Organic chemistry
著者
書誌事項
Organic chemistry
W.H. Freeman, c1994
2nd ed
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
This second edition has been reorganized to include more student study aids, new problem sets and applications. "Organic Chemistry" employs the standard functional group approach, leading students in a logical sequence from the alkanes to more and more highly functionalized classes of molecules. The physical properties of simple organic compounds are introduced early, as are basic physical concepts such as kinetics and thermodynamics. Reaction chemistry is juxtaposed to the mechanism by which each reaction proceeds, and important spectroscopic techniques are introduced as needed and used thereafter to elucidate chemical structures. Throughout, Vollhardt and Schore, a new co-author, demonstrate the everyday relevance of organic chemistry by presenting aoplications to biological and industrial processes.
目次
To the Student. Structure and Bonding in Organic Molecules. Alkanes: Molecules Lacking Functional Groups. Reactions of Alkanes: Bond-Dissociation Energies, Radical Halogenation, and Relative Reactivity. Cyclic Alkanes. Stereoisomers. Properties and Reactions of Haloalkanes: Biomolecular Nucleophilic Substitution. Further Reactions of Haloalkanes: Unimolecular Substitution and Pathways of Elimination. Hydroxy Functional Group: Properties of the Alcohols and Strategic Synthesis. Further Reactions of Alcohols and the Chemistry of Ethers. Using Nuclear Magnetic Resonance Spectroscopy to Deduce Structure. Alkenes and Infrared Spectroscopy. Reactions of Alkenes. Alkynes: The Carbon-Carbon Triple Bond. Delocalized Pi Systems and Their Investigation by Ultraviolet and Visible Spectroscopy. Unusual Stability of the Cyclic Electron Sextet: Benzene, Other Cyclic Polyenes, and Electrophilic. Aromatic Substitution. Electrophilic Attack on Derivatives of Benzene: Substituents Control Regioselectivity. Aldehydes and Ketones: The Carbonyl Group. Enols and Enones: alpha, beta-Unsaturated Alcohols, Aldehydes, and Ketones. Carboxylic Acids. Carboxylic Acid Derivatives and Mass Spectroscopy. Amines and Their Derivatives: Functional Groups Containing Nitrogen. Chemistry of Substituents: Alkylbenzenes, Phenols, and Benzenamines. Dicarbonyl Compounds. Carbohydrates: Polyfunctional Compounds in Nature. Heterocycles: Heteroatoms in Cyclic Organic Compounds. Amino Acids, Peptides, and Proteins: Nitrogen-Containing Polymers in Nature. Answers to Exercises.
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