書誌事項

Catalyzed direct reactions of silicon

edited by Kenrich M. Lewis, David G. Rethwisch

(Studies in organic chemistry, 49)

Elsevier, 1993

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注記

Includes bibliographical references and indexes

内容説明・目次

内容説明

There has been a scarcity of authoritative, published information on the direct reactions of silicon. Nevertheless, the need for up-to-date information on the reactions and their silane products persists across a broad range of scientists. Recent progress warrants documentation of the state-of-the-art, and identification of the areas for future research. Some of the highlights of the book are: An authoritative presentation of the state of commercial practice on the direct synthesis of chlorosilanes and methylchlorosilanes in more depth and breadth than can be found elsewhere in a single volume; the use of in-line FTIR for real time analysis of methylchlorosilane vapors exiting the direct reaction shortens the analysis time from 30 minutes to 20 seconds and provides information comparable to gas chromatography; the first comprehensive publication on the direct synthesis of tri(dimethylamino)silane; chemical engineering modelling of the direct synthesis of chlorosilanes and methylchlorosilanes.

目次

  • Commercial production of silanes by the direct synthesis, B. Kanner and K.M. Lewis
  • production of silicon for the methyl chloride direct synthesis, J.H. Downing et al
  • quality criteria for silicon used for organo-silicon industry, H.M. Rong et al
  • some considerations of the direct synthesis of methylchlorosilanes, W.F. Banholzer et al
  • selection of copper formate catalysts for the direct synthesis of methylchlorosilanes, K.M. Lewis et al
  • catalyst preparation for the direct synthesis of methylchlorosilanes - practical, theoretical, and reactor design considerations, L.K. Doraiswamy and A.N. Gokarn
  • kinetics of the methyl chloride-silicon direct reaction, I.R. Moore and J.A. Nelson
  • gas chromatographic analysis of methylchlorosilanes produced by the direct reaction, L.G. Hawkins
  • gas chromatographic analysis in the manufacture of chlorosilanes, H. Rotzsche et al
  • in-line Fourier transform infrared spectroscopic analysis of methylchlorosilanes produced by the direct reaction, H.B. Friedrich et al
  • copper-catalyzed etching of silicon, J.A. Mucha et al
  • model reaction studies of the direct synthesis of methylchlorosilanes, K.A. Magrini et al
  • selective formation of dimethylchlorosilane on Si surfaces, K.A. Magrini and J.L. Falconer
  • effects of promoters on the catalytic synthesis of methylchlorosilanes, L.D. Gasper-Galvin et al
  • chemisorption and catalytic activity of Cu and Ag atoms on Si(111) surfaces, S.H. Chou et al
  • surface-chemical studies of the mechanism of the direct synthesis of methylchlorosilanes, K.M. Lewis et al
  • direct synthesis of chlorosilanes and silane, W.C. Breneman
  • by-products from waste treatment for a bench scale trichlorosilane/tetrachlorosilane direct process, J.A. Cervantes et al
  • mathematical modelling of diffusion and microkinetics in direct reactions of silicon and in the processing of electronic components, S.S.E.H. Elnashaie
  • copper-catalyzed reaction of dimethylamine with silicon, K.M. Lewis et al
  • author index
  • subject index.

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