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9 : gw ISBN 9783540935902
内容説明
Organometallic compounds have been attracting a great deal of attention. They have a practical importance, and the work on these compounds has raised and answered significant theoretical questions. A few years ago the Gmelin-Institute initiated three series on organoiron compounds. Series A describes ferrocene and its derivatives, Series B describes the mononuclear compounds, and Series C describes the compounds with two or more iron atoms per molecule. Some volumes have been published in each of these series and further volumes are on the way. This volume continues the description of unbridged disubstituted ferrocenes, FeC10H8R1R2, by treating compounds in which at least R1 contains N, S, Se, B, or Si. The description of the unbridged disubstituted ferrocenes was initiated with in "Eisen-Organische Verbindungen A, Ferrocene 7 (starting with R1 and R2 containing C and H, and at least R1 containing halogen and continuing with compounds containing at least O and R1 to form alcohols and phenols, their esters, ethers, acetals, and aldehydes), and was followed by "Organoiron Compounds" A, Ferrocene 8 (with at least R1 containing O). Ferrocene 8 contains the formula index for the compounds covered in the volumes Ferrocene 7 and 8. "Organoiron Compounds" A, Ferrocene 9 systematically covers the literature through the end of 1986 and even includes some references published more recently. A formula index provides ready access to the compounds covered. Series A so far comprises volumes A 1 to A 9, and it has been surveyed in the preface to A 7 (1980).
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10 : gw ISBN 9783540936404
内容説明
This volume covers all of the chemical, physical and catalytic properties of over 1000 mononuclear unbridged di-and tri-substituted ferrocenes. Central chiral nomenclature is employed for optically active compounds. It describes di-and tri-substituted ferrocenes with P-containing substituents. Their importance is based on their ability to influence the course of synthetic reactions for organic compounds as ligands of transition metal complexes, particularly for Ni, Co, Rh and Pd complexes. The chiral ferrocenylphosphines are of special interest in that their optically active forms catalyze asymmetric syntheses in which compounds of high optical purity can be obtained (up to >90% ee).
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11 : gw ISBN 9783540937098
内容説明
Part of an encyclopaedic reference on inorganic and organometallic chemistry, this volume decribes the mononuclear, unbridged, tetra- to decasubstituted ferrocenes. Information on all chemical, physical and catalytic properties is given. The decasubstituted compounds represent the mostly examined group of compounds with Fe(C5(CH3)5)2 and its salts as the main substances, followed by the tetrasubstituted compounds.
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