Solubility behavior of organic compounds
著者
書誌事項
Solubility behavior of organic compounds
（Techniques of chemistry, v. 21）
Wiley, c1990
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注記
Bibliography: p. 547-577
Includes indexes
内容説明・目次
内容説明
This book explains the various factors, particularly the chemical nature of the molecules, which influence and control the solubility of an organic compound in a particular solvent, especially organic solvents, mixed organic solvents, water and aqueous solutions. The book also explains how to predict the solubility of an organic compound in the solvents mentioned above. Furthermore, the book similarly treats the partition (distribution) coefficient of an organic compound between two relatively immiscible solvents. Thus solubility behaviour comprises both solubility and partitioning between two solvents. This book provides an understanding of concepts of solubility behaviour and practical means for predicting solubilities, partition coefficients and dissolution rates.
目次
- Solubility, Intermolecular Forces, and Thermodynamics
- Activities of Solutes, Selection of Standard State and Henry's Law Constants
- Specific Interactions in Solubility Phenomena
- Influence of Complexation, Especially Hydrogen Bonding, on Solubility in Organic Solvents: Prediction of Association Constants
- Structure of Solvents and Effects of Self-Association on Solubility
- Group Contributions in Prediction
- Solubility in and Partitioning into Water
- Ion Pairs and Solubility Behavior
- Phase-Solubility Analysis and Complexation in Aqueous Solution
- Dissolution Rates of Solids
- Afterword
- References
- Author Index
- Subject Index.
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