Olefin metathesis and polymerization catalysts : synthesis, mechanism, and utilization
著者
書誌事項
Olefin metathesis and polymerization catalysts : synthesis, mechanism, and utilization
(NATO ASI series, Series C,
Kluwer, c1990
- : alk. paper
大学図書館所蔵 全7件
  青森
  岩手
  宮城
  秋田
  山形
  福島
  茨城
  栃木
  群馬
  埼玉
  千葉
  東京
  神奈川
  新潟
  富山
  石川
  福井
  山梨
  長野
  岐阜
  静岡
  愛知
  三重
  滋賀
  京都
  大阪
  兵庫
  奈良
  和歌山
  鳥取
  島根
  岡山
  広島
  山口
  徳島
  香川
  愛媛
  高知
  福岡
  佐賀
  長崎
  熊本
  大分
  宮崎
  鹿児島
  沖縄
  韓国
  中国
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  イギリス
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注記
"Proceedings of the NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts, Alcay, Turkey, September 10-22, 1989"--T.p. verso
"Published in cooperation with NATO Scientific Affairs Division."
Includes bibliographical references and index
内容説明・目次
内容説明
Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has been drawn to the metal-carbene and metallacyclobutane complexes as active species, the initiation mechanisms, the stereochemistry and thermodynamics of these reactions. New catalytic systems for the metathesis of alkenes and alkynes and fot' ring opening polymeriZation I block copolymerization reactions have been introduced. Spectroscopic studies for the characteriZation of catalysts, simulation studies explaining the function of chain carrier species and polymer degradation have also been covered. A detailed industrial report concerning the patents and applications in olefin metathesis I cyc1001efin polymerization area, fabrication and derivation has been presented. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay. Babkesir. Turkey between 10th and 22nd September 1989.
目次
- Overture: Olefin Metathesis and Metathesis Polymerization. A Historical Perspective.- The Stereochemistry of Metathesis of Acyclic and Cyclic Olefins.- Electrochemical Generation of Catalysts for Alkene Metathesis.- Catalysts for the Homogeneous Metathesis of Functionalized Olefins.- Block Copolymers by Anionic to Metathesis Transformation Reactions.- The Kinetics of Polymerization of Cyclopentene.- Tacticity in Polymers Initiated by Metathesis Polymerization: Effect of Catalyst.- Degradation of Polymers by Metathesis Catalysts.- Metathesis Polymerization by Homogeneous Catalysts
- Simulations.- General Properties of Supported Metathesis Catalysts.- Surface Functionalization of Supported Catalysts.- Novel Supported Catalysts for Terminal Alkene Metathesis.- Characterisation of Rhenium Oxide/Alumina Metathesis Catalysts.- Stoichiometric Reactions with Reduced Phillips Catalysts.- Catalytic Reactions with Reduced Phillips Catalysts.- Non-Chromium Surface Compounds.- Coordination Chemistry of Silica Supported Cr Ions: Types of Cr(II) Ions on Reduced Samples.- Structural Analysis of Supported Chromium Systems.- Industrial Aspects of Olefin Metathesis/Polymerization Catalysts.- Syntheses of Heterogeneous, Bimetallic Metathesis Catalysts by Reactions of Fischer Type Carbene and Carbyne Complexes with Reduced Phillips Catalyst.- New Results on Alkene Metathesis and Alkyne Polymerisation with Heterogeneous Carbene Tungsten(VI) Complexes.- Aqueous Ring-Opening Metathesis Polymerizations of 7-Oxa-norbornene Derivatives Using Ruthenium Catalysts.- The Application of Ring Opening Metathesis Polymerization to the Synthesis of Substituted Polyacety lenes.- Raman Spectroscopy of Surface Rhenium Oxide on Alumina, Silica, Titania, Niobia and Magnesia.- Raman Spectroscopy of Chromium Oxide Supported on Alumina, Titania and Silica: A Comparative Study.- Stoichiometric and Catalytic Carbene Complex Reactions with the Reduced Phillips Catalyst.- Metathesis-Like Reactions of Heteroalkenes and Heteroallenes with the Carbyne Complex Cl3(dme)W=CCMe3.- Catalytic Metathesis of Alkynes.- Electrochemical Synthesis of Catalytic Species for Alkene Metathesis.- Chromium Supported Catalysts for Ethylene Gas Phase Polymerization.- Metathetical Degradation of Sulfur Vulcanized Polybutadiene by W(CO)6/CCl4/hV.- Photocatalytic Ring-Opening Polymerization of Norbornene and Norbornadiene and Cyclopentene.
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