書誌事項

Molecular sieves

edited by Mario L. Occelli, Harry E.Robson

(Synthesis of microporous materials, v. 1)

Van Nostrand Reinhold, c1992

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Top international experts present their findings here on new commercial pillared clays and the latest work in industrial microporous solids. Culled from recent investigations, some presented at the Symposium on Advances in Zeolites and Pillared Clays synthesis sponsored by the American Chemical Society, these papers include previously unpublished reports on commercial materials from major corporations and research institutes. They offer how-to information on zeolite synthesis, as well as a survey of advances in novel zeolites.

目次

Attempted translation of the original old-Swedish paper of Cronstedt. The chemistry of NaY crystallization from sodium silicate solutions. Synthesis of zeolite Y in gelatin solution. Synthesis and characterization of Breck Structure Six. Synthesis and characterization of VPI-6 - another intergrowth of hexagonal and cublic faujasite. A study of ultrastable zeolite Y using solid state NMR with H-27A1 cross-polarization and fast magic-angle spinning. Crystallization kinetics of the zeolite s faujasite, P, mordentite, L, omega, offretite and sodalite in the system (Na, K TMA) A10[x2 n [ (Na, K, TMA)[xm H [x4-[xm S10[x4 p H[x20 in dependence on the ratio of the cations. 12-Ring channell templated mazzite: a stabilized calcined structure. Common factors in the synthesis of Na-chabazite and K-Mazzite. Precursor phases and nucleation of zeolite TON. Zeolite synthesis in the Na-TMA system at low temperature. Low temperature crystallization of MFI zeolite in alkaline flouride medium. [Gallosilicate derivatives of the EUO framework zeolites] gallosilicate: a novel derivative of EUO framework zeolites. On the accesibility of the zeolite MFI structure for the T atom introducing reagents. Quantitative evaluation of framework gallium in AS-synthesized and post-synthesis modified gallo- and gallo-alumino MFI-zeolites. From clathrasils to large-pore zeolites: the effects of systematically altering a template structure. Clear solution synthesis of A1PO[x4 molecular sieves. Investigation of the crystallization of very large pore aluminophosphate phases and their physico-chemical characterization. Structure and chemical behavior of the VPI-5 family of compounds. In situ monitoring of the degree of transformation of VPI-5 to A1PO[x4-8 at varoius temperatures by multinuclear solid state NMR and DTA. Isomorphous substitutions of silicone and cobalt in molecular sieve A1P0[x4-5. Solid-state NMR studies of a high-temperature phase transformation of hydrated porous aluminophosphate VPI-5. Synthesis of VPI-7: a novel 3-membered ring containing molecular sieve. Zeolite NU-87: aspects of its synthesis, characterization, structure and properties. Aluminium- and boron-containing SSZ-24 - the silica analog of A1PO[x4-5. Orienting effect of flouride anions in the synthesis of a novel gallophosphate of LTA type. Hydrothermal synthesis and structural characterization of new zinc phosphate having a channel structure, Zn[xg(PO[x4)[x2.H[x2O. The synthesis and characterization of some new hydrated sodium zinc phosphates. Synthesis of adsorptive properties of titanium silicate molecular sieves. Intergrowths in zeolite structures. Two-dimensional NMR studies of the structure and reactivity of molecular sieve catalysts. Model considerations for the crystallization of zeolites. Microwave techniques in zeolite synthesis. Dynamic features of the synthesis of zeolites in a mixed alkali ion system. ]x1]x8 C and 'H magic-angle-spinning NMR studies of the conversation of methanol over offretite/erionite intergrowths. EXAFS studies of iron-substitution zeolites with the ZSM-5 structure.

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