Quantum description of high-resolution NMR in liquids

著者

書誌事項

Quantum description of high-resolution NMR in liquids

Maurice Goldman

（International series of monographs on chemistry, 15）

Clarendon Press , Oxford University Press, 1988

  • : hbk
  • : pbk

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注記

Includes index

内容説明・目次

内容説明

This is a study of the main methods of one- and two-dimensional high-resolution NMR spectroscopy in liquids within the quantum-mechanical formalism of the density matrix, aimed particularly at those scientists who do not have a working knowledge of quantum calculations. This knowledge is provided in the first part of the book through a description of quantum mechanics as applied to spin systems: this description is both self-contained and limited to the essentials. A final chapter is devoted to the principles of relaxation theory. The book aims to give the reader enough practice in the theoretical tools of NMR to enable him to analyze critically comprehensive treatises or articles on new methods.

目次

  • Part 1 Elementary description of NMR: classical description of NMR
  • quantum description of NMR
  • relation between pulsed and CW NMR. Part 2 Epitome of quantum mechanics: the principles of quantum mechanics
  • vectors and operators in Hilbert space
  • some properties of operators
  • hermitian and unitary operators
  • relation with physics. Part 3 Spin and magnetic moment: angular momentum
  • the spin 2 1
  • spins larger than 2 1
  • examples of manipulation of spin operators
  • the nuclear magnetic moment. Part 4 Quantum statistical mechanics: the density matrix
  • the central limit theorem. Part 5 Quantum description of NMR: spins subjected to the sole Zeeman interaction
  • chemical shifts and indirect interactions. Part 6 Generalities on 2D spectroscopy - J spectroscopy: the double Fourier transform method
  • J spectroscopy. Part 7 Shift correlation spectroscopy: heteronuclear correlation spectroscopy
  • homonuclear correlation spectroscopy. Part 8 Multiple quantum coherence and applications: multiple quantum spectroscopy
  • multi-Q-filtered COSY
  • indirect interactions in 13C spin pairs - the method INADEQUATE
  • cross-relaxation spectroscopy - the method NOESY. Part 9 Fundamentals of relaxation theory: general features of relaxation
  • the master equation of relaxation
  • dipolar relaxation
  • other mechanisms of relaxation. References. Index.

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