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v. 67 ISBN 9780470041451
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world-renowned experts with extensive hands-on experience in the field. The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions.
目次
1. CATALYTIC ENANTIOSELECTIVE ALDOL ADDITION REACTIONS (Erick M. Carreira, Alec Fettes, and Christiane Marti). 2. BENZYLIC ACTIVATION AND STEREOCHEMICAL CONTROL IN REACTIONS OF TRICARBONYL(ARENE)CHROMIUM COMPLEXES (Motokazu Uemura).
CUMULATIVE CHAPTER TITLES BY VOLUME.
AUTHOR INDEX, VOLUMES 1-67.
CHAPTER AND TOPIC INDEX, VOLUMES 1-67.
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v. 68 ISBN 9780470098981
内容説明
Organic Reactions is a collection of chapters, each devoted to a single reaction or a definitive phase of a reaction of wide applicability, with particular attention given to limitations, interfering influences, effects of structure, and the selection of experimental techniques.
Volume 68 includes two chapters on important reactions: Chapter 1 on Contrimerizations of Acetylenic Compounds by Max Malacria, and Chapter 2 on Glycosylation on Polymer Supports by Peter Seeberger
Includes tables that contain all possible examples of the reactions under consideration
Each reaction is fully referenced to the primary literature
目次
1. COTRIMERIZATIONS OF ACETYLENIC COMPOUNDS (Nicolas Agenet, Olivier Buisine, Franck Slowinski, Vincent Gandon, Corinne Aubert, and Max Malacria) 2. GLYCOSYLATION ON POLYMER SUPPORTS (Simone Bufali and Peter H. Seeberger).
CUMULATIVE CHAPTER TITLES BY VOLUME .
AUTHOR INDEX, VOLUMES 1-68 .
CHAPTER AND TOPIC INDEX, VOLUMES 1-68 .
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v. 71 ISBN 9780470098998
内容説明
Organic Reactions is a collection of chapters, each devoted to a single reaction or a definitive phase of a reaction of wide applicability, with particular attention given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Volume 71 includes a chapter on Ionic and Organometallic-Catalyzed Organosilane Reductions.
Includes tables that contain all possible examples of the reactions under consideration
Each reaction is fully referenced to the primary literature
目次
Chapter 1. Ionic and Organometallic-Catalyzed Organosilane Reductions (Gerald L. Larson and James L. Fry). Cumulative Chapter titles by Volume.
Author Index, Volumes 1-71.
Chapter and Topic Index, Volumes 1-71.
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v. 69 ISBN 9780470223970
内容説明
Dental Implants for Hygienists and Therapists An essential handbook for dental hygienists and therapists seeking a comprehensive resource covering dental implants
Dental Implants for Hygienists and Therapists delivers an accessible and informative exploration of the fundamental principles of tooth replacement with dental implants, as well as the science and theory that underlies modern implants, and the factors impacting their success and survival.
The book offers robust guidance on the assessment of peri-implant tissues in health and in disease, an evidence-based approach to their management, and instruction on when a referral should be made. It also covers function and anatomy in health and disease around dental implants and the supporting tissues as well as the factors that influence predictability and patient management. This book includes:
Thorough introductions to the history of dental implants and osseointegration, including the difference between success and survival
Comprehensive exploration of one-piece and two-piece implant systems, patient selection and indications for implant treatment
Practical discussions of surgical (including augmentation) and prosthodontic protocols and peri-implant tissues
In-depth examinations of maintenance care, including the management of peri-implant disease with non-surgical and surgical treatment, and the role of the hygienist
Dental Implants for Hygienists and Therapists is invaluable to dental hygienists and therapists seeking a one-stop resource on dental implantology
目次
1. Dioxirane Oxidations of Compounds Other Than Alkenes 1
Waldemar Adam, Cong-Gui Zhao, and Kavitha Jakka
2. Electrophilic Fluorination With N-F Reagents 347
Jerome Baudoux and Dominique Cahard
Cumulative Chapter Titles By Volume 673
Author Index, Volumes 1-69 687
Chapter And Topic Index, Volumes 1-69 693
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v. 70 ISBN 9780470254530
内容説明
Organic Reactions is a collection of chapters, each devoted to a single reaction or a definitive phase of a reaction of wide applicability, with particular attention given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Volume 70 includes two chapters, the first takes a look at the Catalytic Asymmetric Strecker Reaction, the second at the Synthesis of Phenols and Quinones via Fischer Carbene Complexes.
Includes tables that contain all possible examples of the reactions under consideration
Each reaction is fully referenced to the primary literature
目次
1. THE CATALYTIC ASYMMETRIC STRECKER REACTION (Masakatsu Shibasaki, Motomu Kanai, and Tsuyoshi Mita). 2. THE SYNTHESIS OF PHENOLS AND QUINONES VIA FISCHER CARBENE COMPLEXES (Marcey L. Waters and William D. Wulff ).
CUMULATIVE CHAPTER TITLES BY VOLUME.
AUTHOR INDEX, VOLUMES 1-70.
CHAPTER AND TOPIC INDEX, VOLUMES 1-70.
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v. 72 ISBN 9780470423745
内容説明
For all volumes: the volumes of Organic Reactions are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method. Each chapter contains tablets that include all the examples of the reaction under consideration that the author has been able to find.
目次
CHAPTER PAGE. 1. ELECTROPHILIC AMINATION OF CARBANIONS, ENOLATES, AND THEIR SURROGATES (Engelbert Ciganek).
2. DESULFONYLATION REACTIONS (Diego A. Alonso and Carmen Najera).
CUMULATIVE CHAPTER TITLES BY VOLUME.
AUTHOR INDEX, VOLUMES 1-72.
CHAPTER AND TOPIC INDEX, VOLUMES 1-72.
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v. 73 ISBN 9780470436905
内容説明
Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Bronsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis.
Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates.
The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.
目次
1. Allylboration of Carbonyl Compounds 1
Hugo Lachance and Dennis G. Hall
Cumulative Chapter Titles by Volume 575
Author Index, Volumes 1-73 589
Chapter and Topic Index, Volumes 1-73 595
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v. 74 ISBN 9780470530481
内容説明
This series provides the most comprehensive and highly focused treatment of important organic reactions currently available. This volume in the prestigious series includes chapters covering two of the most fundamental processes in organic chemistry: oxidation and reduction. The coverage also includes tables containing all possible examples of the reactions under consideration, as well as references to the primary literature, reaction conditions, products, and yields where available for each reaction. Written by world-reowned experts with extensive hands-on experience in the field, Organic Reactions, Volume 74 is a key working resource.
目次
1. CATALYTIC ASYMMETRIC HYDROGENATION OF C=N FUNCTIONS (Hans-Ulrich Blaser and Felix Spindler). 2. OXOAMMONIUM- AND NITROXIDE-CATALYZED OXIDATIONS OF ALCOHOLS (James M. Bobbitt, Christian Bruckner, and Nabyl Merbouch).
3. ASYMMETRIC EPOXIDATION OF ELECTRON-DEFICIENT ALKENES (Michael J. Porter and John Skidmore).
CUMMULATIVE CHAPTER TITLES BY VOLUME.
AUTHRO INDEX, VOLUMES 1-74.
CHAPTER AND TOPIC INDEX, VOLUMES 1-74.
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v. 76 ISBN 9780470638439
内容説明
Volume 76 in the venerable Organic Reactions series comprises three chapters that cover the ever-increasing emphasis of transition metal catalysis in organic synthesis. These three chapters represent some of the most important transformations that enable the construction of carbon-carbon bonds, heterocycles and carbon-heteratom bonds. This volume features a comprehensive treatment of transition metal (palladium, nickel, copper) catalyzed a-arylation of enolates derived from many common functional groups such as ketones, aldehydes, esters and nitriles (Prim, Marque, Gaucher, Campagne) including enantioselective variants; palladium catalyzed cyclization to form indoles (Cacchi, Fabrizi, Goggiamani) one of the most prevalent and important classes of heterocycles in natural products and pharmaceutical agents; and an overview of a newly developed dihydroxylation reaction of alkenes (Donohoe, Bataille, Innocenti) that uses hydrogen bonding interactions to direct the delivery of an osmium catalyst with high selectivity. As with all Organic Reactions chapters, these reviews emphasize the preparative aspects of the featured transformation and contain comprehensive compilations of all known examples in the tables.
目次
1. HYDROGEN-BONDING-MEDIATED DIRECTED OSMIUM DIHYDROXYLATION
Timothy J. Donohoe, Carole J. R. Bataille, and Paolo Innocenti1 2. TRANSITION-METAL-CATALYZED -ARYLATION OF ENOLATES
Damien Prim, Sylvain Marque, Anne Gaucher, and Jean-Marc Campagne 49
3. INDOLES VIA PALLADIUM-CATALYZED CYCLIZATION
Sandro Cacchi, Giancarlo Fabrizi, and Antonella Goggiamani 281
CUMULATIVE CHAPTER TITLES BY VOLUME535
AUTHOR INDEX, VOLUMES 1-76 551
CHAPTER AND TOPIC INDEX, VOLUMES 1-76 557
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v. 75 ISBN 9780470889077
内容説明
This series provides the most comprehensive and highly focused treatment of important organic reactions currently available. All volumes of Organic Reactions (including this one) are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method.
目次
CHAPTER PAGE 1. HYDROCYANATION OF ALKENES AND ALKYNES
T. V. RajanBabu1
2. INTERMOLECULAR C-H INSERTIONS OF CARBENOIDS
Huw M. L. Davies and Phillip M. Pelphrey 75
3. CROSS-COUPLING WITH ORGANOSILICON COMPOUNDS
Wen-Tau T. Chang, Russell C. Smith, Christopher S. Regens, Aaron D. Bailey, Nathan S. Werner, and Scott E. Denmark 213
4. THE AZA-COPE/MANNICH REACTION
Larry E. Overman, Philip G. Humphreys, and Gregory S. Welmaker 747
CUMULATIVE CHAPTER TITLES BY VOLUME 821
AUTHOR INDEX, VOLUMES 1-75 835
CHAPTER AND TOPIC INDEX, VOLUMES 1-75 841
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v. 25 ISBN 9780471017417
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
THE RAMBERG-BLACKLUND REARRANGEMENT (Leo A. Paquette).
Synthetic Application of Phosphoryl-Stabilized Anons (William S.Wadsworth Jr.).
Hydrocyanation of Conjugated Carbonyl Compounds (Wataru Nagata& Mitsuru Yoshioka).
Author Index, Volumes 1-25.
Chapter and Topic Index, Volumes 1-25.
Subject Index.
Volume 25.
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v. 45 ISBN 9780471031611
内容説明
The volumes in this series are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The subjects are presented from a preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques.
目次
Photocyclization of Stilbenes and Related Molecules (F. Mallory & C. Mallory).
Olefin Synthesis by Deoxygenation of Vicinal Dials (E. Block).
Author Index.
Chapter and Topic Index.
Subject Index.
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v. 26 ISBN 9780471052098
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Heteroatom-Facilitated Lithiations (H. Gschwend and R. Rodriguez).
Intramolecular Reactions of Diazocarbonyl Compounds (S. Burke and P. Grieco).
Author Index, Volumes 1-26.
Chapter and Topic Index, Volumes 1-26.
Subject Index, Volume 26.
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v. 46 ISBN 9780471086192
内容説明
The volumes in this series are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The subjects are presented from a preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques.
目次
Tin (II) Enolates in the Aldol, Michael, and Related Reactions (T.Mukaiyama & S. Kobayashi).
The [2,3]-Wittig Reaction (T. Nakai & K. Mikami).
Reductions with Samarium (II) Iodide (G. Molander).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 27 ISBN 9780471096573
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Allylic and Benzylic Carbanions Substituted by Heteroatoms.
(Jean Francois Biellmann and Jean Bernard Ducep).
Palladium-Catalyzed Vinylation of Organic Halides (Richard F. Heck).
Author Index, Volumes 1-27.
Chapter and Topic Index, Volumes 1-27.
Subject Index, Volume 27.
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v. 58 ISBN 9780471105909
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction as well as tables including all the pertinent examples.
目次
Simmons-Smith Cyclopropanation Reaction (A. Charette & A. Beauchemin).
Preparation and Applications of Functionalized Organozinc Compounds (P. Knochel, et al.).
Cumulative Chapter Titles by Volume.
Author Index, Volumes 1-58.
Chapter and Topic Index, Volumes 1-58.
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v. 47 ISBN 9780471117377
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
Lateral Lithiation Reactions Promoted by Heteroatomic Substituents(R. Clark & A. Jahangir).
The Intramolecular Michael Reaction (R. Little, et al.).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 48 ISBN 9780471146995
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Asymmetric Epoxidation of Allylic Alcohols: The Katsuki-Sharpless Epoxidation Reaction (T. Katsuki & V. Martin).
Radical Cyclization Reactions (B. Giese, et al.).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 49 ISBN 9780471156550
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
The Vilsmeier Reaction of Fully Conjugated Carbocycles and Heterocycles (G. Jones & S. Stanforth).
[6 + 4] Cycloaddition Reactions (J. Rigby).
Carbon-Carbon Bond-Forming Reactions Promoted by Trivalent Manganese (G. Melikyan).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 50 ISBN 9780471156574
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
The Stille Reaction (V. Farina, et al.).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 15 ISBN 9780471171683
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
1. The Dieckmann Condensation--John P. Schaefer and Jordan J.Bloomfield.
2. The Knoevenagel Condensation--G. Jones
Author Index, Volumes 1-15
Chapter Index, Volumes 1-15
Subject Index, Volume 15
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v. 16 ISBN 9780471171690
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
The Aldol Condensation
Author Index, Volumes 1-16
Chapter Index, Volumes 1-16
Subject Index, Volume 16
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v. 59 ISBN 9780471176558
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. The subjects are presented from the preparative viewpoint and particular attention is given to limitation, interfering influences, effects of structure, and the selection of experimental techniques.
目次
Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents (Ellen W. Baxter & Allen B. Reitz). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-59. Chapter and Topic Index, Volumes 1-59.
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v. 51 ISBN 9780471183945
内容説明
The latest volume in this series presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. The volume includes tables that contain all possible examples of the reaction under consideration.
目次
Asymmetric Aldol Reactions Using Boron Enolates (C. Cowden & I.Paterson).
The Catalyzed proportional to -Hydroxyalkylation and proportionalto -Aminoalkylation of Activated Olefins (The Morita-Baylis-HillmanReaction) (E. Ciganek).
(4 + 3) Cycloaddition Reactions (J. Rigby & F. Pigge).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 52 ISBN 9780471183952
内容説明
The volumes of Organic Reactions are collections of chapters, eachdedicated to a singled reaction or definitive phase of a reactionof wide applicability. The subject is presented from thepreparative viewpoint & particular attention is given tolimitations, interfering influences, effects of structure & theselection of experimental techniques.
目次
The Retro-Diels-Alder Reaction, Part I: C-C Dienophiles (B.Rickborn).
Enantioselective Reduction of Ketones (S. Itsuno).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 17 ISBN 9780471196150
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
1. The Synthesis of Substituted Ferrocenes and Other phi-Cyclopentadienyl-Transition Metal Compounds--Donald E. Bublitz and Kenneth L. Rinehart, Jr
2. The gamma-Alkylation and gamma-Arylation of Dianions of beta-Dicarbonyl Compounds--Thomas M. Harris and Constance M. Harris
3. The Ritter Reaction--L. I. Krimen and Donald J. Cota
Author Index, Volumes 1-17
Chapter and Topic Index, Volumes 1-17
Subject Index, Volume 17
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v. 18 ISBN 9780471196181
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
1. Preparation of Ketones from the Reaction of Organolithium Reagents with Carboxylic Acids Margaret J. Jorgenson
2. The Smiles and Related Rearrangements of Aromatic Systems William E. Truce, Eunice M. Kreider, and William W. Brand
3. The Reactions of Diazoacetic Esters with Alkenes, Alkynes, Heterocylic and Aromatic Compounds Vinod Dave and E. W. Warnhoff
4. The Base Promoted Rearrangements of Quaternary Ammonium Salts Stanley H. Pine
Author Index, Volumes 1-18
Chapter Index, Volumes 1-18
Subject Index, Volume 18
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v. 19 ISBN 9780471196198
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
1. Conjugate Addition Reactions of Organocopper Reagents Gary H. Posner
2. Formation of Carbon-Carbon Bonds Via phi-Allylnickel Compounds Martin F. Semmelhack
3. The Thiele-Winter Acetoxylation of Quinones J. F. W. McOmie and J. M. Blatchly
4. Oxidative Decarboxylation of Acids by Lead Tetra-Acetate Roger A. Sheldon and Jay K. Kochi
Author Index, Volumes 1-19
Chapter and Topic Index, Volumes 1-19
Subject Index, Volume 19
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v. 20 ISBN 9780471196211
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
1. Cyclopropanes from Unsaturated Compounds, Methylene Iodide, andZinc-Copper Couple Howard E. Simmons, Theodore L. Cairns, Susan A.Vladuchick, and Connie M. Hoiness
2. Sensitized Photooxygenation of Olefins R. W. Denny and A.Nickon
3. The Synthesis of 5-Hydroxyindoles by the Nenitzecu ReactionGeorge R. Allen, Jr.
4. The Zinin Reduction of Nitroarenes H. K. Porter
Author Index, Volumes 1-20
Chapter and Topic Index, Volumes 1-20
Subject Index, Volume 20
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v. 21 ISBN 9780471196228
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Fluorination by Sulfur Tetrafluorid (E G. A. Boswell, Jr., W. C.Ripka, R. M. Scribner, and C. W. Tullock.
Modern Methods to Prepare Monofluoroaliphatic Compounds (Clay M.Sharts and William A. Sheppard).
Author Index, Volumes 1 21
Chapter Index, Volumes 1 21
Subject Index, Volume 21
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v. 22 ISBN 9780471196235
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
1. The Claisen and Cope Rearrangements
Sara Jane Rhoads and N. Rebecca Raulins
2. Substitution Reactions Using Organocopper Reagents
Gary H. Posner
3. Clemmensen Reduction of Ketones in Anhydrous OrganicSolvents
E. Vedejs.
4. The Reformatsky Reaction
Michael W. Rathke
Author Index, Volumes 1-22
Chapter and Topic Index, Volumes 1-22
Subject Index, Volume 22
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v. 23 ISBN 9780471196242
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Reduction and Related Reactions of gamma,B-Unsaturated Compoundswith Metals in Liquid Ammonia (D. Caine).
The Acyloin Condensation (J. J. Bloomfield, D. C.
Owsley, and J. M.
Nelke).
Alkenes from Tosylhydrazones (R. H. Shapiro).
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v. 24 ISBN 9780471196259
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Homogeneous Hydrogenation Catalysts in Organic Synthesis (A. J.Birch and D. H. Williamson).
Ester Cleavages via SN 2-Type Dealkylation (J. E. McMurry).
Arylation of Unsaturated Compounds by Diazonium Salts (The MeerweinArylation Reaction (C. S. Rondestvedt, Jr.).
Selenium Dioxide Oxidation (N. Rabjohn).
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v. 60 ISBN 9780471235811
内容説明
Organic Reactions is a comprehensive series devoted to important synthetic reactions, each volume having wide applicability. Each chapter focuses on a single reaction or a definitive phase of a reaction, and each is written by world-renowned chemists with extensive hands-on experience in their specialties. The material is presented from a preparative point of view, and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. Each reaction includes information about its conditions, products, and yields, where available, and is fully referenced to the primary literature. The authors also include detailed procedures illustrating the significant modifications of the chemical reaction, as well as tables featuring all pertinent data about the reaction. Volume 60 contains two chapters: "Epoxide Migration (Payne Rearrangement) and Related Reactions," by Robert M. Hanson, and "The Intramolecular Heck Reaction," by J.T. Link. The most comprehensive and highly focused treatment of important organic reactions currently available, this series represents an important addition to chemistry libraries in both academic and industrial settings, and is a valuable resource for both students and professionals in the field.
目次
1. Epoxide Migration (Payne Rearrangement) and Related Reactions (Robert M. Hanson).
2. The Intramolecular Heck Reaction (J. T. Link).
Cumulative Chapter Titles by Volume.
Author Index, Volumes 1-60.
Chapter and Topic Index, Volumes 1-60.
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v. 61 ISBN 9780471274483
内容説明
The most comprehensive and highly focused treatment of important organic reactions currently available, this series represents an important addition to chemistry libraries in both academic and industrial settings, and is a valuable resource for both students and professionals in the field. Volume 61 contains two chapters: "[3 + 2] Cycloaddition of Trimethylenemethane and its Synthetic Equivalents," by Shigeru Yamago and Eiichi Nakamura, and "Dioxirane Epoxidation of Alkenes," by Waldemar Adam, Chantu R. Saha-Moeller, and Cong-Gui Zhao.
目次
[3+2] Cycloaddition of Trimethylenemethane and its Synthetic Equivalents (Shigeru Yamago and Eiichi Nakamura).
Dioxirane Epoxidation of Alkenes (Waldemar Adam, et al.).
Cumulative Chapter Titles by Volume.
Author Index, Volumes 1-61.
Chapter and Topic Index, Volumes 1-61.
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v. 44 ISBN 9780471303022
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method. Each chapter contains tablets that include all the examples of the reaction under consideration that the author has been able to find.
目次
Preparation of ,beta-Unsaturated Carbonyl Compounds and Nitriles bySelenoxide Elimination (H. Reich & S. Wollowitz).
Enone Olefin [2 + 2] Photochemical Cycloadditions (M. Crimmins& T. Reinhold).
Cumulative Chapter Titles by Volume.
Author Index, Volumes 1-44.
Chapter and Topic Index, Volumes 1-44.
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v. 53 ISBN 9780471326090
内容説明
Every volume in the Organic Reactions series contains chapters devoted to a single reaction-or a definitive phase of a reaction-of wide applicability. Volume 53 features coverage of the Retro-Diels-Alder Reaction and the enantioselective reduction of ketones. Both subjects are presented from the preparative viewpoint.
目次
The Oxidation of Alcohols by Modified Oxochromium (VI)-Amine Reagents (F. Luzzio). The Retro-Diels-Alder Reaction. Part II. Dienophiles with One or More Heteroatom (B. Rickborn). Cumulative Chapter Titles by Volume. Indexes.
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v. 54 ISBN 9780471348887
内容説明
As with previous volumes in this acclaimed series, Volume 54 is devoted to a specific process with important applications in organic and medicinal chemistry. In two major parts, expert contributions address aromatic substitution by the S-RN1 reaction and the oxidation of carbonyl compounds with organohypervalent iodine reagents. The authors draw on their experience with the processes surveyed, presenting topics from the preparative viewpoint and discussing limitations, interfering influences, effects of structure, and how to select experimental techniques.
目次
Aromatic Substitution by the S-RN1 Reaction ( R. Rossi, et al.). Oxidation of Carbonyl Compounds with Organohypervalent Iodine Reagents (R. Moriarty & O. Prakash). Cumulative Chapter Titles by Volume. Indexes.
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v. 55 ISBN 9780471376149
内容説明
This volume focuses on the synthesis of nucleotides, presented from the preparative viewpoint. Attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method and contains tablets that include all the examples of the reaction under consideration.
目次
Nucleoside Synthesis. Silyl-Hilbert-Johnson Reaction in the Presence of Friedel-Crafts Catalysts. Mechanism of Nucleoside Formation in the Presence of Friedel-Crafts Catalysts. Special Preparations. Miscellaneous Methods. Alternative Nucleoside-Forming Reactions. Experimental Conditions. Experimental Procedures. Tabular Survey. References.
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v. 56 ISBN 9780471395683
内容説明
Organic Reactions is a comprehensive series of volumes devoted to important synthetic reactions. For each volume, the authors are world-renowned experts with extensive hands-on experience in the field. The subjects are presented from the preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques.
Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction, as well as tables listing all the pertinent examples of the reaction. The topics discussed in Volume 56 are the Hydroformylation reaction and the Vilsmeier reactions of non-aromatic compounds. Each reaction is presented with information about the reaction conditions, products, and yields where available, and is fully referenced to the primary literature.
目次
The Hydroformylation Reaction (I. Ojima, et al.).
The Vilsmeier Reaction. 2. Reactions with Compounds Other Than Fully Conjugated Carbocycles and Heterocycles (G. Jones & S. Stanforth).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 57 ISBN 9780471435112
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction as well as tables including all the pertinent examples. Each reaction is presented with information about the conditions, products, and yields where available. * Particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions
目次
Intermolecular Metal-Catalyzed Carbenoid Cyclopropanations (H. Davies & E. Antoulinakis). Oxidation of Phenolic Compounds with Organohypervalent Iodine Reagents (R. Moriarty & O. Prakash). Synthetic Uses of Tosylmethyl Isocyanide (TosMIC) (D. van Leusen & A. van Leusen). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-57. Chapter and Topic Index, Volumes 1-57.
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v. 63 ISBN 9780471445326
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world-renowned experts with extensive hands-on experience in the field.
The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions.
目次
Chapter 1. The Biginelli Dihydropyrimidine Synthesis (C. Oliver Kappe and Alexander Stadler). Chapter 2. Microbial Arene Oxidations (Roy A. Johnson).
Chapter 3. Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Synthesis: The Ullmann Reaction (Todd D. Nelson and R. David Crouch).
Cumulative Chapter Titles by Volume.
Author Index, Volumes 1-63.
Chapter and Topic Index, Volumes 1-63.
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v. 62 ISBN 9780471445333
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. World-renowned experts, who have extensive hands-on experience in this field, have written the chapters that comprise this volume. The chemistry is presented from a preparative point of view, with particular attention given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction as well as tables including all the pertinent examples of the reaction. Each reaction is presented with information about the reaction conditions as well as products and yields where available. Organic Reactions, Volume 62 includes chapters such as "The Ramberg-Backlund Reaction," "a -Hydroxylation of Enolates and Silyl Enol Ethers," "The a -Hydroxyl Ketone (a -Ketol) and Related Rearrangements," and " Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives." Filled with in-depth insights and expert advice, Organic Reactions, Volume 62 provides the most comprehensive and highly focused treatment of important organic reactions currently available.
目次
1. a-Hydroxylation of Enolates and Silyl Enol Ethers (Bang-Chi Chang, et al.). 2. The Ramberg-Backlund Reaction (Richard J.K. Taylor and Guy Casy).
3. The a-Hyroxyl Ketone (?-Ketol) and Related Rearangements (Leo A. Paquette and John E. Hofferberth).
4. Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives (Robert J. Ferrier and Oleg A. Zubkov).
Cumulative Chapter Titles by Volume.
Author Index, Volumes 1-62.
Chapter and Topic Index, Volumes 1-62.
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v. 37 ISBN 9780471501695
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Chiral Synthons by Ester Hydrolysis Calalyzed by Pig Liver Esterase (M. Ohno & M. Otsuka).
The Electrophilic Substitution of Allylsilanes and Vinylsilanes (I. Fleming et al.).
Author Index, Volumes 1-37.
Chapter and Topic Index, Volumes 1-37.
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v. 38 ISBN 9780471515944
内容説明
The volumes in this series are collections of essays devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The subjects are presented from the preparative viewpoint and particular attention is given to the limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method.
目次
The Peterson Olefination Reaction (D. Ager).
Tandem Vicinal Difunctionalization: B-Addition to ,B-Unsaturated Carbonyl Substrates Followed by -Functionalization (M. Chapdelaine & M. Hulce).
The Nef Reaction (H. Pinnick).
Author Index, Volumes 1-38.
Chapter and Topic Index, Volumes 1-38.
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v. 39 ISBN 9780471526322
内容説明
Part of a series of volumes for organic chemists in industry, this work presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. The volume includes tables that contain all possible examples of the reaction under consideration.
目次
Lithioalkenes from Arenesulfonylhydrazones (A. Chamberlin & S. Bloom).
The Polonovski Reaction (D. Grierson).
Oxidation of Alcohols to Carbonyl Compounds via Alkoxysulfonium Ylides: The Moffatt, Swern, and Related Oxidations (T. Tidwell).
Author Index, Volumes 1-39.
Chapter and Topic Index, Volumes 1-39.
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v. 40 ISBN 9780471538417
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
The Pauson-Khand Cycloaddition Reaction for Synthesis ofCyclopentenones (N. Schore).
Reduction with Diimide (D. Pasto & R. Taylor).
The Pummerer Reaction of Sulfinyl Compounds (O. De Lucchi, etal.).
The Catalyzed Nucleophilic Addition of Aldehydes to ElectrophilicDouble Bonds (H. Stetter & H. Kuhlmann).
Author Index, Volumes 1-40.
Chapters and Topic Index, Volumes 1-40.
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v. 41 ISBN 9780471544098
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Divinylcylopropane--Cycloheptadiene Rearrangement (T. Hudlicky, etal.).
Formation of Carbon-Carbon Bonds via Organocopper Reagents (BLipshutz & S. Sengupta).
Indexes.
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v. 42 ISBN 9780471544104
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
The Birch Reduction of Aromatic Compounds (P. Rabideau & Z.Marcinow).
The Mitsunobu Reaction (D. Hughes).
Indexes.
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v. 43 ISBN 9780471584797
内容説明
Each volume in this series contains sections devoted to a single reaction, or a definitive phase of a reaction. Particular attention is given to limitations, interfering influences, the effects of structure and the selection of experimental techniques.
目次
Carbonyl Methylenation and Alkylidenation Using Titanium-BasedReagents (S. Pine).
Anion-Assisted Sigmatropic Rearrangements (S. Wilson).
The Baeyer-Villiger Oxidation of Ketones and Aldehydes (G.Krow).
Cumulative Chapter Titles by Volume.
Indexes.
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v. 66 ISBN 9780471682585
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world-renowned experts with extensive hands-on experience in the field. The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions.
* Each reaction is fully referenced to the primary literature
* Numerous detailed procedures illustrate the significant modifications of each method
* Includes tables that contain all possible examples of the reaction under consideration
目次
1. THE ALLYLIC TRIHALOACETIMIDATE REARRANGEMENT (Larry E. Overman and Nancy E. Carpenter). 2. ASYMMETRIC DIHYDROXYLATION OF ALKENES (Mark C. Noe, Michael A. Letavic, Sheri L. Snow, and Stuart W. McCombie).
CUMULATIVE CHAPTER TITLES BY VOLUME.
AUTHOR INDEX, VOLUMES 1-66.
CHAPTER AND TOPIC INDEX, VOLUMES 1-66.
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v. 65 ISBN 9780471682608
内容説明
"Organic Reactions" is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world renowned experts with extensive hands on experience in the field. The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. Each reaction is fully referenced to the primary literature. Numerous detailed procedures illustrate the significant modifications of each method. This book includes tables that contain all possible examples of the reaction under consideration
目次
Chapter 1. The Passerini Reaction. (Luca Banfi and Renata Riva).Chapter 2. Diels-Alder Reactions of Imino Dienophiles. (Geoffrey R. Heintzelman, Ivona R. Meigh, Yogesh R. Mahajan, and Steven M. Weinreb).Cumulative Chapter Titles By Volume.Author Index, Volumes 1-65.Chapter and Topic Index, Volumes 1-65.
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v. 64 ISBN 9780471682622
内容説明
Organic Reactions is a comprehensive series of volumes composed of chapters devoted to a single reaction, or a definite phase of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reactions under consideration. Authors are world-renowned experts with extensive hands-on experience in the field Volume 64 includes the following chapters: 1. ADDITIONS OF ALLYL, ALLENYL, AND PROPARGYLSTANNANES TO ALDEHYDES AND IMINES By Benjamin W. Gung 2. GLYCOSYLATION WITH SULFOXIDES AND SULFINATES AS DONORS AND PROMOTERS By David Crich and Linda B. L. Lim 3. ADDITION OF ORGANOCHROMIUM REAGENTS TO CARBONYL COMPOUNDS By Kazuhiko Takai
目次
1. ADDITIONS OF ALLYL, ALLENYL, AND PROPARAGYLSTANNANES TO ALDEHYDES AND IMINES (Benjamin W. Gung). 2. GYLCOSYLATION WITH SULFOXIDES AND SULFINATES AS DONORS OR PROMOTERS (David Crich and Linda B. L. Lim). 3. ADDITION OF ORGANOCHROMIUM REAGENTS TO CARBONYL COMPOUNDS (Kazuhiko Takai). CUMULATIVE CHAPTER TITLES BY VOLUME. AUTHOR INDEX, VOLUMES 1-64. CHAPTER AND TOPIC INDEX, VOLUMES 1-64.
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v. 33 ISBN 9780471802297
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Formation of Carbon-Carbon and Carbon-Heteroatom Bonds viaOrganoboranes and Organoborates (E. Negishi and M.Idacavage).
The Vinylcyclopropane-Cyclopentene Rearrangement (T. Hudlicky etal.).
Author Index.
Chapter and Topic Index.
Subject Index.
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v. 34 ISBN 9780471806738
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Reductions by Metal Alkoxyaluminum Hydrides (J. Malek).
Fluorination by Sulfur Tetrafluoride (C. Wang).
Author Index.
Chapter and Topic Index.
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v. 35 ISBN 9780471832539
内容説明
Each subject of organic chemistry reviewed in this series is presented from a preparative viewpoint. Emphasis is placed on limitations, interfering influences, effects of structure and the selection of experimental techniques.
目次
The Beckmann Reactions: Rearrangements, Elimination-Additions, Fragmentations, and Rearrangement-Cyclizations
Robert E. Gawley
2. The Persulfate Oxidation of Phenols and Arylamines (The Elbs and the Boyland-Sims Oxidations)
E. J. Behrman
3. Fluorination with Diethylaminosulfur Trifluoride and Related Aminofluorosulfuranes
Milos Hudlicky
Author Index, Volumes 1-35
Chapter and Topic Index, Volumes 1-35
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v. 36 ISBN 9780471857488
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
The Nitrone-Olegin Cycloaddition Reaction (P. N. Confalone & E. M. Huie).
Phosphorus Addition at sp 2 Carbon (R. Engel).
Reduction by Metal Alkoxyaluminum Hydrides (J. Malek).
Author Index, Vols. 1-36.
Chapter and Topic Index, Vols. 1-36.
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v. 28 ISBN 9780471861416
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
The Reimer-Tiemann Reaction (Hans Wynberg and Egbert W. Meijer).
The Friedlander Synthesis of Quinolines (Chia-Chung Cheng and Shou-Jen Yan).
The Directed Aldol Reaction (Tenuaki Mukaiyama).
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v. 29 ISBN 9780471874904
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Replacement of Alcoholic Hydroxyl Groups by Halogens and Other Nucleophiles Via Oxyphosphonium Intermediates (B. Castro).
Reductive Dehalogenation of Polyhalo Ketones with Low-Valent Metals and Related Reducing Agents (R. Nayori & Y. Hayakawa).
Base Isomerizations of Epoxides (J. Crandall & M. Apparu).
Author Index, Volumes 1-29.
Chapter and Topic Index, Volumes 1-29.
Subject Index, Volume 29.
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v. 32 ISBN 9780471881018
内容説明
Leading experts present papers devoted to a single reaction, or a definite phase of a reaction, of wide applicability. Emphasizes limitations, interfering influences, effects of structure, and the selection of experimental techniques. Chapters include detailed procedures illustrating the significant modifications of the method. Includes tables with examples of the reaction under consideration.
目次
The Intramolecular Diels-Alder Reaction (E. Ciganek).
Syntheses Using Alkyne-Derived Alkenyl--And Alkynylaluminum Compounds (G. Zweifel & J. Miller).
Author Index, Volumes 1-32.
Chapter and Topic Index, Volumes 1-32.
Subject Index, Volume 32.
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v. 31 ISBN 9780471886716
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Addition and Substitution Reactions of Nitrile-Stabilized Carbanions (S. Areniyadis et al.).
Author Index, Volumes 1-31.
Chapter and Topic Index, Volumes 1-31.
Subject Index, Volume 31.
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v. 30 ISBN 9780471890133
内容説明
The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
Photocyclization of Stilbenes and Related Molecules (F. Mallory & C. Mallory).
Olefin Synthesis by Deoxygenation of Vicinal Dials (E. Block).
Author Index.
Chapter and Topic Index.
Subject Index.
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v. 77 ISBN 9781118163801
内容説明
This new volume in the venerable Organic Reactions series comprises two chapters written in part by the inventors of the unique and important name reactions discussed in these chapters. The first chapter describes a truly remarkable transformation of carboxylic acid derivatives into heteroatom-substituted cyclopropanes, now known as Kulinkovich Cyclopropanation. The second chapter represents an homage to one of the giants of organic chemistry, Sir Derek H. R. Barton. This chapter covers the radical deoxygenation of secondary alcohols that has become known as the Barton-McCombie Reaction.
目次
1. The Kulinkovich Cyclopropanation of Carboxylic Acid Derivatives 1
Jin Kun Cha and Oleg G. Kulinkovich
2. The Barton-Mccombie Reaction 161
Stuart W. McCombie, William B. Motherwell, and Matthew J. Tozer
Cumulative Chapter Titles By Volume 593
Author Index, Volumes 1-77 609
Chapter and Topic Index, Volumes 1-77 615
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v. 78 ISBN 9781118356364
内容説明
This volume in the venerable Organic Reactions series contains three chapters focusing on the introduction or the removal of nitrogen from organic compounds. The first chapter features a classic chemical reaction for introducing nitrogen into organic compounds, namely the Schmidt Reaction. The second chapter highlights a less-well-known yet fascinating transformation that introduces nitrogen into organic compounds, The Neber Rearrangement. The third chapter describes an unusual class of reactions that involve the loss of small molecular fragments from a ring, where separate carbon atoms unite to form alkenes.
目次
CHAPTER PAGE 1. THE SCHMIDT REACTION
Aaron Wrobleski, Thomas C. Coombs, Chan Woo Huh, Sze-Wan Li, and Jeffrey Aube 1
2. THE NEBER REARRANGEMENT
William F. Berkowitz 321
3. TWOFOLD EXTRUSION REACTIONS
Lynn James Guziec and Frank S. Guziec, Jr 411
CUMULATIVE CHAPTER TITLES BY VOLUME 551
AUTHOR INDEX, VOLUMES 1-78 567
CHAPTER AND TOPIC INDEX, VOLUMES 1-78 573
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v. 79 ISBN 9781118509418
内容説明
Volume 79 in the venerable Organic Reactions series contains two chapters. The first addresses cross-coupling reactions of organotrifluoroborate salts, useful in the development of natural products, materials, and pharmacologically active substances. It is an excellent companion to two previous chapters on tin-based and silicon-based cross-couplings contained in Volumes 50 and 75, respectively. The second chapter addresses asymmetric transformations by deprotonation using chiral lithium amides, useful in target-oriented synthesis, and representing one of the most powerful workhorse reactions in organic synthesis.
目次
1. CROSS-COUPLING REACTIONS OF ORGANOTRIFLUOROBORATE SALTS
Gary A. Molander and Ludivine Jean-Gerard 1
2. ASYMMETRIC TRANSFORMATIONS BY DEPROTONATION USING CHIRAL LITHIUM
AMIDES
Nigel S. Simpkins and Michael D. Weller 317
CUMULATIVE CHAPTER TITLES BY VOLUME 637
AUTHOR INDEX, VOLUMES 1-79 653
CHAPTER AND TOPIC INDEX, VOLUMES 1-79 659
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v. 80 ISBN 9781118513088
内容説明
Volume 80 in the venerable Organic Reactions series contains two chapters. The first describes the use of chiral rhodium complexes to effect catalytic, asymmetric carbon-hydrogen insertion reactions intramolecularly. It details the structural scenarios in which diazocarbonyl compounds can be generated and activated to form, inter alia, lactones, lactams and cyclic ketones. The second chapter describes the use of (chiral) rhodium complexes in combination with diazocarbonyl compounds, but in this case to effect a remarkable transformation that dramatically increases the molecular complexity of the substrates.
目次
1. CATALYTIC, ASYMMETRIC, INTRAMOLECULAR CARBON-HYDROGEN INSERTION 1
Michael P. Doyle, Yu Liu, and Maxim Ratnikov
2. CYCLOADDITIONS OF CARBONYL YLIDES DERIVED FROM DIAZOCARBONYL COMPOUNDS 133
David M. Hodgson, Agn`es H. Labande, and Sengodagounder Muthusamy
CUMULATIVE CHAPTER TITLES BY VOLUME 497
AUTHOR INDEX, VOLUMES 1-80 513
CHAPTER AND TOPIC INDEX, VOLUMES 1-80 519
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v. 81 ISBN 9781118674253
内容説明
Volume 81 represents the confluence of two rare and important phenomena for chapters in the Organic Reactions series, namely, it is a single-chapter volume, and it contains a name reaction coauthored by the inventor. Of the 261 chapters published thus far, only seven have been of sufficient impact to appear as single-chapter volumes. The single chapter in this volume entitled "The Krapcho Dealkoxycarbonylation Reaction of Esters with a-Electron-Withdrawing Substituents" has been coauthored by A. Paul Krapcho together with Organic Reactions' long-time contributor Engelbert Ciganek. The "Krapcho Decarboxylation," as it is known in common parlance, is an extraordinarily useful alternative to the classical hydrolysis-decarboxylation of esters bearing a-electron-withdrawing substituents. This process replaces the strongly basic or acidic conditions normally required for ester saponification with the neutral cleavage of the ester group by a BAC2 mechanism through the combination of water and a dipolar aprotic solvent at high temperature. However, another popular variant involves the use of inorganic salts such as lithium chloride, sodium iodide, or sodium cyanide in a dipolar aprotic solvent which can open a second mechanistic pathway (dependent upon the ester) through BAL2 cleavage. Drs. Krapcho and Ciganek expertly outline the broad substrate scope of this reaction and identify the preferred conditions for various substrate classes. The 371 pages of tables containing all known examples of this simple but important transformation, together with the 1,908 references cited in this Chapter, are testimony to the synthetic usefulness of the Krapcho reaction.
目次
1 THE KRAPCHO DEALKOXYCARBONYLATION REACTION OF ESTERS WITH -ELECTRON-WITHDRAWING SUBSTITUENTS
A Paul Krapcho and Engelbert Ciganek 1 CUMULATIVE CHAPTER TITLES BY VOLUME 537
AUTHOR INDEX, VOLUMES 1-81 553
CHAPTER AND TOPIC INDEX, VOLUMES 1-81 559
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v. 82 ISBN 9781118674284
内容説明
Volume 82 describe reactions that involve one of the most common transformations in organic chemistry, namely, the pairwise combination of double bonded functional groups. The importance of this enormous family of reactions is a reflection of the spectacular diversity of precursors and products that can arise from appropriate modulation of reactivity of the partners and especially selection of reagents that dictate the outcome.
The first chapter authored by Takeshi Takeda and Akira Tsubouchi describes the combination of carbonyl compounds in the presence of highly reactive, low valent titanium reagents in the classic McMurry reaction.
The second chapter concerns the chemistry of highly-reactive, double-bonded functional groups, namely ketenes.
目次
1. THE McMURRY COUPLING AND RELATED REACTIONS
Takeshi Takeda and Akira Tsubouchi 1
2. CATALYTIC ASYMMETRIC KETENE [2+ 2] AND [4+ 2] CYCLOADDITIONS
Scott G. Nelson, Robert D. Dura, and Timothy J. Peelen 471
CUMULATIVE CHAPTER TITLES BY VOLUME 623
AUTHOR INDEX, VOLUMES 1-82 639
CHAPTER AND TOPIC INDEX, VOLUMES 1-82 645
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v. 83 ISBN 9781118835227
内容説明
The two chapters in Volume 83 describe reactions that represent two major (and growing) franchises in the Organic Reactions series, namely, transition metal catalyzed cross-coupling reactions and multicomponent reactions. These two processes not only have a rich history in synthetic organic chemistry, but also represent some of the most commonly employed transformations in the modern practice of molecule construction. The first chapter authored by Eiichi Nakamura, Takuji Hatakeyama, Shingo Ito, Kentaro Ishizuka, Laurean Ilies, and Masaharu Nakamura describes one of the most exiting advances in the field of transition metal catalyzed cross-coupling reactions: the use of iron catalysts. The second chapter authored by Stephen G. Pyne and Minyan Tang describes the latest in a long line of multicomponent reactions published in this series: the boronic acid Mannich reaction, sometimes called the Petasis reaction.
目次
CHAPTER PAGE 1. IRON-CATALYZED CROSS-COUPLING REACTIONS
Eiichi Nakamura, Takuji Hatakeyama, Shingo Ito, Kentaro Ishizuka, Lauren Ilies, and Masaharu Nakamura 1
2. THE BORONIC ACID MANNICH REACTION
Stephen G. Pyne and Minyan Tang 211
CUMULATIVE CHAPTER TITLES BY VOLUME 499
AUTHOR INDEX, VOLUMES 1-83 515
CHAPTER AND TOPIC INDEX, VOLUMES 1-83 521
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v. 84 ISBN 9781118841907
内容説明
The two chapters in Volume 84 describe transition metal catalyzed processes that form carbon-carbon bonds and carbon-oxygen bonds in very interesting and practical ways. The first chapter authored by Christina Moberg describes an important subset of one of the earliest and most important enantioselective carbon-carbon bond forming reactions that employ transition metal complexes, namely molybdenum-catalyzed, asymmetric allylic alkylations. The second chapter authored by Brian W. Michel, Laura D. Steffens, and Matthew S. Sigman deals with one of the oldest examples of transition metal catalyzed oxidation, known as the Wacker process.
目次
1. Molybdenum-Catalyzed Asymmetric Allylic Alkylations
Christina Moberg 1 2. The Wacker Oxidation
Brian W. Michel, Laura D. Steffens, and Matthew S. Sigman 75
Cumulative Chapter Titles by Volume 415
Author Index, Volumes 1-84 431
Chapter and Topic Index, Volumes 1-84 437
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v. 85 ISBN 9781118976517
内容説明
Volume 85 represents the ninth single chapter volume to be produced in Organic Reactions' 72-year history. The original authors, Drs. Shaughnessy and DeVasher, have compiled an enormous (and growing) literature and distilled it into an extraordinarily useful treatise on all aspects of the copper-catalyzed amination process. Given the myriad types of nitrogen-based nucleophiles and various ligand sets and reaction conditions, the authors have done an outstanding job of identifying the best options for various permutations of donor and acceptor. This comprehensive treatment of so many different options constitutes a dream "field guide" for the perplexed chemist who wants to know how best to approach the formation of a C-N bond in a target structure and whether copper or palladium catalysis is recommended.
目次
1. Copper-Catalyzed Amination of Aryl and Alkenyl Electrophiles 1
Kevin H. Shaughnessy, Engelbert Ciganek, and Rebecca B. DeVasher
Cumulative Chapter Titles by Volume 669
Author Index, Volumes 1-85 685
Chapter and Topic Index, Volumes 1-85 691
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v. 86 ISBN 9781119013990
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.
目次
1. Ring-Expanding Carbonylation of Epoxides 1
John W. Kramer, John M. Rowley, and Geoffrey W. Coates
2. The Tishchenko Reaction 105
Ari M. P. Koskinen and Antti O. Kataja
Cumulative Chapter Titles by Volume 411
Author Index, Volumes 1-86 427
Chapter and Topic Index, Volumes 1-86 433
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v. 87 ISBN 9781119014003
内容説明
The first chapter describes the manifold ways in which the latent functionality embedded in the humble heterocycle furan can be revealed by various oxidative processes.The second chapter details the fascinating cycloaddition and electrocyclization chemistry of unsaturated ketenes. The third chapter chronicles the development of a remarkable organometallic reaction of unactivated alkenes and alkynes, namely carbozincation.
目次
1. Oxidative Cleavage of Furans
Pedro Merino 1 2. Cycloaddition and Electrocyclic Reactions of Vinylketenes, Allenylketenes, and Alkynylketenes
Nanyan Fu and Thomas T. Tidwell 257
3. Carbozincation Reactions of Carbon-Carbon Multiple Bonds
Genia Sklute, Hannah Cavender, and Ilan Marek 507
Cumulative Chapter Titles by Volume 765
Author Index, Volumes 1-87 781
Chapter and Topic Index, Volumes 1-87 787
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v. 88 ISBN 9781119103851
内容説明
Volume 88 represents the tenth single-chapter-volume produced in our 73-year history. Such single-chapter volumes represent definitive treatises on extremely important chemical transformations. The success of the research efforts over the past 20 years forms the basis for the single chapter in this volume namely, Hydroamination of Alkenes by Alexander L. Reznichenko and Kai C. Hultzsch. The authors have compiled an enormous (and growing) literature and distilled it into an extraordinarily useful treatise on all aspects of the hydroamination process.
目次
1. Hydroamination of Alkenes
Alexander L. Reznichenko and Kai C. Hultzsch 1 Cumulative Chapter Titles by Volume 555
Author Index, Volumes 1-88 571
Chapter and Topic Index, Volumes 1-88 577
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v. 89 ISBN 9781119211211
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. Olefin Ring-Closing Metathesis Larry Yet 1 Abbreviations 92
Chart 1. Catalysts Used in Tables 95
Chart 2. Ligands Used in Tables 107
Table 1. Synthesis of Carbocycles 108
Table 2A. Synthesis of Cyclic Amides 374
Table 2B. Synthesis of Cyclic Ethers 569
Table 2C. Synthesis of Phosphorous-Containing Heterocycles 764
Table 2D. Synthesis of Silicon-Containing Heterocycles 788
Table 2E. Synthesis of Sulfur-Containing Heterocycles 818
Table 2F. Synthesis of Sulfonamide-Containing Heterocycles 828
Table 2G. Synthesis of Boron-Containing Derivatives 837
Table 2H. Synthesis of Unsaturated Lactams 838
Table 2I. Synthesis of Cyclic Peptides 916
Table 2J. Synthesis of Unsaturated Lactones 953
Table 2K. Synthesis of Heterocycles Containing Multiple Heteroatoms 1118
Table 3. Synthesis of Supramolecular Compounds 1180
Table 4. Tandem Metathesis Reactions 1204
References 1248
Cumulative Chapter Titles by Volume 1305
Author Index, Volumes 1-89 1321
Chapter and Topic Index, Volumes 1-89 1327
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v. 93 ISBN 9781119281412
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. Enantioselective, Rhodium-Catalyzed 1,4-Addition of Organoboron Reagents to Electron-Deficient Alkenes 1
Alan R. Burns, Hon Wai Lam, and Iain D. Roy
Cumulative Chapter Titles by Volume 687
Author Index, Volumes 1-93 705
Chapter and Topic Index, Volumes 1-93 711
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v. 92 ISBN 9781119281429
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. Gold-Catalyzed Cyclizations ofAlkynes with Alkenes and Arenes 1
Antonio M. Echavarren, Michael E. Muratore, Veronica Lopez-Carrillo, Ana Escribano-Cuesta, Nuria Huguet, and Carla Obradors
2. Cyclization of Vinyl and Aryl Azides into Pyrroles, Indoles, Carbazoles, and Related Fused Pyrroles 413
William F. Berkowitz and Stuart W. McCombie
Cumulative Chapter Titles by Volume 659
Author Index, Volumes 1-92 677
Chapter and Topic Index, Volumes 1-92 683
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v. 91 ISBN 9781119281436
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. Nucleophilic Additions of Perfluoroalkyl Groups
Petr Beier, Mikhail Zibinsky, and G. G. Surya Prakash 1 Cumulative Chapter Titles by Volume 743
Author Index, Volumes 1 91 761
Chapter and Topic Index, Volumes 1 91 767
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v. 90 ISBN 9781119281443
内容説明
The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. The Catalytic, Enantioselective Michael Reaction
Efraim Reyes, Uxue Uria, Jose L. Vicario, and Luisa Carrillo 1 Cumulative Chapter Titles by Volume 899
Author Index, Volumes 1-90 915
Chapter and Topic Index, Volumes 1-90 921
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v. 95 ISBN 9781119308928
内容説明
The 95th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. The Julia-Kocienski Olefination 1
Paul R. Blakemore, Selena Milicevic Sephton, and Engelbert Ciganek
2. Asymmetric Synthesis of -Lactams by the Staudinger Reaction 423
Aitor Landa, Antonia Mielgo, Mikel Oiarbide, and Claudio Palomo
Cumulative Chapter Titles by Volume 595
Author Index, Volumes 1-95 613
Chapter and Topic Index, Volumes 1-95 619
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v. 94 ISBN 9781119308935
内容説明
The 94th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. [3 + 2] Dipolar Cycloadditions of Cyclic Nitrones with Alkenes 1
Alberto Brandi, Francesca Cardona, Stefano Cicchi, Franca M. Cordero, and Andrea Goti
Cumulative Chapter Titles by Volume 531
Author Index, Volumes 1-94 549
Chapter and Topic Index, Volumes 1-94 555
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v. 96 ISBN 9781119374534
内容説明
The 96th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. CATALYTIC, ENANTIOSELECTIVE HYDROGENATION OF HETEROAROMATIC COMPOUNDS
Lei Shi and Yong-Gui Zhou 1
2. TRANSITION-METAL-CATALYZED HYDROACYLATION
Vy M. Dong, Kevin G. M. Kou, and Diane N. Le 229
CUMULATIVE CHAPTER TITLES BY VOLUME 593
AUTHOR INDEX, VOLUMES 1-96 611
CHAPTER AND TOPIC INDEX, VOLUMES 1-96 617
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v. 97 ISBN 9781119374541
内容説明
The 97th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. [2 + 2 + 2] Cycloadditions of Alkynes with Heterocumulenes and Nitriles
Nicholas D. Staudaher, Ryan M. Stolley, and Janis Louie 1
2. Amide-Forming Ligation Reactions 203
Vijaya R. Pattabiraman, Ayodele O. Ogunkoya,and Jeffrey W. Bode
Cumulative Chapter Titles by Volume 691
Author Index, Volumes 1-97 709
Chapter and Topic Index, Volumes 1-97 715
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v. 98 ISBN 9781119456582
内容説明
The 98th volume in this series for organic chemists in academia and industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.
目次
1. The Saegusa Oxidation and Related Procedures 1
Jean Le Bras and Jacques Muzart
2. The Asymmetric Vinylogous Mukaiyama Aldol Reaction 173
Martin H. C. Cordes and Markus Kalesse
Cumulative Chapter Titles by Volume 775
Author Index, Volumes 1-98 793
Chapter and Topic Index, Volumes 1-98 799
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v. 99 ISBN 9781119456629
内容説明
ORGANIC REACTION
目次
1. Addition of Non-Stabilized Carbon-Based Nucleophilic Reagents to Chiral N-Sulfinyl Imines 1
Melissa A. Herbage, Jolaine Savoie, Joshua D. Sieber, Jean-Nicolas Desrosiers, Yongda Zhang, Maurice A. Marsini, Keith R. Fandrick, Daniel Rivalti, and Chris H. Senanayake
2. Iridium-Catalyzed, Enantioselective, Allylic Alkylations with Carbon Nucleophiles 423
Jian-Ping Qu, Gunter Helmchen, Ze-Peng Yang, Wei Zhang, and Shu-Li You
Cumulative Chapter Titles by Volume 633
Author Index, Volumes 1-99 651
Chapter and Topic Index, Volumes 1-99 657
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v. 100 ISBN 9781119456667
内容説明
Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others.
In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.
目次
1. The Negishi Cross-Coupling Reaction 1
Colin Diner and Michael G. Organ
2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63
Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel
3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121
Haoxuan Wang and Stephen L. Buchwald
4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207
Yeshua Sempere and Erick M. Carreira
5. Enantioselective Lithiation-Substitution of Nitrogen-Containing Heterocycles 255
Kevin Kasten, Nico Seling, and Peter O'Brien
6. Catalytic, Enantioselective, Transfer Hydrogenation 329
Masahiro Yoshimura and Masato Kitamura
7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383
Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green
8. Carbon-Carbon Bond Formation by Metallaphotoredox Catalysis 471
Eric D. Nacsa and David W. C. MacMillan
9. Suzuki-Miyaura Cross-Coupling 547
Alexander B. Pagett and Guy C. Lloyd-Jones
10. ortho-Directed C-H Alkylation of Substituted Benzenes 621
Yusuke Ano and Naoto Chatani
11. Catalytic, Enantioselective, C-H Functionalization to Form Carbon-Carbon Bonds 671
Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu
12. Catalytic, Enantioselective Fluorination Reactions 749
Richard T. Thornbury and F. Dean Toste
13. Catalyst-Controlled Glycosylation 801
Samuel M. Levi and Eric N. Jacobsen
14. Palladium-Catalyzed Amination of Aryl Halides 853
John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green
15. Catalytic, Enantioselective, Copper-Boryl Additions to Alkenes 959
Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee Lee
Cumulative Chapter Titles by Volume 1057
Author Index, Volumes 1-100 1075
Chapter and Topic Index, Volumes 1-100 1083
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