The organometallic chemistry of the transition metals

書誌事項

The organometallic chemistry of the transition metals

Robert H. Crabtree

Wiley, c1988

  • : pbk

大学図書館所蔵 件 / 29

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注記

"A Wiley-Interscience publication."

Includes bibliographies and index

内容説明・目次

巻冊次

: pbk ISBN 9780471573883

内容説明

This study deals with practical and biological aspects of the subject, processes of industrial significance and organic synthesis. Methods of characterization and bio-organometallic chemistry are also discussed, along with high valent organometallic species.

目次

  • List of Abbreviations
  • General Properties of Organometallic Complexes
  • The Metal-Carbon and Metal-Hydrogen Bonds
  • Ligand Substitution Reactions
  • Complexes of Pi-Bound Ligands
  • Oxidative Addition and Reductive Elimination
  • Insertion and Elimination
  • Nucleophilic and Electrophilic Addition and Abstraction
  • Homogeneous Catalysis
  • Characterization of Organometallic Compounds
  • Carbenes, Metathesis and Polymerization
  • The Activation of Small Molecules
  • Clusters and the Metal-Metal Bond
  • Applications to Organic Synthesis
  • Oxidation and High-Oxidation-State Complexes
  • Bioorganometallic Chemistry
  • Solutions to Problems
  • Index.
巻冊次

ISBN 9780471853060

内容説明

Organometallic chemistry is presented within a logical framework of fundamental ideas in this book which deals with practical applications of the subject, processes of industrial significance, and organic synthesis. The biological aspects of the subject, which are just beginning to emerge, are also covered. Methods of characterization and bio-organometallic chemistry are discussed and high valent organometallic species and applications to organic chemistry are considered.

目次

  • General Properties of Organometallic Complexes
  • The Metal-Carbon and Metal-Hydrogen Bonds
  • Ligand Substitution Reactions
  • Complexes of Pi-Bound Ligands
  • Oxidative Addition and Reductive Elimination
  • Insertion and Elimination
  • Nucleophilic and Electrophilic Addition and Abstraction
  • Homogeneous Catalysis
  • Characterization of Organometallic Compounds
  • Carbenes, Metathesis and Polymerization
  • The Activation of Small Molecules
  • Clusters and the Metal-Metal Bond
  • Applications to Organic Synthesis
  • Oxidation and High-Oxidation-State Complexes
  • Bioorganometallic Chemistry
  • Solutions to Problems.

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