Intramolecular motion and chemical reaction : proceedings of a Royal Society Discussion Meeting, held on 14 and 15 February 1990
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書誌事項
Intramolecular motion and chemical reaction : proceedings of a Royal Society Discussion Meeting, held on 14 and 15 February 1990
Royal Society, 1990
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注記
Includes bibliographical references
内容説明・目次
内容説明
Until recently intramolecular motions were regarded either as completely orderly, when undergoing small amplitude vibrations, or completely chaotic, when dissociating. The immediate energy region was experimentally inaccessible but modern laser techniques have transformed the situation to the extent that we can now begin to understand the dynamical processes responsible for internal energy transfer and chemical reaction. This volume, which reports the proceedings of a Royal Society discussion meeting held in February 1990, includes accounts of femtosecond pulse experiments, stimulated emission pumping, state-selected intramolecular vibrational relaxation and photodissociation, and stereochemical alignment studies. Definitive quantum mechanical calculations, close to and and beyond the onset of classical chaos are also reported and new ideas for the spectroscopic assignment in the classical chaotic regime are outlined.
目次
- Pathways for intramolecular relaxation in S1 benzene, E. Riedle et al
- the role of quantum intramolecular dynamics in unimolecular reactions, Martin Quack
- recent developments in classical mechanics (abstract only), I.C. Percival
- femtochemistry of the reaction of IhgI - theory versus experiment, M. Gruebele et al
- photofragment mapping of intramolecular motion, M. Brouard et al
- state- and bond-selected photodissociation and bimolecular reaction of water, F.F. Crim et al
- unimolecular dissociation - an eigenchannel generalized quantum view, M.S. Child
- unimolecular reactions, rates and quantum state distribution of products, R.A. Marcus
- the high-resolution spectroscopy of dissociating molecules, C.B. Moore et al
- variational calculations of rovibrational states - a precise high-energy potential surface for HCN, Stuart Carter et al
- highly excited rovibrational states of small molecules, Jonathon Tennyson et al
- periodic orbit assignment for spectra of highly excited molecular systems, Eli Pollak
- entrance channel stereospecifity of photointiated H-atom reactions in weakly bonded complexes, Seung Koo Shin et al
- stereochemical and angular momentum constraints in the photodissociation of ammonia, M.N.R. Ashfold et al.
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