書誌事項

Surface science of catalysis : in situ probes and reaction kinetics

Daniel J. Dwyer, editor, Friedrich M. Hoffmann, editor

(ACS symposium series, 482)

American Chemical Society, 1992

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注記

"Developed from a symposium sponsored by the Division of Colloid and Surface Chemistry at the 201st National Meeting of the American Chemical Society, Atlanta, Georgia, April 14-19, 1991."

Includes bibliographical references and indexes

内容説明・目次

内容説明

Presents an excellent overview of the impact of surface science on the field of catalysis. Explores the exciting new advances in surface science and catalysis, which for the first time allow for direct spectroscopic and kinetic observation of surface reactions. Twenty-two chapters cover fundamental aspects of catalytic reactions at surfaces, applications of surface probes to the study of catalytic reactions and kinetics, and novel aspects of catalytic reactions at surfaces. Highlights the success of surface science techniques in the study of industrially important catalytic processes, including hydrogenation of CO to produce hydrocarbons and methanol, the oxidation of methane to methanol, and conversions of CO to carbon dioxide.

目次

  • The Promise of Surface Science in Catalysis: Success or Failure?
  • Molecular-Beam Studies of the Effect of Surface Temperature on the Probability of Dissociative Chemisorption
  • New Molecular-Beam Methods for Coverage-Dependent Kinetic Measurements Using Time-Resolved Specular Helium Scattering
  • Kinetics and Mechanism of Carbon Monoxide Oxidation on Platinum, Palladium, and Rhodium Foils
  • Infrared Reflection-Absorption Spectroscopy: New Technique for In Situ Determination of Local Surface Structure
  • Nickel Monoxide Surface Films on Ni(100): High-Temperature Structure, Thermal Stability, and Reactivity Toward Hydrogen
  • Building of Complex Catalysts on Single-Crystal Surfaces
  • Forward and Reverse Water-Gas Shift Reactions on Model Copper Catalysts: Kinetics and Elementary Steps
  • Carbon Monoxide Oxidation on Model Single-Crystal Catalysts
  • Molecular Ingredients of Platinum-Tin Reforming Catalysts
  • Controlled-Atmosphere Photoelectron Spectroscopy
  • Ultrasoft X-ray Absorption Detected by Fluorescence Yield: In Situ Method for Characterizing Adsorbates and Surface Reactions
  • In Situ Studies of Catalytic Reactions with Fourier Transform-Infrared Reflection-Absorption Spectroscopy: Island Formation and Stability of Ultrathin Layers at High Pressure
  • NMR Studies of the Structures and Reactions of Simple Molecules Adsorbed on Metal Clusters
  • In Situ Surface Kinetics by Dynamic Isotopic Tracing: Application to Methane Oxidative Coupling
  • Infrared Study of Surface Species Under High-Pressure Conditions
  • Effect of Structure in Propylene Oxidation on Molybdenum Trioxide
  • Chemical Reactions in High Electric Fields
  • Surface Reactions on an Atomic Scale: Field Desorption with Field and Photon Pulses
  • Mass Effects in Photodissociation of Chloromethane: Quenching by Substrate Metal
  • Photoinduced Pathways to Dissociation and Desorption of Dioxygen on Ag(110) and Pt(111)
  • Time-Resolved Study of Laser-Induced Thermal Desorption

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