Complexes in free-radical polymerization
Author(s)
Bibliographic Information
Complexes in free-radical polymerization
（Polymer science library, 6）
Elsevier, 1988
- Other Title
-
Komplexy v radikálovej polymerizácii
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Note
Bibliography: p. [245]-268
Includes indexes
Translation copyright: Alena Rebrova
Description and Table of Contents
Description
The last twenty years have seen an enormous growth in the number of studies on the role of complexes in free-radical polymerization. New possibilities for polymerization initiation and the significant influence on the kinetics of the elementary polymerization reactions, such as propagation, chain transfer, and termination, are the main areas which have attracted attention from specialists in this field. The most important breakthrough has probably been made in the regulation of free-radical polymerization by various complex-forming substances. Advances in this area have not only contributed to the better understanding of the kinetics and mechanism of radical chain reactions, but they have also created a background for the solution of some practical problems associated with the synthesis of new polymeric materials. This volume provides a survey of the latest achievements in the field of free-radical polymerization. The scope of the volume permits the presentation of these extensive problems in a concise form only, nevertheless it contains an invaluable source of information on topical questions relating to the participation of complexes in free-radical polymerization.
Table of Contents
I. Complexes in Initiation Reactions of Radical Polymerization. Initiating systems based on metal compounds. One-component systems. Metal complexes and metal chelates. Metal salts. Two-component and multi-component systems based on metal compounds. Special initiating systems. Initiating systems based on complexes of organic compounds. Effect of complexes and complex formation on the kinetics and mechanism of the decomposition of peroxides, hydroperoxides and azo-compounds. Diacyl peroxides and dialkyl peroxides. Dibenzoyl peroxide. Other diacyl peroxides. Dailkyl peroxides. Hydroperoxides. Azo-compounds. 2,2 1 -Azoisobutyronitrile. Other azo-initiators. II. Complexes in the Propagation Step of Radical Homopolymerization and Copolymerization. Monomer-solvent and propagating radical-solvent complexes. Monomer-Lewis acid and propagating radical-Lewis acid complexes. Donor-acceptor complexes of electron-acceptor and electron-donor monomers. Complexes between polymers and monomers. Metal complexes with coordinatively bound monomer. III. Effect of Complexes on Termination, Chain Transfer, Inhibition and Retardation Reactions. Termination reactions. Methacrylates, acrylamide, acrylonitrile, acrylic acid and methacrylic acid. Other vinyl monomers. Termination in ``living radical polymerization'' and in grafting by alternating copolymer. Transfer reactions. Effect of complexes on transfer reactions in radical homopolymerization. Effect of complexes on transfer reactions in radical copolymerization. Retardation and inhibition reactions. References. Author Index. Subject Index.
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