Radical, single electron transfer, and concerted reactions
著者
書誌事項
Radical, single electron transfer, and concerted reactions
(Advances in detailed reaction mechanisms : a research annual / series editor, James M. Coxon, v. 1)
JAI Press, 1991
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内容説明・目次
内容説明
Advances in Detailed Reaction Mechanisms, Volume 1: Radical, Single Electron Transfer, and Concerted Reactions presents the unique properties of reactions. This book discusses the approaches to synthetic strategies, including nucleophilic substitution and the study of the radicals of the amino acids. Organized into four chapters, this volume begins with an overview of the complications that can arise in mechanistic probe investigations. This text then examines the development of free radicals that reflects several factors, including the recognition that their unique characteristics may be harnessed in simple approaches to synthetic strategies. Other chapters consider the variety and types of reaction that free radicals can undergo. This book discusses as well the factors that affect the formation and reaction of a-carbon-centered radicals derived from amino acids and their derivatives. The final chapter deals with deuterium isotope effects as well as fluorine substituent effects. This book is a valuable resource for physical organic chemists.
目次
Contents
List of Contributors
Introduction to the Series
Preface
Radical Kinetics and Mechanistic Probe Studies
Free Radical Reactions: Fragmentation and Rearrangements in Aqueous Solution
a-Carbon-Centered Radicals From Amino Acids and Their Derivatives
Cycloadditions of Allenes: Reactions of Unusual Mechanistic Perspicuity
Index
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