Interpretation of carbon-13 NMR spectra
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Bibliographic Information
Interpretation of carbon-13 NMR spectra
Wiley, 1988
2nd ed
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Description and Table of Contents
Description
This is the second edition of a very successful book which provides the conceptual and experimental basis for the interpretation of 13 C NMR spectra. Considerable emphasis has been placed on the various experimental methods and on the interpretation of spectral details which enable individual resonance lines to be associated with the various carbons in the molecule. The book benefits from the thorough teaching experience the authors have acquired in the large number of 13 C NMR workshops and seminars they have conducted at universities throughout Europe. With the advent of pulsed high-resolution NMR techniques some years ago, 13 C NMR has become one of the most powerful techniques for the organic chemist to tackle structural, stereochemical and conformational problems. Beyond these straightforward applications, 13 C NMR has proven its virtues in such domains as the characterization of synthetic and biological macromolecules, elucidation of reaction mechanisms and for the study of chemical and conformational equilibria.
The easy access to spin lattice relaxation measurements further widens the scope of 13 C spectroscopy by providing a further means to study structure and conformation. Here is a guide to the thorough interpretation of your 13 C NMR data.
Table of Contents
- Basic Principles: History of Carbon-13 NMR, Relaxation and Nuclear Overhauser Effect, Instrumental Requirements
- The Spectral Parameters: The Chemical Shift, Spin- Spin Coupling
- Experimental Techniques for Spectral Assignment: Summary of Methods, Proton Decoupling Techniques, Polarization Transfer and Related Experiments, Selective Excitation, Two- Dimensional Experiments, Carbon-Carbon Connectivity Experiments, Lanthanide Shift Reagents, Chemical Shift Comparison, Isotope Effect, Solid State 13 C NMR
- Nuclear Spin Relaxation: Correlation and Spectral Density Function, Dipole-Dipole Relaxation, Other Relaxation Mechanisms, Anisotropic Rotational Diffusion, Experimental Techniques for the Measurement of T 1, and the Nuclear Overhauser Effect (NOE), Temperature and Concentration Dependence of the Rotational Correlation Time, Relative Contributions from Individual Relaxation Mechanisms
- Applications: Structure Elucidation of Organic Molecules, Dynamic Processes, Conformational Analysis, 2-D Techniques for the Elucidation of Exchange, Rotamer Equilibria, Macromolecules, Solid-State 13 C NMR Applications, Mechanistic Studies, Spin- Lattice Relaxation and Nuclear Overhauser Studies, Quantitative, Analysis.
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