Higher excited states of polyatomic molecules

著者

• Robin, Melvin B.

書誌事項

Higher excited states of polyatomic molecules

Melvin B. Robin

Academic Press, 1974-1985

• v. 1
• v. 2
• v. 3

注記

Bibliography: v. 1, p. 320-348; v. 2, p. 347-390

Includes indexes

内容説明・目次

巻冊次

v. 1 ISBN 9780125899017

内容説明

Higher Excited States of Polyatomic Molecules, Volume I focuses on the spectra in the vacuum-ultraviolet region between 50,000 and 100,000 cm-1. This book explores the higher excitations in molecules beyond 50,000 cm-1. Organized into three chapters, this volume starts with an overview of the excited-state properties of a molecule and the excited-state ionization potential. This book then proceeds with a discussion of the original classification of the properties as well as the types of excitations observed in the vacuum-ultraviolet. Other chapters discuss photoelectron spectroscopy, which is an independent, self-sustaining branch of molecular spectroscopy. This text examines as well the distinction between valence shell and Rydberg excitations. The final chapter deals with several topics, including the saturated molecules that are classified as having all valence electrons, the alkene absorption spectra, and the spectroscopic data on boron compounds. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.

目次

Foreword PrefaceAcknowledgments Contents of Volume IIIntroductionChapter I Theoretical Aspects I.A. Classification of Molecular Transitions and Their Properties I.A-1. Rydberg States in Atoms and Molecules I.A-2. Antiresonances I.A-3. Plasmons and Collective Excitations I.B. Excited-State Calculations I.B-1. Rydberg-State Calculations I.B-2. Valence-Shell-State Calculations I.C. Rydberg Spectra I.C-1. Observation of Trends in Rydberg Spectra I.C-2. Calculation of Rydberg Trends in Molecular Spectra Chapter II Experimental Technique II.A. Photoelectron Spectroscopy II.B. High-Pressure Effects on Ultraviolet Spectra II.C . Vacuum-Ultraviolet Spectra in Condensed Phases II.D. Electron-Impact Spectroscopy II.E. Instrumentation II.E-1. Light Sources II.E-2. Solvents II.E-3. Absorption Cells II.E-4. Frequency Shifters II.E-5. Polarizers II.E-6. Optical Spectrometers Chapter III Saturated Absorbers III.A. The Alkanes III.A-1. Methane and the Methyl Radical III.A-2. Ethane III.A-3. Propane and the Higher Acyclic Alkanes III.A-4. Simple Rings and Polycyclic Alkanes III.A-5. Postscript to the Alkane Spectra III.B. The Alkyl Halides III.B-1. Alkyl Monochlorides, Bromides, and Iodides III.B-2. Di-, Tri-, and Tetrachloro-, Bromo-, and Iodoalkanes III.B-3 . Fluoroalkanes III.C. Boron Compounds III.C-1. Boron Hydrides and Halides III.C-2. Boron-Nitrogen Compounds III.D. Group V Systems III.D-1. Amines III.D-2. Compounds of Phosphorus, Arsenic, and Antimony III.E. Oxo Compounds III.E-1. Water III.E-2. Alcohols III.E-3. Ethers III.F. Compounds of Sulfur, Selenium, and Tellurium III.G. Silanes, Germanes, and Stannanes Appendix Rydberg Term TableReferencesIndex

巻冊次

v. 2 ISBN 9780125899024

内容説明

Higher Excited States of Polyatomic Molecules, Volume II focuses on a higher level of activity in vacuum ultraviolet spectroscopy. This book explores the Rydberg states in atoms and molecules. Comprised of five chapters, this volume starts with an overview of the two-center unsaturated molecules that usually display sharp Rydberg transitions originating with the pi electrons. This book then discusses the unsaturated double bond that adds another dimension to the spectrum. Other chapters explore the optical spectrum of the amide group, which is the basic chromophoric unit in polypeptides. This text further discusses the all-electron calculations of the electronic structure of the amide group that is performed in Gaussian orbital basis sets. This book considers as well the prominent characteristic of Rydberg excitations in benzene. The final chapter deals with the biological molecules that are polyfunctional in general. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.

目次

Preface to Volume II Acknowledgments Contents of Volume I Chapter IV Two-Center Unsaturates IV.A. Olefins IV.A-1. Ethylene IV.A-2. Alkyl Olefins IV.A-3. Haloethylenes IV.B. Azo and Imine Compounds IV.C. Aldehydes and Ketones IV.D. Acetylenes IV.E. Nitriles Chapter V Nonaromatic Unsaturates V.A. Amides, Acids, Esters, and Acyl Halides V.A-1. Amides V.A-2. Polymeric Amides V.A-3. Acids, Esters, and Acyl Halides V.B. Oxides of Nitrogen V.C. Dienes and Higher Polyenes V.C-1. Dienes V.C-2. Heterocyclic Dienes V.C-3. Higher Polyenes V.D. The CumulenesChapter VI Aromatic Compounds VI.A. Phenyl Compounds VI.A-1. Benzene VI.A-2. Alkyl Benzenes VI.A-3. Halobenzenes VI.A-4. Azabenzenes VI.A-5. Substituent Effects in Benzene VI.B. Higher Aromatics Chapter VII Inorganic Systems VII.A. Nonmetals VII.B. Metals Chapter VIII Biochemical Systems Addendum References Index

巻冊次

v. 3 ISBN 9780125899031

内容説明

Higher Excited States of Polyatomic Molecules, Volume III focuses on higher electronic excitations in polyatomic molecules, with emphasis on excitations beyond 50,000 cm-1. This book explores the various transitions on the basis of their orbital characteristics. Organized into 22 chapters, this volume begins with an overview of the relationships between spectra of different molecules and between the results of various types of spectroscopy. This book then discusses the higher excited states involving Rydberg excitation. Other chapters explore the higher excited states in all classes of biological, organic, and inorganic molecules. This text further discusses the progress in the area of higher excitations in polyatomic atoms and the technique of multiphoton ionization (MPI) spectroscopy that yields a remarkable amount of spectroscopic information applicable to the vacuum-ultraviolet region. The final chapter deals with the vacuum-ultraviolet spectroscopy of biological materials. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.

目次

• Preface Acknowledgments Chapter I. A Catalog of Orbitals and Excitations in Polyatomic Molecules IA. Definitions IB. Inner-Shell and Outer-Shell Rydberg Excitations Splitting of Hydrogenic Rydberg Levels Term Values and Antishielding Rydberg States in Ions Rydberg Intensities IC. Inner-Shell and Outer-Shell Valence Excitations A-Band Definitions A-Band Term Values I.D. Rydberg/Valence Conjugates
• Existence, Mixing and Ordering Coexistence of Rydberg/Valence Conjugates Conjugate and Nonconjugate Mixing Valence Miscibility with the Rydberg Sea Mixing Effects and Unmixing Wave Function Collapse and Giant Resonances Rydberg/Valence Ordering I.E. Addendum Chapter II. New Sources of Spectral Information II.A. Multiphoton Ionization Spectroscopy II.B. Temporary-Negative-Ion Resonances Valence TNI Resonances Feshbach Resonances II.C. Discrete Features in the Ionization Continuum Shake-up Transitions Shape Resonances Two-Electron Excitations Photoionization Cross-Section Maxima and Minima II.D. Vacuum-Ultraviolet Excitations in Dense Phases High-Pressure Gases and Fluid Solutions Solid Solutions and Pure Crystals Plasmons and Collective-Electron Behavior II.E. Addendum Chapter III. Alkanes III.A. Methane and its Fragments III.B. Ethane III.C. Acyclic Alkanes III.D. The Longer Alkanes, Polyethylene and Diamond IIII.E. Cyclic Alkanes Chapter IV. Alkyl Halides IV.A. Alkyl Chlorides IV.B. Alkyl Bromides IV.C. Alkyl Iodides IV.D. Alkyl Fluorides IV.E. Fluoroalkyl Halides IV.F. Addendum Chapter V. Boron Compounds V.A. Boron Hydrides V.B. Boron-Nitrogen Compounds V.C. Boron Halides V.D. Addendum Chapter VI. Amines, Phosphines, Arsine VI.A. Ammonia and Amine Derivatives VI.B. Phosphines and Arsine VI.C. Addendum Chapter VII. Oxo Compounds VII.A. Water and Hydrogen Peroxide Water Vapor Ice Liquid Water Hydrogen Peroxide VII.B. Alcohols VII.C. Ethers VII.D. Addendum Chapter VIII. Compounds of Sulfur, Selenium and Tellurium VIII.A. Hydrogen Sulfide and Hydrogen Selenide VIII.B. Sulfide Derivatives Alkyl Sulfides Sulfur Hexafluoride VIII.C. Addendum Chapter IX. Silanes, Germanes and Stannanes IX.A. Parent Compounds and Alkyl Derivatives IX.B. Halides IX.C. Addendum Chapter X. Olefins X.A. Ethylene X.B. Alkyl Olefins X.C. Haloethylenes X.D. Addendum Chapter XI Azo, Imine and Oxime Compounds XI.A. Azo Compounds XI.B. Imines and Oximes Chapter XII. Aldehydes and Ketones XII.A. Formaldehyde XII.B. Alkyl and Halogen Derivatives XII.C. Thio Derivatives XII.D. Conjugated Aldehydes and Ketones
• Diones and Vinyl Ketones XII.E. Addendum Chapter XIII. Acetylenic Compounds XIII.A. Acetylene and Derivatives Acetylene and Alkyl Derivatives Halo Acetylenes XIII.B. Polyacetylenes and Derivatives XIII.C. Addendum Chapter XIV. Nitriles Chapter XV. Amides, Acids, Esters and Acyl Halides XV.A. Amides XV.B. Acids and Esters XV.C. Acyl Halides Chapter XVI. Oxides of Nitrogen Chapter XVII. Dienes and Higher Polyenes XVII.A. Butadiene XVII.B. Alkyl Dienes XVII.C. Nonconjugated Dienes and Polyenes XVII.D. Heterocyclic Dienes XVII.E. Higher Conjugated Polyenes XVII.F. Addendum Chapter XVIII. Cumulenes XVIII.A. Aliene and Ketene XVIII.B. Addendum Chapter XIX. Phenyl Compounds XIX.A. Benzene XIX.B. Alkyl Benzenes XIX.C. Halobenzenes XIX.D. Azabenzenes XIX.E. Other Phenyl Compounds XIX.F. AddendumChapter XX. Higher Aromatics Chapter XXI. Inorganic Systems XXI.A. Halides XXI.B. Oxides XXI.C. Miscellaneous XXI.D. Addendum Chapter XXII. Biological Molecules References Index

「Nielsen BookData」 より

詳細情報

• NII書誌ID(NCID): BA01419516
• ISBN:
  • 0125899017
  • 0125899025
  • 0125899033
• LCCN: 73009446
• 出版国コード: us
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: New York
• ページ数/冊数: 3 v.
• 大きさ: 24 cm
• 分類:
  • LCC : QC454.M6
  • DC19 : 541.2/8
  • NDC8 : 428.1
• 件名:
  • LCSH : Molecular spectroscopy
  • LCSH : Spectrum, Ultraviolet
  • LCSH : Electronic excitation