The Microkinetics of heterogeneous catalysis

著者

書誌事項

The Microkinetics of heterogeneous catalysis

James A. Dumesic ... [et al.]

（ACS professional reference book）

American Chemical Society, 1993

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Defines the emerging field of catalytic reaction synthesis in the search for new catalysts and catalytic processes. Illustrates how experimental data from diverse sources can be consolidated to form a quantitative description of the essential chemistry taking place on the catalyst surface. Elucidates the possible relationships between catalyst kinetic properties and surface chemical bonding properties. Offers examples of microkinetic analysis and catalytic reaction synthesis for a variety of catalytic reactions over metals, oxides, and zeolite catalysts. Illustrates the underlying strategy used to formulate a microkinetic model, calibrate the model to the existing experimental data, and assess the critical aspects of the essential surface chemistry involved in the catalytic process.

目次

  • Microkinetic Analysis and Catalytic Reaction Synthesis
  • Microkinetic Analysis
  • The Supporting Role of Empirical Information
  • Informative Experiments
  • Ethylene Hydrogenation Catalyzed by Platinum
  • Ammonia Synthesis Catalyzed by Iron
  • Ethane Hydrogenolysis Catalyzed by Group VIII Metals
  • Methane Oxidation Catalyzed by Molybdenum and Vanadium Oxides
  • Methane Dimerization Catalyzed by Li-MgO
  • Redox Catalysis by Transition Metals Exchanged in Zeolites
  • Isobutane Cracking Catalyzed by Acid Zeolites
  • Appendix: Rate Constants

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