Colloid chemistry of polymers
著者
書誌事項
Colloid chemistry of polymers
（Polymer science library, 7）
Elsevier, 1988
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注記
Includes bibliographies and index
内容説明・目次
内容説明
This book is a physical chemist's approach to polymers and, as such, takes a unique and intermediate position between physical and polymer chemistry. Intended primarily as an introduction to the study of the subject, it analyses the range of problems encompassed by the colloid chemistry of polymers with the aim of clarifying the most important advances and providing an overview of the general state of the art.
目次
- 1. General Colloid Chemistry of Polymers. General. Dispersion in colloidal polymer systems. 2. Microheterogeneous Structure of One- and Multi-Component Polymer Substances. Modern concepts of the structure of amorphous polymers. Structural heterogeneity of polymers. 3. Structure Formation in Disperse Polymer Systems. Thermodynamics of the formation of particles of a new phase. Theory of spinodal decomposition. Phase separation in polymer systems. Dissipative processes as a cause of microheterogeneity in polymer systems. 4. Surface Tension in Disperse Systems. Surface tension of solutions. Surface tension of polymer melts. Surface tension of solid polymers. 5. Surface-Active Properties of Polymers and the Influence of Low-Molecular-Mass Surfactants on the Properties of Disperse-Polymer Systems. Polymers as surfactants. Influence of surfactants on the properties of oligomers and polymers. Influence of surfactants on the strength and destruction of polymers. 6. Adsorption of Polymers on Solid Surfaces. Adsorption from dilute solutions. Isotherms of polymer adsorption from dilute solutions. Aggregation mechanism of adsorption. Some features of polymer adsorption kinetics on highly dispersed adsorbents. The role of adsorption layers of polymers in stabilizing disperse systems. Adsorption from polymers blends. 7. Polymer Adhesion. Thermodynamic description. Adhesion strength. Adhesion theory. Mechanism of adhesion joint formation. Internal stresses in adhesion joints. Colloid-chemical approaches to the increase of adhesion strength. 8. Structure and Properties of Surface and Interfacial Polymer Layers. Surface layers of polymer phases. Surface layers of polymers on the surface of solids. Interfacial layers in heterogeneous mixtures of polymers. Features of the interfacial region structure in polymer mixtures. Microheterogeneity of surface layers. Monomolecular layers of polymers. 9. Filled Polymers as Disperse Systems. General. Structure formation in polymers in the presence of dispersed fillers. Mechanical properties of filled polymers. Rheological properties of filled polymers. Surface modifications of fillers. Mechanisms of reinforcing action of fillers in polymers. Polymers filled with colloidal metals. 10. Colloidal Mixtures of Polymers. Theoretical concepts of mixing and compatability of polymers. Empirical determination of polymer compatability. Features of diagrams of the state of binary mixtures. Rheological properties of binary mixtures. 11. Colloid-Chemical Features of Polymer-Polymer Systems. Separation of polymer-polymer systems. Thermodynamics of the formation of stable dispersion systems. Dispersity of polymer-polymer compositions. Colloidal and chemical structure of polymer-polymer systems. 12. Gelation of Solutions
- Polymer Gels. Classification of polymer gels. Gel-formation conditions. Mechanism of gel-formation processes and structure of polymer gels. Phase state of polymer gels. Polymer gels as disperse colloidalsystems. 13.
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