Nonequilibrium processes in catalysis
著者
書誌事項
Nonequilibrium processes in catalysis
CRC, c1994
- タイトル別名
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Neravnovesnye prot︠s︡essy v katalize
- 統一タイトル
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Neravnovesnye prot︠s︡essy v katalize
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注記
Includes bibliographical references (p. 263-281) and index
内容説明・目次
内容説明
Nonequilibrium Processes in Catalysis presents modern ideas and experimental data (e.g., molecular beams, laser technique) on adsorption and catalysis, the mechanism of energy exchange in the processes of particles interaction with a surface, and the lifetimes of excited particles on a surface. Previously unpublished theoretical information regarding the principle of chemoenergetical stimulation accounting for the acceleration of one reaction at the expense of reactant excitation in another is provided, and new ideas about nonequilibrium surface diffusion are explored. Examples of the formation of nonequilibrium dissipative structures in catalysis are presented, including auto-oscillations, auto-waves, multiplicity of kinetic regimes, nonequilibrium phase transition, and decelerated electron exchange between solid and adsorbed species. The book also describes new experimental methods for studying nonequilibrium and quick processes in catalysis. Nonequilibrium Processes in Catalysis will benefit physicists involved with surface science, chemists involved with adsorption and catalysis, engineers, vacuum scientists, physical chemists, materials chemists, students, and others interested in these processes.
目次
Introduction. Research Methods. Heterogeneous Deactivation of Excited Molecules. Interaction of Molecular Beams with Surface. Lifetime of Excited Molecules on Surface. Precursor and Nonequilibrium Diffusion. Chemoenergetic Stimulation. Thermodynamics of Irreversible Processes and Dissipative Structures in Catalysis. Phase Transformations in Catalysis. Nonequilibrium States of Catalyst. References. Index.
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