Synthesis and characterization of oligomers
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書誌事項
Synthesis and characterization of oligomers
CRC Press, c1991
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
This book provides an excellent introduction to the fundamentals of oligomer chemistry. Each section describes the synthesis, separation, physico-chemical characterization, and present and future applications of individual classes of oligomers organized according to the chemical structure of the main chain. In addition, this book features up-to-date references from both journals and patents and an extensive appendix covering synthesis and characterization methods of oligomeric derivatives. Synthesis and Characterization of Oligomers is a broad, state-of-the-art survey and will be useful not only for students and professionals working with oligomers, but also chemists who are new to the field.
目次
GENERAL CONSIDERATIONS. Historical. Applications. Origins and Nomenclature. GENERAL METHODS FOR THE SYNTHESIS OF OLIGOMERS. RADICAL OLIGOMERIZATION. Radical Oligomerization Initiated by Chemical Agents. Radical Oligomerization Initiated by Physical Means. Telomerization. OLIGOCONDENSATION. Introduction. Functionality. Molecular Weight Distribution. Origins of Oligomers in Step-Growth Reactions. Synthesis of Individual Oligomers. IONIC OLIGOMERIZATION. Basic Principles of Ionic Oligomerization. Cationic Oligomerization. Oligomerization by Coordinative and Miscellaneous Mechanisms. CHARACTERIZATION. SOLUBILITY OF OLIGOMERS. General Considerations. MOLECULAR WEIGHT AND STRUCTURE-MOLECULAR WEIGHT RELATIONSHIP. Introduction. Molecular Weight. Functionality. Structure-Functionality-Molecular Weight Relationship. OLIGOMER FRACTIONATION. Oligomer Fractionation by Solubility Methods. Oligomer Fractionation by Gel Permeation Chromatography. Oligomer Fractionation by Liquid Chromatographic Methods. Determination of the Structure and of the Chemical Composition of Oligomers. Dielectric Properties. Thermal Properties of Oligomers. INDEX.
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