Compounds with sulfur of oxidation number IV

著者

• Baumann, Norbert
• Heibel, Brigitte
• Kubny, Alfons
• Fachmann, Hans-Jürgen

書誌事項

Compounds with sulfur of oxidation number IV

authors, Norbert Baumann ; chief editor, Brighitte Heibel

（Gmelin handbook of inorganic chemistry / prepared and issued by Gmelin-Institut für Anorganische Chemie der Max-Planck-Gesellschaft zur Förderung der Wissenschaften ; director, Ekkehard Fluck, system no. 9 . S, sulfur-nitrogen compounds）

Springer, 1985-

8th ed

• pt. 2 (gw)
• pt. 2 (us)
• pt. 3 (gw)
• pt. 3 (us)
• pt. 4 (gw)
• pt. 4 (us)
• pt. 5 (gw)
• pt. 5 (us)
• pt. 6 (gw)
• pt. 6 (us)
• pt. 7 (gw)
• pt. 7 (us)
• pt. 8 (gw)
• pt. 8 (us)

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注記

pt. 2: "Literature closing date: end of 1983, in many cases more recent data have been considered" -- t.p. verso

pt. 3-4: "Literature closing date: end of 1984, in many cases more recent data have been considered" -- t.p. verso

pt. 5-6: "Literature closing date: end of 1988" -- t.p. verso

pt. 7-8: "Literature closing date: 1989" -- t.p. verso

pt. 5-8 ; chief editor, Alfons Kubny

pt. 5: authors, Hans-Jürgen Fachamn ... [et al.]

内容説明・目次

巻冊次

pt. 3 (gw) ISBN 9783540935445

内容説明

The present volume describes cyclic sulfur-nitrogen compounds whose ring system con- tains one or two other types of atoms in addition to sulfur and nitrogen. At least one sulfur atom can be regarded as having oxidation number IV in one resonance structure. That means the sulfur in fact has an oxidation number higher than 11 and lower than VI. The volume continues "Sulfur-Nitrogen Compounds" Part 2, in which the binary sulfur(lV)-nitrogen ring systems are described. Compounds with the same "hetero atom" in the sulfur-nitrogen ring are arranged in groups. Within a group the compounds are arranged according to ring size, and for a given number of ring atoms, in order of decreasing S: N ratio. Neutral compounds are described before ions, and saturated compounds before unsaturated, aromatic ones. A very heterogeneous material is brought together in this volume. SN Se2 rings, which 2 strongly resemble the binary S3N2 ring, are covered. S-N-Si rings with five, six, and eight atoms, and also N-S-N-bridged eight-membered rings, are described. The S-N-P rings form a puzzling and complex part of this volume; they readily interconvert by dimerization, cleavage, and by addition and loss of NSN and NPN groups. Especially interesting is the aromatic character of 8-N-P rings.

目次

Sulfur(IV)-Nitrogen-Element Ring Systems.- 1 S-N-O Ring Systems.- 2 S-N-Se Ring Systems.- 3 S-N-Si Ring Systems.- 4 S-N-P Ring Systems.- 5 S-N-As Ring Systems.- 6 S-N-Sn Ring Systems.- 7 S-N-Pb Ring System.- 8 Four and Five Atom S-N-C and S-N-C-O Ring Systems.- Table of Conversion Factors.

巻冊次

pt. 4 (gw) ISBN 9783540935537

内容説明

The rapid development of the sulfur-nitrogen chemistry during the last decades has yielded new compounds in such an amount that the edition of volumes dedicated to sulfur-nitrogen compounds is justified. Cyclic S-N compounds with sulfur of formal oxidation number IV containing C atoms, C and O atoms, or C and P atoms in the six-, seven-, eight-, or nine-membered ring systems are described. This volume concludes the description of cyclic compounds with Sulfur or Oxidation Number IV. In addition to the formula index, a ring index for parts 3 and 4 of S-N compounds facilitates finding specific ring systems, and also illustrates the puzzling manifold of the described ring system.

巻冊次

pt. 5 (gw) ISBN 9783540935995

内容説明

The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx. The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a !arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters."

巻冊次

pt. 6 (gw) ISBN 9783540936091

内容説明

This volume continues the description of acyclic sulfur(II)-nitrogen compounds with two-coordinate sulfur. N,N,N',N'-Tetraorganyl-substituted diaminosulfanes are generally prepared by reacting secondary amines with SCl2. N,N,N',N'-Tetraalkyl-diamino-sulfanes form adducts with boron compounds and complexes with transition metals. Carbon disulfide and various reagents of the X=C=Y type can be readily inserted into the S-N bonds. R2NSNR2 is reacted with CS2 to give R2NC(S)-Sn-C(S)NR2, n z 2. Reactions of R2NSNR2 with isocyanate and isothiocyanate, R'N=C=Y (Y = O,S), produce R2NSN(R')C(Y)NR2. The biological activity of diaminosulfanes with the appropriate substituents (e.g., R-OC(O), R = 2,2-dimethyl-2,3-dihydro-7-yl-benzofuran) has been explored.

巻冊次

pt. 7 (gw) ISBN 9783540936244

内容説明

Part of an encyclopaedic reference on inorganic and organometallic chemistry, this present volume continues a series on acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The description of sulfur-nitrogen compounds with 2-co-ordinate sulfur is continued with the sulfur diimides and sulfur diimide anions, their transition metal complexes, and radicals, cations and radical anions derived from sulfur diimides. The examination of sulfur diimides begins with the parent compound HN=S=NH, and the sulfur diimide anion [N=S=N]2-, whose potassium salt can act as a starting compound for the preparation of acyclic and cyclic sulfur diimides and their transition metal complexes. The following sections of the text deal with sulfur diimides bearing substituents at the nitrogen atoms which involve elements of the main groups VII to VIII. There are numerous examples of symmetrically and unsymmetrically N,N'-disubstituted sulfur diimides. The volume concludes with a detailed description of the class of N,N'-diorganyl-sulfur diimides, RN=S=NR'. The main importance of these compounds is their function as intermediates for organic synthesis.

巻冊次

pt. 8 (gw) ISBN 9783540936374

内容説明

This volume describes over 1250 acyclic sulfur-nitrogen compounds with three and four co-ordinate sulfur in the formation oxidation. It devotes much space to the description of the chemical and physical properties of DAST.

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詳細情報

• NII書誌ID(NCID): BA04033479
• ISBN:
  • 3540935126
  • 0387935126
  • 3540935444
  • 0387935444
  • 3540935533
  • 0387935533
  • 3540935991
  • 0387935991
  • 3540936092
  • 0387936092
  • 3540936246
  • 0387936246
  • 3540936378
  • 0387936378
• LCCN: 25001383
• 出版国コード: gw
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Berlin ; Tokyo
• ページ数/冊数: v.
• 大きさ: 26 cm
• 親書誌ID:
  • BA00215780