Ring enlargement in organic chemistry
著者
書誌事項
Ring enlargement in organic chemistry
VCH, c1991
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注記
Includes bibliographical references and indexes
内容説明・目次
内容説明
Ring enlargement reactions are important not only for the synthesis of natural compounds and pharmaceuticals but also for their substantial role in organic synthesis. This book summarizes the methodology of ring enlargement of heteroatom rings. The nine chapters are arranged according to reaction type, enabling easy access to the information.
目次
- One-atom insertion procedures
- the three-membered ring - a building element for ring enlargement reactions
- ring expansion from four-membered rings or via four-membered intermediates
- the cope rearrangement, the (1.3) sigmatropic shift, the Sommelet-Hauser reaction, and sulfur mediated ring expansion
- transamidation reactions
- ring enlargement by side chain incorporation
- ring expansion by cleavage of the zero bridge in bicycles
- cleavage of the one-atom bridge in bicycles and transesterification.
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