Bibliographic Information

Vibronic interactions in molecules and crystals

I.B. Bersuker, V.Z. Polinger

(Springer series in chemical physics, v. 49)

Springer-Verlag, c1989

  • : us
  • : gw

Other Title

Vibronnye vzaimodeĭstvii︠a︡ v molekulakh i kristallakh

Vibronnuie vsaimodeistviya v molekulakh i kristallakh

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Note

Translation of: Vibronnye vzaimodeĭstvii︠a︡ v molekulakh i kristalakh

"This edition is an updated version of the original Russian edition: Vibronnuie vsaimodeistviya v moledulakh i kristallakh"--T.p. verso

Bibliography: p. [397]-418

Includes index

Description and Table of Contents

Description

Vibronic interaction effects constitute a new field of investigation in the physics and chemistry of molecules and crystals that combines all the phenomena and laws originating from the mixing of different electronic states by nuclear displacements. This field is based on a new concept which goes beyond the separate descriptions of electronic and nuclear motions in the adiabatic approximation. Publications on this topic often appear under the title of the lahn-Thller effect, although the area of application of the new approach is much wider: the term vibronic interaction seems to be more appropriate to the field as a whole. The present understanding of the subject was reached only recently, during the last quarter of a century. As a result of intensive development of the theory and experiment, it was shown that the nonadiabatic mixing of close-in-energy elec tronic states under nuclear displacements and the back influence of the modified electronic structure on the nuclear dynamics result in a series of new effects in the properties of molecules and crystals. The applications of the theory of vibronic in of spectroscopy [including visible, ultraviolet, in teractions cover the full range frared, Raman, EPR, NMR, nuclear quadrupole resonance (NQR), nuclear gam ma resonance (NOR), photoelectron and x-ray spectroscopy], polarizability and magnetic susceptibility, scattering phenomena, ideal and impurity crystal physics and chemistry (including structural as well as ferroelectric phase transitions), stereochemistry and instability of molecular (including biological) systems, mechanisms of chemical reactions and catalysis."

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Details

  • NCID
    BA0733968X
  • ISBN
    • 038719259X
    • 354019259X
  • LCCN
    88016100
  • Country Code
    gw
  • Title Language Code
    eng
  • Text Language Code
    eng
  • Original Language Code
    rus
  • Place of Publication
    Berlin ; Tokyo
  • Pages/Volumes
    xii, 422 p.
  • Size
    25 cm
  • Classification
  • Subject Headings
  • Parent Bibliography ID
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