Calixarenes
著者
書誌事項
Calixarenes
（Monographs in supramolecular chemistry, no. 1）
Royal Society of Chemistry, 1989
- : hbk
- : pbk
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内容説明・目次
- 巻冊次
-
: pbk ISBN 9780851863856
内容説明
The aim of this volume is to provide researchers with a complete survey of the chemistry of the molecular baskets called calixarenes. Historical vignettes and biographies of those responsible for early research in the field have been included in the text.
目次
- Part 1 From resinous tar to molecular baskets: the resinous tar
- glistening crystals - the Zinke products
- more crystals - the Niederl products
- cyclic tetramers - proofs of structure
- the petrolite chapter
- cyclic tetramers and the quest for enzyme mimics
- unraveling the literature
- nomenclature of the calixarenes. Part 2 Making the baskets - synthesis of calixarenes: procedures for one-step base-induced syntheses
- procedures for one-step acid-catalyzed synthesis of calixarenes
- procedures for one-step formation of calixarenes under neutral conditions
- multi-step synthesis of calixarenes
- mechanisms of calixarene-forming reactions
- homocalixarenes, oxacalixarenes and homooxacalixarenes
- heterocalixarenes. Part 3 Proving the baskets - the characterization and properties of calixarenes: x-ray crystallography - the ultimate proof of structure
- proof of structure by chemical interconversion
- physical properties of calixarenes
- spectral properties of calixarenes
- TLC and HPLC analysis of calixarenes. Part 4 Shaping the baskets - conformations of calixarenes: conformations of flexible calixarenes in the solid state
- conformations of flexible calixarenes in solution
- resorcinol-derived calixarenes
- conformations of non-hydroxylic calixarenes
- conformationally immobile calixarenes
- the conformations of calixarene oxyanions. Part 5 Embroidering the baskets - reactions of calixarenes and introduction of functional groups: reactions at the "lower rim" of the calix
- reactions at the "upper rim" of the calix
- oxidation reactions of calixarenes. Part 6 Filling the baskets - complex formation with calixarenes: solid state complexes
- solution state complexes in nonaqueous solvents
- solution state complexes of water-soluble calixarenes. Part 7 Using the baskets - calixarenes in action: the patent literature of calixarenes
- calixarenes in industry
- calixarenes as complexers of neutral compounds
- calixarenes as catalysts and biomimics
- calixarenes as physiological compounds.
- 巻冊次
-
: hbk ISBN 9780851869162
内容説明
Calixarenes was the first book to be published in the `Monographs in Supramolecular Chemistry' series and is also the first complete survey available of this rapidly developing field. It provides a fascinating and lively account of the history, development and applications of calixarenes, which are probably the world's most readily available synthetic molecular baskets. These basket shaped compounds possess the ability to hold metal ions, as well as molecules, in their interior and as a result of their extraordinarily easy synthesis from phenols and aldehydes are receiving increasingly wide attention. This book is a must for advanced undergraduates and post-graduates studying bio-organic and supramolecular chemistry.
目次
- From Resinous Tar to Molecular Baskets
- Making the Baskets: Synthesis of Calixarenes
- Proving the Baskets: The Characterization and Properties of Calixarenes
- Shaping the Baskets: Conformations of Calixarenes
- Embroidering the Baskets: Reactions of Calixarenes and Introduction of Functional Groups
- Filling the Baskets: Complex Formation with Calixarenes
- Using the Baskets: Calixarenes in Action
- Subject Index.
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