New aspects of spillover effect in catalysis : for development of highly active catalysts : proceedings of the third International Conference on Spillover, Kyoto, Japan, August 17-20, 1993
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Bibliographic Information
New aspects of spillover effect in catalysis : for development of highly active catalysts : proceedings of the third International Conference on Spillover, Kyoto, Japan, August 17-20, 1993
（Studies in surface science and catalysis, v. 77）
Elsevier, 1993
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Other editors: K. Fujimoto, T. Uchijima, M. Masai
Includes bibliographical references and index
Description and Table of Contents
Description
The spillover effect is one of the most promising factors in the enhancement of catalytic reaction rates. The spillover phenomenon was found in the 1960s by several researcch groups independently. It was defined at the previous International Symposium on Spillover as follows "Spillover involves the transport of active species which are adsorbed or formed on a first phase onto another phase that does not adsorb or form the species under the same condition". However, this effect appears typically in the dynamic state, i.e., during reactions, which advance with a considerable reaction rate. This makes it difficult to elucidate the spillover effect through static methods. Therefore, more fundamental investigations are necessary. The development of alternative energy sources and protection of the environment demands highly selective and very rapid catalytic reactions at deviating conditions. To achieve these goals new concepts, such as the spillover effect, aree needed. This proceedings book, which comprises 80 papers contains methods for preparing catalysts in order to realize spillover effects and suggests the most probable mechanisms to explain these non-linear phenomena.
It also contains studies on applications of the spillover effect to improve industrial catalytic processes. The book will be invaluable in the development of industrial catalysts and for solving energy and environmental protection problems.
Table of Contents
- Part 1 Plenary lectures: the control of selectivity and stability of catalysts by spillover processes, B. Delmon
- catalyst design based on spillover theory, K. Fujimoto
- spillover effect as the key concept for realizing rapid catalytic reactions, T. Inui. Part 2 Special lecture: th ehistory and perspectives of spillover, S.J. Teichner. Part 3 Invited lectures: synergism in the catalysis of supported gold, M. Hanuta, et al
- the effect of spillover hydrogen on coke formation catalyzed by HY zeolite and pillared montmorillonite, E. Kikuchi and T. Matsuda
- spectroscopic insight into spillover, W.C. Conner Jr.
- molecular hydrogen-orienated solid acid catalyst, I. Nakamura, et al
- attempt at the characterization of spillover adsorbed species during catalysis, G.M. Pajonk
- oxygen spillover for the design of industrial oxidation catalysts, Y. Moro-oka. Part 3 Oral presentations: (a selection of papers)
- ion spillover as the origin of the NEMCA effect, C.G. Vayenas, et al
- hydrogen spillover on bimetallic supported Pt-Re particles, D.T. On and Che L. Bonneviot
- hydrogen spillover in the conversion of cyclohexane on ZSM-5 zeolites, F. Roessner, et al
- the role of spillover in hydrogenation of oxygenates adsorbed on Ni/Al203, B. Chen and J.L. Falconer
- selective hydrogen permeation through metal-dispersed porous alumina membrane, K. Eguchi, et al
- methoxy formation/spillover on Pd/A1203 studied by 13C1H NMR, O.H. Han, et al
- a mathematical model for spillover, Y.. Nam and P.L. Silverston
- promoting effect and hydrogen spillover in supported SeRh6-cluster analysis, Y. Izumi and Y. Iwasawa
- heterogeneous catalytic ammoximation of cyclohexanone with ammonia and molecular oxygen, G. Busca, et al.
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