Transition metal nuclear magnetic resonance
著者
書誌事項
Transition metal nuclear magnetic resonance
(Studies in inorganic chemistry, 13)
Elsevier , Distributors for the U.S. and Canada, Elsevier Science Pub. Co., 1991
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Transition metal NMR spectroscopy has progressed enormously in recent years. New methods, and specifically solid-state methods and new pulse sequences, have allowed access to data from nuclei with relatively low receptivities with the result that chemists have begun to consider problems previously inaccessible. Moreover, theory, and computational science in particular, now permits the calculation of not just 13C, 15N and other light nuclei chemical shifts, but also heavy main-group elements and transition metals. This, combined with increasing access to high field pulsed spectrometers has produced a wealth of new data on NMR of transition metals.
This book contains a collection of review articles concerned with measuring, understanding and using the nuclear magnetic resonance spectra of the metals of Groups 3-12. The reader is provided with a view on how these nuclei are currently being approached, and what information can be obtained. The authors have liberally reproduced spectra as well as correlations relating metal-NMR data to different physical characteristics of their molecules.
目次
Groups 3-5. Scandium to Tantalum (D. Rehder). Group 6. Chromium to Tungsten (C. Brevard, P.S. Pregosin and R. Thouvenot). Group 7. Manganese to Rhenium (P.S. Pregosin). Group 8. Iron to Osmium (R. Benn). Group 9. Cobalt and Rhodium (B.E. Mann and P.S. Pregosin). Group 10. Nickel to Platinum (P.S. Pregosin). Groups 11 and 12. Copper to Mercury (P. Granger). Index.
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