Properties and applications of glass
Author(s)
Bibliographic Information
Properties and applications of glass
(Glass science and technology, v. 3)
Elsevier Scientific Pub. Co. , distributor for the U.S. and Canada, Elsevier, North-Holland, 1980
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Note
ISBN:0444423214 --- 2nd. impression.
Bibliography: p. 292-306
Includes indexes
Description and Table of Contents
Description
In this book the author summarizes the present state of knowledge of those physical and chemical properties of glasses that are important as regards their application and manufacture. The nature of these applications is briefly described. The introductory chapter deals with the nature and chemical composition of inorganic glasses, covering such topics as structure, devitrification and phase separation. The main part of the book comprises a group of chapters describing the important physical properties: viscosity, thermal expansion, mechanical strength, refractive index and dispersion, absorption of radiation and electrical properties. The final chapter deals with chemical durability. Most chapters deal briefly with methods of measurement of the property concerned and with the effects of glass composition, temperature, heat treatment, etc. Wherever appropriate, the scientific principles relevant to particular applications are discussed. Sufficient references to the literature are given to enable the reader to follow up in more detail the various topics discussed.
Table of Contents
1. Some Aspects of the Nature of Inorganic Glasses. Definition of the term ``Glass''. The transformation range. The chemical nature of inorganic glasses. Devitrification. Immiscibility in melts and glasses. The structure of oxide glasses. II. Viscosity. Definition. Viscosity values. Analysis of some simple problems in viscous laminar flow. Measurement of viscosity. Variation of viscosity with temperature. Flow properties in the transformation range. Effects of glass composition. III. Thermal Expansion. The shape of the thermal expansion curve. Methods of measurement. Effects of glass composition. Stresses in glass seals. Thermal stresses. Annealing. Measurement of internal stresses in glassware. IV. The Strength of Glass. The theoretical strength of glass. Effect of surface flaws on the strength of glass - the Griffith equation. Methods for measuring glass strength. High strength glass surfaces. Damage to glass surfaces. Factors affecting the strength of damaged surfaces. Increasing the strength of glass. V. The Strength of Glassware. Determination of service stresses. The simulated service testing of glass containers. Fracture analysis. VI. Refractive Index and Dispersion. Introduction. Refractive index. Dispersion. Optical glasses. The significance of optical properties in lens design. Glass optical fibres. VII. The Absorption of Radiation by Glasses. Introduction. Units and nomenclature. Transition metal ion colours. The absorptivity of oxide glasses in the UV. Colloidal colours. Absorption in the IR. Decolourizing of commercial glasses. Laser glasses. VIII. Electrical Properties. Introduction. Ionically conducting glasses. Semi-conducting glasses. Dielectric loss in oxide glasses. IX. Chemical Durability. Introduction. Weathering. Reactions of silicate glasses with aqueous solutions. Standard tests for chemical durability. Methods of improving the durability of glassware or reducing the attack by specific reagents. References. Author Index. Subject Index.
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