Determination and use of stability constants
著者
書誌事項
Determination and use of stability constants
VCH Publishers , VCH Verlagsgesellschaft, c1992
2nd ed
- : us
- : gw
- : Wiley-VCH
大学図書館所蔵 全22件
注記
Includes bibliographical references
内容説明・目次
- 巻冊次
-
: Wiley-VCH ISBN 9780471188179
内容説明
This book describes potentiometric methods for determining stability constants and explains how these constants can be used to describe metal ion speciation in complex environmental and biological systems. It also provides three original computer programs on a disk for calculating stability constants and for using stability constants to calculate concentrations of molecular species in solution.
The author gives examples of calculations for simple metal chelates, for metal complexes of large organic molecules, and for mixtures containing several metal ions and complexing agents in aqueous solution. They also describe common errors in calculating stability constants and how to avoid them.
This carefully revised second edition is now even more useful to the reader, and, in particular, to those who make use of the program disk. Each program has been revised to improve speed, control, and error trapping.
目次
Introduction/
Equilibrium constants, protonation constants, formation constants/
Experimental methods for measuring equilibrium constants/
Experimental procedure for potentiometric p(H) measurement of metal complex equilibria/
Common errors and their elimination or minimization/
Examples of stability constant determination/
Macroscopic and microscopic constants/
Determination of stability constants and species concentration of complex systems/
Critical stability constants and their selection/
Development of a complete critical metal complex data base
- 巻冊次
-
: gw ISBN 9783527895168
内容説明
This work aims to serve as a useful manual for those beginning to work with metal complexes in solution and to establish uniform guidelines for those already engaged in the measurement and use of metal complex stability constants. It describes new developments like the use of graphic illustrations to test the self-consistency of calculated results. Descriptions are provided for the development and use of a comprehensive database applicable to the determination of individual molecular species in multicomponent systems of the type found in the environment, biological fluids and other complex natural systems.
「Nielsen BookData」 より