書誌事項

Selectivity in catalysis

Mark E. Davis, editor, Steven L. Suib, editor

(ACS symposium series, 517)

American Chemical Society, 1993

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注記

"Developed from a symposium sponsored by the Catalysis and Surface Science Secretariat at the Fourth Chemical Congress of North America (202nd National Meeting of the American Chemical Society), New York, New York, August 25-30, 1991."

Includes bibliographical references and indexes

内容説明・目次

内容説明

This title discusses recent research in enhancing selectivity in catalysis through stereoselectivity, reaction pathway control, shape electivity, and alloys and clusters., It presents an interdisciplinary approach to increasing selectivity in homogeneous and heterogeneous catalysis research. The book provides: tutorial chapters on stereoselectivity; reaction pathway control; shape selectivity; alloys and clusters; and an overview chapter that discusses both the current state of the field and possible future directions.

目次

  • Selectivity in catalysis - an overview
  • stereoselectivity - the ultimate challenge in catalysis
  • asymmetric catalytic hydrogenation of 2-arylacrylic acids as a low-cost route to pharmaceutical products
  • chiral rhodium (II) carboxamides - remarkably effective catalysts for enantioselective metal carbene transformations
  • discrete chiral rhodium phosphine complexes as catalysts for asymmetric hydrosilation of ketones
  • catalytic asymmetric heck reaction
  • clusters, alloys, and poisoning
  • platinum, tin, alumina catalysts - comparison of alkane dehydrocyclization activity and characterization data
  • alkyne coordination, dimerization, and scission on a tungsten - triiridiuim cluster core - reaction modeling studies related to cluster-derived butane hydrogenolysis catalysts
  • platinum - tin and gold - tin bimetallic particles prepared from solvated metal atoms - structure and catalysis
  • mechanism and selectivity in catalytic olefin polymerization
  • effect of a model hydrogenation on a catalytic palladium membrane
  • vanadium migration between model components of fluid cracking catalysts - SEM-EDX studies
  • shape-selective catalysis with zeolites and molecular sieves
  • reactions of meta-diisopropylbenzene on acid molecular sieves
  • methyl tert butyl ether and ethyl tert butyl ether - synthesis over triflic acid modified Y-zeolite
  • design of layered phosphate hosts containing multiply bonded bimetallic guest species
  • nuclear magnetic resonance imaging of anisotropic solid-state chemical reactions
  • homogeneous adsorption of benzene on naX and naY zeolites
  • reaction pathway analysis - global molecular and mechanistic perspectives
  • preparation, characterization, and catalysis of a modified ZSM-5 zeolite
  • effect of catalyst preparation on the aromatization of n-hexane over Pt clusters supported on hydrotalcite
  • reactions of ethylene over ruY zeolite
  • activation of C-H, C-C, and C-O bonds of oxygenates on rh(III)
  • continuous catalytic conversion of acetylene to higher hydrocarbons over a metal modified shape selective zeolite catalyst
  • characterization of ruCl, impregnated NaY zeolite
  • non-flory product distributions in fischer-tropsch synthesis catalyzed by ruthenium, cobalt, and iron.

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詳細情報

  • NII書誌ID(NCID)
    BA19693380
  • ISBN
    • 0841225192
  • LCCN
    92042872
  • 出版国コード
    us
  • タイトル言語コード
    eng
  • 本文言語コード
    eng
  • 出版地
    Washington, DC
  • ページ数/冊数
    xi, 410 p.
  • 大きさ
    24 p
  • 分類
  • 件名
  • 親書誌ID
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