書誌事項

Catalysis in polymer synthesis

Edwin J. Vandenberg, editor, Joseph C. Salamone, editor

(ACS symposium series, 496)

American Chemical Society, 1992

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注記

"Developed from a symposium sponsored by the Division of Polymeric Materials: Science and Engineering at the 201st National Meeting of the American Chemical Society, Atlanta, Georgia, April 14-19, 1991"

Includes bibliographical references and indexes

内容説明・目次

内容説明

Examines the role of catalysis in applied polymer developments, focusing on metal catalysis of olefins, epoxides, oxetanes, cyclic phosphazenes, and cyclic silanes. Provides discussion of metal catalyzed coordination polymerization of olefins and diolefins and ring opening coordination polymerization of epoxides and oxetanes. Covers recent developments on anionic and cationic polymerization. Places particular emphasis on early and recent developments on propylene polymerization as related to isotactic and syndiotactic propylene. Provides a review of the work of E.J. Vandenberg, recipient of the 1991 ACS Award in Applied Polymer Science, in olefin, epoxide, and oxetane polymerization.

目次

  • Catalysis: A Key to Advances in Applied Polymer Science
  • Most Advanced Magnesium Chloride Supported Ziegler-Natta Catalyst
  • Polymerization of C[2-C[6 *a-Olefins in the Presence of Modified Ziegler-Natta Catalysts Based on Titanium Halides and Organoaluminum Sulfates
  • Isotactic Olefin Polymerization with Optically Active Catalysts
  • 1-Butene Polymerization with Ethylenebis-(1-indenyl)-zirconium Dichloride and Methylaluminoxane Catalyst System: Effect of Hydrogen Addition
  • Rate of Ethylene Polymerization with the Catalyst System (*h]5-RC[5H[4)[2ZrCl[2-Methylalumininoxane: Effects of Cyclopentadienyl Ring Substituents
  • Migratory Nickel(0)-Phosphorane Catalyst: *a-Olefin Polymerization by 2,*w-Linkage
  • Structure and Morphology of Highly Stereoregular Syndiotactic Polypropylene Produced by Homogeneous Catalysts
  • Dicyclopentadiene Polymerization Using Well-Characterized Tungsten Phenoxide Complexes
  • Structural Effects and Reactivity of Polymer-Bound Functional Groups: Kinetics of Nucleophilic Displacement Reactions on Chlorinated Polyethers
  • Mechanism of Oxirane Coordination Polymerization of Soluble Polynuclear -Oxometal Alkoxide Aggregates
  • '^3C NMR Analysis of Polyether Elastomers
  • Calorimetric Study of Cure Behavior of an Amine-Epoxy Resin under Ambient Conditions
  • X-ray Fiber Diffraction Study of a Synthetic Analog of Cellulose: Poly[3,3-bis(hydroxymethyl)Oxetane]
  • Metalloporphyrin Catalysts for Control of Polymerization
  • Oligomerization of Oxiranes with Aluminum Complexes as Initiators
  • Catalysis and Initiators for Controlling the Structure of Polymers with Inorganic Backbones
  • Mechanisms and Catalysis in Cyclophosphazene Polymerization
  • Polyaddition of Epoxides and Diepoxides to the Acids of Phosphorus: Synthesis of Poly(alkylene phosphate)s
  • Poly(methyl methacrylate)-block-polyisobutylene-block-poly(methyl methacrylate) Thermoplastic Elastomers: Synthesis, Characterization, and Some Mechanical Properties

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