The concept of electronegativity and structural chemistry
著者
書誌事項
The concept of electronegativity and structural chemistry
(Soviet scientific reviews, section B . Chemistry reviews ; vol. 15,
Harwood Academic Publishers, 1990
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内容説明・目次
内容説明
Work carried out by the author and his colleagues to determine electronegativities (EN) in molecules and crystals using various physical methods is described and compared with similar work in the USSR and elsewhere. Experimental methods of determining EN are emphasized.
目次
- Thermochemical determination of EN
- calculation of EN from ionization potentials
- determination of EN from geometrical characteristics
- determination of EN from optical data
- concept of EN, recommended system of the EN of atoms and radicals
- bond ionicity in molecules
- bond ionicity in crystals
- variability of bond ionicity in crystals under pressure
- EN and the structural-chemical properties of substances
- conclusions.
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