic Metals; Two: Precipitation Phenomena; Three: Metal Speciations and Complexation in Natural Systems; Four: Sorption Onto Surfaces; Five: Ion Separation; Six: Soils Contamination and Decontamination; Seven: Waste Reduction and Recovery Case Studies. Index.

Table of Contents

  • KEYNOTE PAPERS. Cycles, Fluxes and Speciation of Trace Metals in the Environment. Metals Control Technology
  • Past, Present, and Future. PART I: CHEMISTRY OF TOXIC METALS. METALS SPECIATION IN SLUDGES FROM WASTEWATERS TREATMENT BY BULK AND SURFACE (XPS) ANALYSIS. Abstract. Introduction. X-Ray Photoelectron Spectroscopy. Samples Treatment and Experimental Techniques. Results and Discussion. Conclusions. Acknowledgments. References. Discussion. CHEMICAL EQUILIBRIUM ANALYSIS OF LEAD AND BERYLLIUM SPECIATION IN HAZARDOUS WASTE INCINERATORS. Introduction. Metal Transformations in Incineration Systems. Metals Emissions from Incinerators. Modeling Approach. Model Simulations and Analysis. Conclusions. References. Discussion. NUCLEATION AND CRYSTAL GROWTH STUDIES ON PRECIPITATION OF CADMIUM HYDROXIDE FROM AQUEOUS SOLUTIONS. Abstract. Introduction. Background. Experimental. Results and Discussion. Conclusions. Acknowledgments. References. Discussion. EFFECT OF SPECIATION ON THE RATES OF OXIDATION OF METALS. Introduction. Background. Effect of pH on the Rates of Oxidation. Effect of the Major Ionic Components of Natural Waters on the Rates of Oxidation. Acknowledgments. References. Discussion. PART II: PRECIPITATION PHENOMENA. EXPERIMENTS ON THE SIMULTANEOUS OXIDIZING EXTRACTION PROCESS OF Fe(II). Summary. Introduction. Experimental Methods. Experimental Results and Discussion. Symbols. References. Discussion. HYDROLYSIS, PRECIPITATION AND AGING OF COPPER (II) IN THE PRESENCE OF NITRATE. Introduction. Background. Experimental. Results and Discussion. Summary and Conclusions. Acknowledgments. References. Discussion. ROLE OF COPPER COMPLEXATION ON TREATMENT EFFICIENCY AND DESIGN OF TWO INDUSTRIAL WASTESTREAMS. Abstract. Introduction. Some Theoretical Considerations. Results and Discussion. Conclusions. References. Discussion. PART III: METAL SPECIATION AND COMPLEXATION IN NATURAL SYSTEMS. SPECIATION OF ALUMINUM IN GEOTHERMAL BRINES: COMPARISON OF DIFFERENT METHODOLOGIES. Summary. Introduction. Experimental. Results and Discussion. Conclusions. References. Discussion. SPECIATION OF TIN IN SEDIMENTS OF ARCACHON BAY (FRANCE). Introduction. Material and Methods. Results and Discussion. Conclusions. References. Discussion. METAL COMPLEXATION BY WATER-SOLUBLE ORGANIC SUBSTANCES IN FOREST SOILS. Abstract. Introduction. Metal-Complexing Capacity of Leaf-Litter Leachates. Metal-Solubilization from Forest Soils by the Litter Leachates. Discussion. Acknowledgments. References. Discussion. THEORETICAL AND EXPERIMENTAL DRAWBACKS IN HEAVY METAL SPECIATION IN NATURAL WATERS. Introduction. The Biological Problem. The Chemical Problem. Conclusions. Acknowledgments. References. Discussion. PART IV: SORPTION ONTO SURFACES. PROTON AND METAL ION BINDING ON HUMIC SUBSTANCES. Abstract. Introduction. The Mono-Component Proton Adsorption Isotherm. Calculation of Qi,H(pH5) Curves from Experimental Proton Adsorption Data for Humic and Fulvic Acids. Metal-Ion Adsorption. Conclusions. Acknowledgments. References. Discussion. POLYELECTROLYTIC METAL IONS SEQUESTRANTS. Introduction. Results and Discussion. Concluding Remarks. Experimental. Acknowledgments. References. Discussion. CHEMICAL SPECIATION OF HEAVY METALS IN SOILS FOLLOWING LAND APPLICATION OF CONDITIONED BIOLOGICAL SLUDGES AND RAW PIG MANURE. Introduction. Preliminary Investigation. Heavy Metals in Agricultural Soil. Materials and Methods. Results and Discussion. Conclusions. References. Discussion. PART V: ION SEPARATION. A PROCESS TO IMPROVE THE REGENERATED EFFLUENT CONCENTRATION OF ION EXCHANGE. Introduction. Background. Limit Regenerated Effluent Concentration Theory. Step-by-Step Regeneration Process. Experimental Results. Conclusions. Acknowledgments. References. Discussion. HEAVY METAL REMOVAL USING NATURAL ZEOLITE. Introduction. Theoretical Aspects of the Ion Exchange Process. Experimental Procedure. Results. Discussion. Concluding Remarks. References. Discussion. METAL ION SEPARATIONS FROM HAZARDOUS WASTE STREAMS BY IMPREGNATED CERAMIC MEMBRANES. Abstract. Introduction. Coupled Transport of Metal Ions in Ceramic Membranes. Experimental Apparatus and Technique. Preliminary Results. Conclusion and Future Work. Acknowledgments. Notation. References. Discussion. PART VI: SOILS CONTAMINATION AND DECONTAMINATION. PARTITIONING OF HEAVY METALS INTO SELECTIVE CHEMICAL FRACTIONS IN SEDIMENTS FROM RIVERS IN NORTHERN GREECE. Abstract. Introduction. Materials and Methods. Results and Discussion. Conclusions. References. Discussion. CHEMICAL DECONTAMINATION OF DREDGED MATERIALS, SLUDGES, COMBUSTION RESIDUES, SOILS, AND OTHER MATERIALS CONTAMINATED WITH HEAVY METALS. Introduction. Treatment Techniques. Chemical Decontamination: A Concept for the Final Disposal of Materials Contaminated with Heavy Metals. Advantages of Chemical Decontamination-Practical Realization. References. Discussion. RESULTS OF BENCH-SCALE RESEARCH EFFORTS TO WASH CONTAMINATED SOILS AT BATTERY-RECYCLING FACILITIES. Introduction and Background. Summary of Findings. Site Profiles. Soil Characterization. Experimental Soil-Washing Procedures. Results and Discussion. Conclusions. Acknowledgments. Discussion. PART VII: WASTE REDUCTION AND RECOVERY CASE STUDIES. THREE CASE STUDIES OF WASTE MINIMIZATION THROUGH USE OF METAL RECOVERY PROCESSES. Introduction. Background. Case Study No. 1. Materials Balance. Economic Analysis. Conclusions. Case Study No. 2. Case Study No. 3. References. Discussion. METRO RECOVERY SYSTEMS-A CENTRALIZED METALS RECOVERY AND TREATMENT FACILITY IN TWIN CITIES, U.S. Introduction. Project Evaluations. The Central Treatment and Recovery Facility. Summary and Conclusions. Acknowledgments. References. Discussion. RECOVERY OF METALS FROM WASTE STREAMS BY HYDROMETALLURGICAL PROCESSES. Summary. Introduction. Metal Recovery by Hydrometallurgical Techniques. Recovery of Metals from Spent Hydrodesulphurizing Catalyst. Recovery of Metals from Spent Batteries. Conclusions. References. Discussion. CHROMIUM RECOVERY FROM TANNERY SLUDGE BY INCINERATION AND ACID EXTRACTION. Introduction. Definition of Objectives. Experimental. Experimental Results. Conclusions. References. Discussion. RESEARCH NEEDS WORKSHOP: RESEARCH NEEDS IN METALS SPECIATION, SEPARATION, AND RECOVERY. Group A: Analysis and Speciation Chemistry. Group B: Solid-Liquid Interface Chemistry. Group C: Selective Separation Technology. Group D: Metal Sludges Management. References. Index.

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