Solid state chemistry : synthesis, structure, and properties of selected oxides and sulfides
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書誌事項
Solid state chemistry : synthesis, structure, and properties of selected oxides and sulfides
Chapman & Hall, 1993
- : pbk. : acid-free paper
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注記
Includes bibliographical references and index
内容説明・目次
- 巻冊次
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ISBN 9780412036118
内容説明
Written from the point of view of the chemist, rather than the physicist, "Solid State Chemistry" emphasizes the importance of careful synthesis to understanding the properties of a large number of transition metal oxides and sulfides. It discusses many widely used solid state materials, including high-temperature oxide superconductors, diamond films, catalysts, semiconductors, and magnetic materials. The introductory tutorial section familiarizes the reader with basic elements of crystallography; the electronic, magnetic, and optical properties of solids; and phase diagrams. The tutorials use physics and mathematics at levels that any senior chemistry student should be able to follow with little difficulty. The chapters that follow treat the synthesis of oxides and sulfides as both polycrystalline solids and single crystals. Compounds selected for discussion are classified according to structure type, which are illustrated by clear drawings. Throughout, the focus is on how synthesis is related to properties and how sensitive properties are to small levels of contaminants. The book uses a single extended molecular orbital model to correlate properties with synthesis and structure.
"Solid State Chemistry" is suitable for use as a text for a one-semester course in chemistry or materials science. Each chapter includes problems (some with answers) that test the student's ability to apply the principles discussed and encourage further reading in the literature. This book should be of interest to suitable as a text for a condensed course in chemistry or materials science.
目次
- Tutorial crystal structure - characterization of solids, electrical properties of semiconductors, magnetochemistry, phase diagrams
- transition metal oxides - synthetic techniques, binary oxides, ternary and higher oxides
- selected metal sulfides - binary sulfides, chalcogenides with the tetrahedral structure, ternary transition metal chalcogenides ABXX4.
- 巻冊次
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: pbk. : acid-free paper ISBN 9780412036217
内容説明
The subject matterofsolid state chemistry lies within the spheres ofboth physical and inorganic chemistry. In addition, there is a large overlap with solid state physics and materials engineering. However, solid state chemistry has still to be recognized by the general body ofchemists as a legitimate subfield ofchemistry. The discipline is not even well defined as to content and has many facets that make writing a textbook a formidable task. The early studies carried out in the United States by Roland Ward and his co workers emphasized the synthesisofnew materials and the determination oftheir structure. His work on doped alkaline earth sulfides formed the basis for the development of infrared phosphors and his pioneering studies on oxides were important in understanding the structural features of both the perovskite oxides as well as the magnetoplumbites. In 1945, A. F. Wells published the first edition of Structural Inorganic Chemistry. This work attempts to demonstrate that the synthesis, structure, and properties of solids form an important part of inorganic chemistry. Now, after almost 50 years during which many notable advances have been made in solid state chemistry, it is still evident that the synthesis, structure determination, and properties of solids receive little attention in most treatments of inorganic chemistry. The development of the field since the early studies of Roland Ward (early 1940s) has been rapid.
目次
- Preface. Part I: Tutorial. Crystal structure: Translation
- Crystal planes and directions
- Bravais or space lattices
- Symmetry elements
- Screw axes and glide planes
- space groups
- Problems. Characterization of solids. Characterization of the major phase: Microscopy
- Microprobe analysis
- Density determination
- X-ray diffraction
- Neutron diffraction
- Thermal analysis
- Wet chemistry
- Spectroscopic methods. Characterization of minor phazes and impurities: Limitations of analytical methods. Problems. Electrical properties of semiconductors: Problems. Magnetochemistry: Problems. Phase diagrams: Binary phase diagrams
- Ternary phase diagrams
- Problems. Part II: Transition metal oxides. Introduction. Synthetic techniques. Preparation of polycrystalline solids: Sol gel synthesis of transition metal oxides
- Chimie Douce. Sintering and crystal growth. The growth of oxide single crystals: Growth from the melt
- High-temperature solution growth
- Flux growth
- Chemical vapor transport
- Hydrothermal synthesis
- High-pressure synthesis
- electrolytic reduction of fused salts. Problems. Binary oxides. Transition metal monoxides: Transition metal monoxides and the rock salt structure
- Copper(II) oxide. Transition metal dioxides: Titanium(IV) oxide
- Vanadium(IV) oxide
- Other transition metal dioxides
- The crystal chemistry of ZrO2. Several transition metal oxides with the corundum structure. Ternary and higher oxides. Synthesis and characterization of ABO2 delafossite compounds. Perovskites. Tungsten bronzes and related compounds: Rhenium(VI) oxide and rhenium bronzes
- Rhenium bronzes
- Tungsten bronzes
- Molybdenum bronzes
- Oxyfluoride bronzes of molybdenum
- Platinum metal bronzes. Spinels. Conducting iron tungstates and niobates. High-temperature superconducting oxides. Problems. Part III: Selected metal sulfides. Binary sufides. Low-temperature synthesis of transition metal sulfides: Low-temperature syntheses and properties of Co9S8, Ni3S2 and Fe7S8
- Low-temperature preparation of sulfides with the Pyrite Structure. 3d transition metal disulfides with pyrite structure. Layer structures. Intercalcation compounds. Chevrel phases. Chalcogenides with the tetrahedral structure. Zinc sulphide. Diamond. Chalcopyrite and related structures: Chalcopyrite
- Solid solutions of (ZnS)1-X(CuMS2)X(M = Al, Ga, IN, or Fe)
- Stannite or Wurtz-Stannite. Ternary transition metal chalcogenides AB2X4: Thiospinels
- The Monoclinic defect nickel arsenide structure
- Problems. Answers to selected problems. Index.
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